N-Phenylbenzylamine

Synthesis

Product Name: N-Phenylbenzylamine
CAS No.: 103-32-2
Chemical Name: N-Phenylbenzylamine
Synonyms: N-BENZYLANILINE;BENZYLANILINE;aminobenzophenone;BENZYL-PHENYL-AMINE;Benzenemethanamine, N-phenyl-;AURORA 4803;Phenhenzamine;A-TOLUYL CHLORIDE;aniline,N-benzyl-;AKOS BBS-00003909
CBNumber: CB9762952
Molecular Formula: C13H13N
Formula Weight: 183.25
MOL File: 103-32-2.mol

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N-Phenylbenzylamine Property

Melting point:: 35-38 °C (lit.)
Boiling point:: 306-307 °C (lit.)
Density: 1.061 g/mL at 25 °C (lit.)
refractive index: n20/D 1.5325(lit.)
Flash point:: 217 °F
storage temp.: Store below +30°C.
solubility: alcohol: soluble
form: Crystalline Powder or Low Melting Mass
pka: 3.89±0.10(Predicted)
Specific Gravity: 1.061
color: Colorless to yellow-beige
Water Solubility: INSOLUBLE
Merck: 14,1126
CAS DataBase Reference: 103-32-2(CAS DataBase Reference)
NIST Chemistry Reference: Benzenemethanamine, N-phenyl-(103-32-2)
EPA Substance Registry System: Benzenemethanamine, N-phenyl- (103-32-2)

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Safety

Hazard Codes: C,Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
RIDADR: UN 2577 8/PG 2
WGK Germany: 3
F: 21
HS Code: 29214980

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 185493
Product name: N-Benzylaniline
Purity: ≥99%
Packaging: 25g
Price: $75.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 185493
Product name: N-Benzylaniline
Purity: ≥99%
Packaging: 100g
Price: $117.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.20982
Product name: N-Phenylbenzylamine
Purity: for synthesis
Packaging: 250g
Price: $113
Updated: 2023/01/07

TCI Chemical

Product number: P0159
Product name: N-Phenylbenzylamine
Purity: >98.0%(GC)
Packaging: 25g
Price: $41
Updated: 2024/03/01

TCI Chemical

Product number: P0159
Product name: N-Phenylbenzylamine
Purity: >98.0%(GC)
Packaging: 100g
Price: $82
Updated: 2024/03/01

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N-Phenylbenzylamine Chemical Properties,Usage,Production

Synthesis

N-Phenylbenzylamine can be obtained by condensation of benzyl chloride and aniline. Mix and stir sodium bicarbonate, water and aniline, heat to 90-95°C, and slowly add benzyl chloride. React at 90-95°C for 3h. Cool and filter. The filtrate was separated, and the organic layer was washed with saturated brine and dried over anhydrous sodium sulfate. Then, under reduced pressure distillation, the 81°C (1.6kPa) fraction was collected to recover aniline, and the 170-190°C (1.6kPa) fraction was cooled and solidified to give N-Phenylbenzylamine.

Chemical Properties

colorless to yellow-beige crystalline powder

Uses

N-Benzylaniline is a major metabolite of the antihistaminic Antazoline and other N-substituted benzylanilines.

Uses

N-Benzylaniline was used in the separation of tervalent gallium, indium and thallium by solvent extraction method.

Synthesis Reference(s)

Chemistry Letters, 8, p. 45, 1979
Organic Syntheses, Coll. Vol. 1, p. 102, 1941
Tetrahedron Letters, 19, p. 4987, 1978 DOI: 10.1016/S0040-4039(01)85789-0

General Description

The electropolymerisation of N-benzylaniline at transparent Indium Tin Oxide glass electrodes has been investigated by UV-visible spectroelectrochemistry. N-Benzylaniline on electrochemical oxidation in aqueous sulfuric acid solution produces an adherent conducting polymer film at the platinum electrode.

