Synthesis
ChemicalBook > CAS DataBase List > N-Phenylbenzylamine

N-Phenylbenzylamine

Synthesis
Product Name
N-Phenylbenzylamine
CAS No.
103-32-2
Chemical Name
N-Phenylbenzylamine
Synonyms
N-BENZYLANILINE;BENZYLANILINE;aminobenzophenone;BENZYL-PHENYL-AMINE;Benzenemethanamine, N-phenyl-;AURORA 4803;Phenhenzamine;A-TOLUYL CHLORIDE;aniline,N-benzyl-;AKOS BBS-00003909
CBNumber
CB9762952
Molecular Formula
C13H13N
Formula Weight
183.25
MOL File
103-32-2.mol
More
Less

N-Phenylbenzylamine Property

Melting point:
35-38 °C (lit.)
Boiling point:
306-307 °C (lit.)
Density 
1.061 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.5325(lit.)
Flash point:
217 °F
storage temp. 
Store below +30°C.
solubility 
alcohol: soluble
form 
Crystalline Powder or Low Melting Mass
pka
3.89±0.10(Predicted)
Specific Gravity
1.061
color 
Colorless to yellow-beige
Water Solubility 
INSOLUBLE
Merck 
14,1126
CAS DataBase Reference
103-32-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanamine, N-phenyl-(103-32-2)
EPA Substance Registry System
Benzenemethanamine, N-phenyl- (103-32-2)
More
Less

Safety

Hazard Codes 
C,Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 2577 8/PG 2
WGK Germany 
3
F 
21
HS Code 
29214980
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
185493
Product name
N-Benzylaniline
Purity
≥99%
Packaging
25g
Price
$75.6
Updated
2024/03/01
Sigma-Aldrich
Product number
185493
Product name
N-Benzylaniline
Purity
≥99%
Packaging
100g
Price
$117.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20982
Product name
N-Phenylbenzylamine
Purity
for synthesis
Packaging
250g
Price
$113
Updated
2023/01/07
TCI Chemical
Product number
P0159
Product name
N-Phenylbenzylamine
Purity
>98.0%(GC)
Packaging
25g
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
P0159
Product name
N-Phenylbenzylamine
Purity
>98.0%(GC)
Packaging
100g
Price
$82
Updated
2024/03/01
More
Less

N-Phenylbenzylamine Chemical Properties,Usage,Production

Synthesis

N-Phenylbenzylamine can be obtained by condensation of benzyl chloride and aniline. Mix and stir sodium bicarbonate, water and aniline, heat to 90-95°C, and slowly add benzyl chloride. React at 90-95°C for 3h. Cool and filter. The filtrate was separated, and the organic layer was washed with saturated brine and dried over anhydrous sodium sulfate. Then, under reduced pressure distillation, the 81°C (1.6kPa) fraction was collected to recover aniline, and the 170-190°C (1.6kPa) fraction was cooled and solidified to give N-Phenylbenzylamine.

Chemical Properties

colorless to yellow-beige crystalline powder

Uses

N-Benzylaniline is a major metabolite of the antihistaminic Antazoline and other N-substituted benzylanilines.

Uses

N-Benzylaniline was used in the separation of tervalent gallium, indium and thallium by solvent extraction method.

Synthesis Reference(s)

Chemistry Letters, 8, p. 45, 1979
Organic Syntheses, Coll. Vol. 1, p. 102, 1941
Tetrahedron Letters, 19, p. 4987, 1978 DOI: 10.1016/S0040-4039(01)85789-0

General Description

The electropolymerisation of N-benzylaniline at transparent Indium Tin Oxide glass electrodes has been investigated by UV-visible spectroelectrochemistry. N-Benzylaniline on electrochemical oxidation in aqueous sulfuric acid solution produces an adherent conducting polymer film at the platinum electrode.

Purification Methods

Crystallise the amine from pet ether (b 60-80o) (ca 0.5mL/g). The picrate has m 113o (from Et2O). [Beilstein 12 H 1023, 12 I 449, 12 II 548, 12 III 2215, 12 IV 2172.]

