TERT-BUTYL 3-BROMOBENZYLCARBAMATE

Product Name: TERT-BUTYL 3-BROMOBENZYLCARBAMATE
CAS No.: 171663-13-1
Chemical Name: TERT-BUTYL 3-BROMOBENZYLCARBAMATE
Synonyms: N-Boc-3-broMobenzylaMine;TERT-BUTYL 3-BROMOBENZYLCARBAMATE;1-(Boc-aMinoMethyl)-3-broMobenzene;tert-butyl N-[(3-bromophenyl)methyl]carbamate;(3-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER;N-[(3-Bromophenyl)methyl]-carbamic acid tert-butyl ester;N-[(3-Bromophenyl)Methyl]-Carbamic Acid 1,1-Dimethylethyl Ester;Carbamic acid, N-[(3-bromophenyl)methyl]-, 1,1-dimethylethyl ester
CBNumber: CB9823305
Molecular Formula: C12H16BrNO2
Formula Weight: 286.16
MOL File: 171663-13-1.mol

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TERT-BUTYL 3-BROMOBENZYLCARBAMATE Property

Melting point:: 59-60 °C
Boiling point:: 374.3±25.0 °C(Predicted)
Density: 1.319±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
form: solid
pka: 12.15±0.46(Predicted)
color: White

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Safety

Hazard Codes: Xn
Risk Statements: 22
HS Code: 2924297099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B678483
Product name: (3-Bromobenzyl)carbamicAcidtert-ButylEster
Packaging: 500mg
Price: $130
Updated: 2021/12/16

TRC

Product number: B678483
Product name: (3-Bromobenzyl)carbamicAcidtert-ButylEster
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Activate Scientific

Product number: AS26179
Product name: 1-(Boc-aminomethyl)-3-bromobenzene
Purity: 96+%
Packaging: 1g
Price: $86
Updated: 2021/12/16

Apolloscientific

Product number: OR962712
Product name: tert-Butyl3-bromobenzylcarbamate
Purity: 98%
Packaging: 5g
Price: $261
Updated: 2021/12/16

Activate Scientific

Product number: AS26179
Product name: 1-(Boc-aminomethyl)-3-bromobenzene
Purity: 96+%
Packaging: 5G
Price: $268
Updated: 2021/12/16

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TERT-BUTYL 3-BROMOBENZYLCARBAMATE Chemical Properties,Usage,Production

Synthesis

24424-99-5

39959-54-1

171663-13-1

The general procedure for the synthesis of 1-(Boc-aminomethyl)-3-bromobenzene from 3-bromobenzylamine hydrochloride and di-tert-butyl dicarbonate was as follows: to 250 mL of dichloromethane were added 25 g (110 mmol) of 3-bromobenzylamine hydrochloride and 24.5 g (110 mmol) of di-tert-butyl dicarbonate followed by 15.6 mL (110 mmol) of triethylamine. The reaction mixture was stirred at room temperature for 16 hours. Upon completion of the reaction, the reaction mixture was washed with water and the organic and aqueous phases were separated by sedimentation. The organic phase was dried over anhydrous sodium sulfate and the solvent was subsequently evaporated to give 32.4 g (100% yield) of tert-butyl (3-bromobenzyl)carbamate in crystalline form.

References

[1] Patent: US2009/12129, 2009, A1. Location in patent: Page/Page column 21
[2] Patent: WO2006/18325, 2006, A1. Location in patent: Page/Page column 28 - 29
[3] Patent: US2016/332999, 2016, A1. Location in patent: Paragraph 0420; 0421
[4] Patent: WO2018/5794, 2018, A2. Location in patent: Page/Page column 94
[5] Organic Process Research and Development, 2011, vol. 15, # 6, p. 1247 - 1255

TERT-BUTYL 3-BROMOBENZYLCARBAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL 3-BROMOBENZYLCARBAMATE Suppliers

China 62 India 1 United States 8 Global 71

Shandong Fande Pharmaceutical Technology Co., Ltd.

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Energy Chemical

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Beijing FYF Chemicals Co., Ltd

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View Lastest Price from TERT-BUTYL 3-BROMOBENZYLCARBAMATE manufacturers

Career Henan Chemical Co

Product: TERT-BUTYL 3-BROMOBENZYLCARBAMATE 171663-13-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2018-12-25

171663-13-1, TERT-BUTYL 3-BROMOBENZYLCARBAMATERelated Search:

tert-butyl 3-bromoazetidine-1-carboxylate 1-N-BOC-3-BROMOPIPERIDINE 3-BroMo-indazole-1-carboxylic acid tert-butyl ester TERT-BUTYL 3-BROMOMETHYL-INDOLE-1-CARBOXYLATE BOC-(S)-3-AMINO-3-(3-BROMO-PHENYL)-PROPIONIC ACID 3-(3-BROMO-PHENYL)-3-TERT-BUTOXYCARBONYLAMINO-PROPIONIC ACID TERT-BUTYL 7-BROMO-3,4-DIHYDROISOQUINOLINE-2(1H)-CARBOXYLATE 4-BOC-7-BROMO-1,2,3,5-TETRAHYDRO-BENZO[E][1,4]DIAZEPINE-3-CARBOXYLIC ACID 3-METHYL ESTER [(3-BROMO-4-FLUOROPHENYL)METHYL]-CARBAMIC ACID TERT-BUTYL ESTER 5-BROMO-3,4-DIHYDRO-1H-ISOQUINOLINE-2-CARBOXYLIC ACID TERT-BUTYL ESTER 4-BOC-7-BROMO-2,3,4,5-TETRAHYDRO-1H-BENZO[E][1,4]DIAZEPINE (R)-N-BOC-3-BROMO-BETA-PHENYLALANINE TERT-BUTYL 3-BROMOBENZYLCARBAMATE (S)-N-(TERT-BUTOXYCARBONYL)-3-AMINO-3-(3,5-DIBROMOPHENYL)PROPIONIC ACID (R)-2-(3-BROMO-PHENYL)-PIPERAZINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER 2-(3-BROMOPHENYL)PIPERAZINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER (3-bromophenyl)[(tert-butoxycarbonyl)amino]acetic acid (S)-(3-BROMO-PHENYL)-TERT-BUTOXYCARBONYLAMINO-ACETIC ACID

(3-BROMO-BENZYL)-CARBAMIC ACID TERT-BUTYL ESTER

1-(Boc-aMinoMethyl)-3-broMobenzene

N-Boc-3-broMobenzylaMine

Carbamic acid, N-[(3-bromophenyl)methyl]-, 1,1-dimethylethyl ester

TERT-BUTYL 3-BROMOBENZYLCARBAMATE

N-[(3-Bromophenyl)Methyl]-Carbamic Acid 1,1-Dimethylethyl Ester

tert-butyl N-[(3-bromophenyl)methyl]carbamate

N-[(3-Bromophenyl)methyl]-carbamic acid tert-butyl ester

171663-13-1

amine|alkyl bromide| carboxylic ester