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4-BROMOBENZHYDRAZIDE

Product Name
4-BROMOBENZHYDRAZIDE
CAS No.
5933-32-4
Chemical Name
4-BROMOBENZHYDRAZIDE
Synonyms
4-BROMOBENZHYDRAZIDE;P-BROMOBENZHYDRAZIDE;4-BROMOBENZOHYDRAZIDE;P-BROMOBENZOHYDRAZIDE;4-BROMOBENZOYLHYDRAZINE;P-BROMOBENZOYLHYDRAZINE;4-BROMOBENZOIC HYDRAZIDE;4-Bromobenzohydrazide >4-Bromobenzhydrazide, 98+%;p-bromo-benzoicacihydrazide
CBNumber
CB9775592
Molecular Formula
C7H7BrN2O
Formula Weight
215.05
MOL File
5933-32-4.mol
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4-BROMOBENZHYDRAZIDE Property

Melting point:
167-169°C
Density 
1.615±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
pka
12.09±0.10(Predicted)
color 
Light beige
Water Solubility 
Soluble in hot methanol (almost transparency). Slightly soluble in water.
BRN 
777006
InChI
InChI=1S/C7H7BrN2O/c8-6-3-1-5(2-4-6)7(11)10-9/h1-4H,9H2,(H,10,11)
InChIKey
UYIMBYKIIMYFPS-UHFFFAOYSA-N
SMILES
C(NN)(=O)C1=CC=C(Br)C=C1
CAS DataBase Reference
5933-32-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-37/39
WGK Germany 
3
RTECS 
DG4449250
HS Code 
29280000
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
259624
Product name
4-Bromobenzoic hydrazide
Purity
98%
Packaging
5g
Price
$45.9
Updated
2025/07/31
TCI Chemical
Product number
B2067
Product name
4-Bromobenzohydrazide
Purity
>97.0%(T)
Packaging
5g
Price
$30
Updated
2025/07/31
TCI Chemical
Product number
B2067
Product name
4-Bromobenzohydrazide
Purity
>97.0%(T)
Packaging
25g
Price
$113
Updated
2025/07/31
TRC
Product number
B680398
Product name
4-Bromobenzhydrazide
Packaging
1g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
V2054
Product name
4-Bromobenzhydrazide
Packaging
25g
Price
$94
Updated
2021/12/16
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4-BROMOBENZHYDRAZIDE Chemical Properties,Usage,Production

Chemical Properties

Light beige powder

Uses

4-Bromobenzoic hydrazide has been used in the preparation of {2-[1-oxo-3-(4-bromophenyl)-2-propenyl]hydrazide}-4-bromobenzoic acid, {2,2?-[1,4-phenylenebis(1-oxo-2-propene-3,1-diyl)]dihydrazide}-p-bromobenzoic acid and substituted period[1,2-a]pyrimidine-2,4(3H)-diones (PPMDO).

Synthesis

To a 250 mL three-necked vial was added p-bromobenzoic acid (10.0 g, 49.75 mmol) and 100 mL Tetrahydrofuran, then add N,N'-carbonyl diimidazole (10.45g, 64.68mmol), TLC to monitor whether the raw material reaction is complete, after the reaction is complete, slowly add 80% hydrazine hydrate (4.93g, 78.77mmol) dropwise, dropwise, stirring the reaction for about 6 h. TLC to monitor whether the raw material reaction is complete (Expanding agent: petroleum ether /Ethyl acetate 1:1). After the reaction was completed, cooled to room temperature, concentrated under reduced pressure to remove most of the organic solvent, added about 30mL of water, pulsed at room temperature for a few moments, filtration, washed with water, resulting in a white flaky solid. After 15mL Anhydrous ethanol recrystallization yielded 9.09 g of white solid of Intermediate 3 in 85% yield. m.p. 166-167??C, consistent with literature values.

4-BROMOBENZHYDRAZIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMOBENZHYDRAZIDE Suppliers

Jinan Liheng Biotechnology Co., Ltd.
Tel
0531-18763987518 18763987518
Email
levi@lihengpharm.com
Country
China
ProdList
1797
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
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View Lastest Price from 4-BROMOBENZHYDRAZIDE manufacturers

Career Henan Chemical Co
Product
4-BROMOBENZHYDRAZIDE 5933-32-4
Price
US $1.00/kg
Min. Order
1g
Purity
99%
Supply Ability
100KG
Release date
2018-12-21

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