N-Phenylbenzylamine Preparation Products And Raw materials

Raw materials

Benzyl chloride

Preparation Products

ACID BLUE 15 Acid Blue 9 BEPRIDIL Erioglaucine disodium salt 1R-cis crysanthemic acid
More
Less

N-Phenylbenzylamine Suppliers

Americas 1 Austria 1 Belgium 1 Canada 1 China 167 Europe 3 Germany 4 India 14 Japan 3 Slovakia 1 Switzerland 1 Ukraine 1 United Kingdom 9 United States 25 Global 232
Shanghai YouPeng Chemical Co. Ltd.
Tel
021-69005955 13701776567
Fax
021-69005775
Email
youpengchem@163.com
Country
China
ProdList
4293
Advantage
56
Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-83946278 13820503911
Fax
022-83945176
Email
sales@creasyn.com
Country
China
ProdList
980
Advantage
68
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9809
Advantage
59
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19172
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6134
Advantage
55
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9899
Advantage
55
Zouping Mingxing Chemical Co.,Ltd.
Tel
86-13605431940 13605431940
Fax
0086-0543-2240079
Email
zpmxchemical@126.com
Country
China
ProdList
1999
Advantage
62
TargetMol Chemicals Inc.
Tel
021-021-33632979 15002134094
Fax
021-33632979
Email
marketing@targetmol.com
Country
China
ProdList
7783
Advantage
58
Chemwill Asia Co.,Ltd.
Tel
86-21-51086038
Fax
86-21-51861608
Country
China
ProdList
2930
Advantage
58
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4767
Advantage
60
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-+86-571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
Country
China
ProdList
11481
Advantage
59
Shanghai Song Yuan Chemical Technology Co., Ltd.
Tel
010-1234567 18521000990
Fax
86-021-33275113
Email
sonyuanchemical@163.com
Country
China
ProdList
6479
Advantage
50
Beijing Holiyang Chemical Co. Ltd.
Tel
13718199399
Fax
QQ : 206661479
Email
holiyangchem@163.com
Country
China
ProdList
3381
Advantage
56
Sichuan Hainuowei Technology Co. Ltd.
Tel
13708085536
Fax
QQ : 121102042
Email
hanovichem@163.com
Country
China
ProdList
3383
Advantage
56
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 18112977050
Email
cb6@aikonchem.com
Country
China
ProdList
16684
Advantage
50
Shanghai TongYuan Chemical Co., Ltd.
Tel
021-021-69182866 13701855675
Fax
021-69182022
Email
tongyuanchem@126.com
Country
China
ProdList
4321
Advantage
58
Shanghai Kaisai Chemical Co., Ltd
Tel
021-33516722 13701817765
Fax
021-33516776
Email
kaisaichem@163.com
Country
China
ProdList
4741
Advantage
58
Shanghai LanRun Chemical Co., Ltd.
Tel
021-69515658 ; 69515628 13701998368
Fax
021-69515998
Email
longrunchem@163.com
Country
China
ProdList
3912
Advantage
50
Shanghai Rolead Chemical Technology Co., Ltd.
Tel
021-69992220 13701886816
Fax
021-69992237
Email
roleadchem@163.com
Country
China
ProdList
4750
Advantage
50
Shanghai Kangtuo Chemical Co., Ltd.
Tel
021-69185552 13701777608
Fax
021-69186006
Email
kangtuochem@163.com
Country
China
ProdList
4360
Advantage
55
Hubei Jusheng Technology Co.,Ltd
Tel
027-59599241 18871490274
Fax
027-59599241
Email
1400878000@qq.com
Country
China
ProdList
9958
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Chengdu Research Accelerators Technology Co., Ltd.
Tel
028-64353063
Fax
028-64353063 QQ:784253935
Email
reacchemical@163.com
Country
China
ProdList
5253
Advantage
58
Chengdu RunZeBenTu Chemical Co., Ltd
Tel
028-88469284 18000562381
Email
rzbtsj@163.com
Country
China
ProdList
9951
Advantage
56
Qingxian Creasyn Pharmaceutical Technology Co., Ltd.
Tel
022-83945173 18622315263
Fax
QQ1559208715
Email
export@creasyn.com
Country
China
ProdList
459
Advantage
55
ShangHai Siyan Biological Technology Co., Ltd.
Tel
021-50908862，442785678，326799392 18721037013
Fax
021-50908862
Email
siyansales@126.com
Country
China
ProdList
9627
Advantage
58
Shanghai Qiao Chemical Science Co., Ltd
Tel
021-58892003
Email
info@qiaochem.com
Country
China
ProdList
5902
Advantage
65
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
27313
Advantage
60
Shanghai XiZhi Chemical Co., Ltd.
Tel
021-69005855 13701817869
Fax
021-69005955
Email
xizhichem@163.com
Country
China
ProdList
3339
Advantage
55
Shanghai Pengsuo Biochemical Technology Co., Ltd.
Tel
021-59118555 13701823997
Fax
021-59119222
Email
pengsuochem@163.com
Country
China
ProdList
3300
Advantage
55
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
Advantage
60
Nanjing Hengwang biological pharmaceutical Co., Ltd.
Tel
18061201868
Fax
025-58742456
Email
sales@blakechem.com
Country
China
ProdList
74
Advantage
60
Chengdu Dianchun Technology Co., Ltd
Tel
400-1166-196 18502815961
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
14603
Advantage
60
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Chengdu Synguider Technology Co., Ltd.
Tel
400-086-3412 028-85062459
Fax
028-85062459
Email
synguider@163.com
Country
China
ProdList
3295
Advantage
55
More
Less

