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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

Product Name
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
CAS No.
35789-01-6
Chemical Name
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Synonyms
)amide]samarium(III);samarium tris(hexamethylsilazide);samarium tris(hexamethyldisilazde);SAMARIUM TRIS(HEXAMETHYLDISILAZIDE);tris(bis(trimethylsilyl)amino)samarium;Tris[N,N-bis(trimethylsilyl)amide]samarium;TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III);Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium;Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM;1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt
CBNumber
CB9775244
Molecular Formula
C6H19NSi2Sm
Formula Weight
311.76
MOL File
35789-01-6.mol
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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Property

Melting point:
93-106 °C(lit.)
Boiling point:
83-4°C/1x10-4mmHg
Flash point:
36 °F
form 
solid
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Safety

Hazard Codes 
F,C
Risk Statements 
11-14/15-34
Safety Statements 
16-26-36/37/39-43-45-7/8
RIDADR 
UN 3396 4.3/PG 2
WGK Germany 
3
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H261In contact with water releases flammable gas

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
547980
Product name
Tris[N,N-bis(trimethylsilyl)amide]samarium(III)
Purity
98%
Packaging
1g
Price
$193
Updated
2024/03/01
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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Chemical Properties,Usage,Production

Uses

Reactant for synthesis of:

  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Preparation Products And Raw materials

Raw materials

Preparation Products

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SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Suppliers

China 19 Germany 1 Singapore 1 Switzerland 1 United States 5 Global 27

35789-01-6, SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)Related Search:

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  • TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III)
  • Tris[N,N-bis(trimethylsilyl)amide]samarium
  • Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM
  • 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt
  • Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
  • samarium tris(hexamethylsilazide)
  • Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C
  • samarium tris(hexamethyldisilazde)
  • tris(bis(trimethylsilyl)amino)samarium
  • )amide]samarium(III)
  • 35789-01-6
  • CH33Si2N3Sm
  • C18H54N3Si6Sm
  • SmNSiCH3323
  • Catalysis and Inorganic Chemistry
  • Samarium
  • Rare-Earth Metals
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Precursors by Metal
  • SamariumVapor Deposition Precursors
  • Samariun