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Methyl 3-nitrobenzoate

Product Name
Methyl 3-nitrobenzoate
CAS No.
618-95-1
Chemical Name
Methyl 3-nitrobenzoate
Synonyms
AKOS B029800;RARECHEM AL BF 0189;METHYL M-NITROBENZOATE;METHYL 3-NITROBENZOATE;Methyle3-nitrobenzoate;3-Nitro Methyl Benzoate;4-Methyl-3-nitrobenzoate;Methyl3-Nitrobenzoate>Methyl meta-nitrobenzoate;4-Methyl M-Nitro-Benzoate
CBNumber
CB9778023
Molecular Formula
C8H7NO4
Formula Weight
181.15
MOL File
618-95-1.mol
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Methyl 3-nitrobenzoate Property

Melting point:
78-80 °C (lit.)
Boiling point:
279 °C (lit.)
Density 
1.4283 (rough estimate)
refractive index 
1.5468 (estimate)
Flash point:
279°C
storage temp. 
Sealed in dry,Room Temperature
form 
Crystalline Powder
color 
Beige
Water Solubility 
insoluble
BRN 
392449
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
AXLYJLKKPUICKV-UHFFFAOYSA-N
CAS DataBase Reference
618-95-1(CAS DataBase Reference)
NIST Chemistry Reference
3-O2N-C6H4-COOCH3(618-95-1)
EPA Substance Registry System
Benzoic acid, 3-nitro-, methyl ester (618-95-1)
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Safety

Safety Statements 
24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29163900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
155977
Product name
Methyl 3-nitrobenzoate
Purity
99%
Packaging
100g
Price
$138
Updated
2024/03/01
TCI Chemical
Product number
N0157
Product name
Methyl 3-Nitrobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$50
Updated
2024/03/01
TCI Chemical
Product number
N0157
Product name
Methyl 3-Nitrobenzoate
Purity
>98.0%(GC)
Packaging
500g
Price
$600
Updated
2024/03/01
Alfa Aesar
Product number
A15155
Product name
Methyl 3-nitrobenzoate, 98+%
Packaging
50g
Price
$31.65
Updated
2024/03/01
Alfa Aesar
Product number
A15155
Product name
Methyl 3-nitrobenzoate, 98+%
Packaging
250g
Price
$120
Updated
2024/03/01
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Methyl 3-nitrobenzoate Chemical Properties,Usage,Production

Chemical Properties

beige crystalline powder

Uses

Methyl 3-nitrobenzoate was used in the preparation of iodoarene.

Synthesis Reference(s)

Synthetic Communications, 22, p. 1851, 1992 DOI: 10.1080/00397919208021316
Chemical and Pharmaceutical Bulletin, 36, p. 481, 1988 DOI: 10.1248/cpb.36.481

Purification Methods

Crystallise the benzoate from MeOH (1g/mL). [Beilstein 9 H 378, 9 I 153, 9 II 248, 9 III 1493, 9 IV 1056.]

Methyl 3-nitrobenzoate Preparation Products And Raw materials

Raw materials

Nitric acid Methyl benzoate

Preparation Products

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Methyl 3-nitrobenzoate Suppliers

Americas 1 Belgium 3 China 152 Europe 1 Germany 7 India 19 Japan 3 Russia 1 Slovakia 1 Switzerland 2 The Netherlands 1 United Kingdom 9 United States 20 Global 220
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View Lastest Price from Methyl 3-nitrobenzoate manufacturers

Asia Chem I and E (Jiangsu) Co Ltd
Product
Methyl 3-nitrobenzoate 618-95-1
Price
US $43.26/Kg/Drum
Min. Order
25Kg/Drum
Purity
99.00%HPLC
Supply Ability
16tons/month
Release date
2021-11-09
Hebei Chuanghai Biotechnology Co,.LTD
Product
Methyl 3-nitrobenzoate 618-95-1
Price
US $30.00-10.00/kg
Min. Order
10kg
Purity
99%
Supply Ability
100000kg
Release date
2024-08-20
YANGZHOU SHUANGDING CHEM CO., LTD
Product
Methyl 3-nitrobenzoate 618-95-1
Price
US $0.00/Kg/Drum
Min. Order
200KG
Purity
99%
Supply Ability
100 tons/year
Release date
2020-11-30

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