View Lastest Price from N-Phenylbenzylamine manufacturers

airuikechemical co., ltd.
Product
n-benzylaniline 103-32-2
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-09
Shaanxi Dideu Medichem Co. Ltd
Product
N-Phenylbenzylamine 103-32-2
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2024-08-04
Career Henan Chemical Co
Product
N-Phenylbenzylamine 103-32-2
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2018-08-20

103-32-2, N-PhenylbenzylamineRelated Search:

Benzyl bromide Benzalacetone Benzyltrimethylammonium chloride Benzyltriethylammonium chloride Benzyl chloride N,N-Dimethylbenzylamine DIBENZYLTOLUENE Phthalylsulfathiazole Salicylanilide N-Phenylbenzohydroxamic acid CHLORANTINE FAST RED 5B 5-CHLOROSALICYLANILIDE XYLIDYL BLUE I SODIUM SALT BENZANILIDE N-ETHYL-N-PHENYLBENZYLAMINE NAPHTHOL AS-BI PHOSPHATE Fast Blue BB CI 37155

  • Aniline, N-benzyl-
  • aniline,N-benzyl-
  • Benzenamine, N-(phenylmethyl)-
  • PHENYLACETIC ACID CHLORIDE
  • N-BENZYLANILINE
  • N-PHENYLBENZYLAMINE
  • LABOTEST-BB LT00852555
  • LABOTEST-BB LT00643802
  • BENZYLANILINE
  • BENZYL-PHENYL-AMINE
  • A-TOLUYL CHLORIDE
  • AURORA 4803
  • AKOS BBS-00003909
  • N-PHENYLBENZYLAMINE, 99+%
  • N-Benzylaniline, 99+%
  • Benzenemethanamine, N-phenyl-
  • aminobenzophenone
  • 2-(phenylmethyl)aniline
  • benzeneamine,N-benzyl-
  • Benzylamine, N-phenyl-
  • N-benzylbenzeneamine
  • N-Benzyl-N-phenylamine
  • N-Monobenzylaniline
  • n-phenyl-benzenemethanamin
  • N-Phenylbenzenemethanamine
  • N-phenyl-Benzenemethanamine
  • N-(Phenylmethyl)aniline
  • N-Benzylphenylamine
  • N-Benzylbenzenamine
  • N-Benzylaniline,N-Phenylbenzylamine
  • N-PhenylbenzylaMine, 99% 5GR
  • <i>N</i>-Phenylbenzylamine
  • Phenylbenzylamine
  • N-Phenylbenzylamine for synthesis
  • N-Phenylbenzylamine&gt
  • Phenhenzamine
  • Antazolin Impurity 2
  • Lorazepam Impurity 3
  • 103-32-2
  • 103-32-3
  • C6H5CH2COCl
  • C6H5CH2NHC6H5
  • C6H5COC6H4NH2
  • AMINE
  • Organic Building Blocks
  • Nitrogen Compounds
  • Acid Halides
  • Amines
  • Building Blocks
  • Carbonyl Compounds
  • C11 to C37
  • Amines, Aromatics, Metabolites & Impurities