Purification Methods

Crystallise the amine from pet ether (b 60-80o) (ca 0.5mL/g). The picrate has m 113o (from Et2O). [Beilstein 12 H 1023, 12 I 449, 12 II 548, 12 III 2215, 12 IV 2172.]

N-Phenylbenzylamine Preparation Products And Raw materials

Raw materials

Benzyl chloride

Preparation Products

ACID BLUE 15 Acid Blue 9 BEPRIDIL Erioglaucine disodium salt 1R-cis crysanthemic acid

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N-Phenylbenzylamine Suppliers

Americas 1 Austria 1 Belgium 1 Canada 1 China 167 Europe 3 Germany 4 India 14 Japan 3 Slovakia 1 Switzerland 1 Ukraine 1 United Kingdom 9 United States 25 Global 232

Shanghai YouPeng Chemical Co. Ltd.

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Creasyn Finechem(Tianjin) Co., Ltd.

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J & K SCIENTIFIC LTD.

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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JinYan Chemicals(ShangHai) Co.,Ltd.

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Shanghai Longsheng chemical Co.,Ltd.

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Nanjing Chemlin Chemical Co., Ltd

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Shanghai Hanhong Scientific Co.,Ltd.

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View Lastest Price from N-Phenylbenzylamine manufacturers

airuikechemical co., ltd.

Product: n-benzylaniline 103-32-2
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 99.9%
Supply Ability: 200tons
Release date: 2024-04-09

Shaanxi Dideu Medichem Co. Ltd

Product: N-Phenylbenzylamine 103-32-2
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2024-08-04

Career Henan Chemical Co

Product: N-Phenylbenzylamine 103-32-2
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2018-08-20

103-32-2, N-PhenylbenzylamineRelated Search:

Benzyl bromide Benzalacetone Benzyltrimethylammonium chloride Benzyltriethylammonium chloride Benzyl chloride N,N-Dimethylbenzylamine DIBENZYLTOLUENE Phthalylsulfathiazole Salicylanilide N-Phenylbenzohydroxamic acid CHLORANTINE FAST RED 5B 5-CHLOROSALICYLANILIDE XYLIDYL BLUE I SODIUM SALT BENZANILIDE N-ETHYL-N-PHENYLBENZYLAMINE NAPHTHOL AS-BI PHOSPHATE Fast Blue BB CI 37155

Aniline, N-benzyl-

aniline,N-benzyl-

Benzenamine, N-(phenylmethyl)-

PHENYLACETIC ACID CHLORIDE

N-BENZYLANILINE

N-PHENYLBENZYLAMINE

LABOTEST-BB LT00852555

LABOTEST-BB LT00643802

BENZYLANILINE

BENZYL-PHENYL-AMINE

A-TOLUYL CHLORIDE

AURORA 4803

AKOS BBS-00003909

N-PHENYLBENZYLAMINE, 99+%

N-Benzylaniline, 99+%

Benzenemethanamine, N-phenyl-

aminobenzophenone

2-(phenylmethyl)aniline

benzeneamine,N-benzyl-

Benzylamine, N-phenyl-

N-benzylbenzeneamine

N-Benzyl-N-phenylamine

N-Monobenzylaniline

n-phenyl-benzenemethanamin

N-Phenylbenzenemethanamine

N-phenyl-Benzenemethanamine

N-(Phenylmethyl)aniline

N-Benzylphenylamine

N-Benzylbenzenamine

N-Benzylaniline,N-Phenylbenzylamine

N-PhenylbenzylaMine, 99% 5GR

<i>N</i>-Phenylbenzylamine

Phenylbenzylamine

N-Phenylbenzylamine for synthesis

N-Phenylbenzylamine&gt

Phenhenzamine

Antazolin Impurity 2

Lorazepam Impurity 3

103-32-2

103-32-3

C6H5CH2COCl

C6H5CH2NHC6H5

C6H5COC6H4NH2

AMINE

Organic Building Blocks

Nitrogen Compounds

Acid Halides

Amines

Building Blocks

Carbonyl Compounds

C11 to C37

Amines, Aromatics, Metabolites & Impurities