SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

Product Name: SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
CAS No.: 35789-01-6
Chemical Name: SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Synonyms: )amide]samarium(III);samarium tris(hexamethylsilazide);samarium tris(hexamethyldisilazde);SAMARIUM TRIS(HEXAMETHYLDISILAZIDE);tris(bis(trimethylsilyl)amino)samarium;Tris[N,N-bis(trimethylsilyl)amide]samarium;TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III);Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium;Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM;1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt
CBNumber: CB9775244
Molecular Formula: C6H19NSi2Sm
Formula Weight: 311.76
MOL File: 35789-01-6.mol

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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Property

Melting point:: 93-106 °C(lit.)
Boiling point:: 83-4°C/1x10-4mmHg
Flash point:: 36 °F
form: solid

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Safety

Hazard Codes: F,C
Risk Statements: 11-14/15-34
Safety Statements: 16-26-36/37/39-43-45-7/8
RIDADR: UN 3396 4.3/PG 2
WGK Germany: 3
TSCA: No

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 547980
Product name: Tris[N,N-bis(trimethylsilyl)amide]samarium(III)
Purity: 98%
Packaging: 1g
Price: $193
Updated: 2024/03/01

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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Chemical Properties,Usage,Production

Uses

Reactant for synthesis of:

Heterobimetallic samarium(III) complexes
Binuclear lanthanide complexes

Catalyst for:

Coordination polymerization of renewable butyrolactone-based vinyl monomers
Intramolecular hydroamination of non-activated alkenes
Chiral functionalization of isoxazoles
Enantioselective hydroamination / cyclization

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Preparation Products And Raw materials

Raw materials

Preparation Products

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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Suppliers

China 19 Germany 1 Singapore 1 Switzerland 1 United States 4 Global 26

Meryer (Shanghai) Chemical Technology Co., Ltd.

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Tris[N,N-bis(trimethylsilyl)amide]samarium

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1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt

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samarium tris(hexamethylsilazide)

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tris(bis(trimethylsilyl)amino)samarium

)amide]samarium(III)

35789-01-6

CH33Si2N3Sm

C18H54N3Si6Sm

SmNSiCH3323

Catalysis and Inorganic Chemistry

Samarium

Rare-Earth Metals

Catalysis and Inorganic Chemistry

Chemical Synthesis

Precursors by Metal

SamariumVapor Deposition Precursors

Samariun