9-(2-nitrovinyl)anthracene
- Product Name
- 9-(2-nitrovinyl)anthracene
- CAS No.
- 58349-77-2
- Chemical Name
- 9-(2-nitrovinyl)anthracene
- Synonyms
- Einecs 261-220-2;9-(2-nitrovinyl)anthracene;9-(2-Nitroethenyl)anthracene;Anthracene,9-(2-nitroethenyl)-;(E)-9-(2-Nitrovinyl)anthracene
- CBNumber
- CB9883909
- Molecular Formula
- C16H11NO2
- Formula Weight
- 249.26
- MOL File
- 58349-77-2.mol
9-(2-nitrovinyl)anthracene Property
- storage temp.
- 2-8°C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- A245447
- Product name
- 9-(2-Nitrovinyl)anthracene
- Purity
- 97%
- Packaging
- 100mg
- Price
- $59
- Updated
- 2021/12/16
- Product number
- A245447
- Product name
- 9-(2-Nitrovinyl)anthracene
- Purity
- 97%
- Packaging
- 250mg
- Price
- $87
- Updated
- 2021/12/16
- Product number
- A245447
- Product name
- 9-(2-Nitrovinyl)anthracene
- Purity
- 97%
- Packaging
- 1g
- Price
- $235
- Updated
- 2021/12/16
- Product number
- CD12058635
- Product name
- 9-(2-Nitrovinyl)anthracene
- Purity
- 97%
- Packaging
- 1g
- Price
- $270
- Updated
- 2021/12/16
- Product number
- 61-10481
- Product name
- 9-(2-Nitrovinyl)anthracene
- Purity
- 95-98%
- Packaging
- 1g
- Price
- $315
- Updated
- 2021/12/16
9-(2-nitrovinyl)anthracene Chemical Properties,Usage,Production
Synthesis
75-52-5
642-31-9
58349-77-2
GENERAL METHOD: 9-Anthracenecarboxaldehyde (1; 2.06 g, 10 mmol) was dissolved in anhydrous dichloromethane (20 mL). To this solution nitromethane (559 μL, 10 mmol) and piperidine (202 μL, 2 mmol) were added sequentially. The reaction mixture was heated to reflux and maintained for 8 hours. After completion of the reaction, it was cooled to room temperature and a red solid precipitated. The solid product was collected by filtration and washed with hexane (20 mL) to afford the target compound 9-(2-nitrovinyl)anthracene (1.70 g, 68% yield) as a red solid. Compound Registry Number: 55446-60-1; Thin Layer Chromatography Rf value = 0.56 (Expanding Agent Ratio: Hexane:Ethyl Acetate = 80:20); 1H NMR (CDCl3, 300 MHz) δ = 7.49-7.65 (m, 5H, aromatic hydrogens and -CH=CHNO2), 8.07 (d, J=7.9 Hz, 2H, aromatic hydrogens), 8.20 (d, J=8.8 Hz, 2H, aromatic hydrogen), 8.56 (s, 1H, H-10), 9.03 (d, J=13.8 Hz, 1H, -CH=CHNO2). Ref: Becker, H.D.; Soerensen, H.; Sandros, K. J. Org. Chem. 1986, 51, 3223-3226.
References
[1] Tetrahedron Letters, 2013, vol. 54, # 32, p. 4306 - 4308
[2] Doklady Chemistry, 1975, vol. 225, p. 681 - 684
[3] Dokl. Akad. Nauk SSSR Ser. Khim., 1975, vol. 225, # 6, p. 1323 - 1326
[4] Inorganica Chimica Acta, 2015, vol. 426, p. 119 - 125
[5] Synthetic Communications, 2017, vol. 47, # 6, p. 551 - 556
9-(2-nitrovinyl)anthracene Preparation Products And Raw materials
Raw materials
Preparation Products
9-(2-nitrovinyl)anthracene Suppliers
- Tel
- --
- Fax
- --
- sales@combi-blocks.com
- Country
- United States
- ProdList
- 6618
- Advantage
- 69
- Tel
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- Fax
- --
- sales@matrixscientific.com
- Country
- United States
- ProdList
- 6632
- Advantage
- 80
View Lastest Price from 9-(2-nitrovinyl)anthracene manufacturers
- Product
- 9-(2-nitrovinyl)anthracene 58349-77-2
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99.0%
- Supply Ability
- 100kg
- Release date
- 2020-01-09