2-Methylfurane-5-boronic acid pinacol ester

Product Name: 2-Methylfurane-5-boronic acid pinacol ester
CAS No.: 338998-93-9
Chemical Name: 2-Methylfurane-5-boronic acid pinacol ester
Synonyms: 5-Methylfuran-2-boronic acid p;5-Methyl-2-furanboronic acid pinacol ester;2-Methylfurane-5-boronic acid pinacol ester;5-Methylfuran-2-boronic acid pinacol ester 95%;(5-Methylfuran-2-yl)boronic Acid Pinacol Ester;2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan;2-(5-Methyl-2-furanyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(5-methyl-2-furanyl)-;5-Methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxoborolan-2-yl)furan, 2-(5-Methylfur-2-yl)-4,4,5;5-Methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxoborolan-2-yl)furan, 2-(5-Methylfur-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CBNumber: CB9969126
Molecular Formula: C11H17BO3
Formula Weight: 208.06
MOL File: 338998-93-9.mol

More

Less

2-Methylfurane-5-boronic acid pinacol ester Property

Melting point:: 217°
Boiling point:: 277.8±28.0 °C(Predicted)
Density: 1.023 g/mL at 25 °C
refractive index: n20/D1.476
storage temp.: 2-8°C
form: clear liquid
color: Light yellow to Yellow to Orange

More

Less

Safety

WGK Germany: 3
HS Code: 2932190090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 680109
Product name: 5-Methyl-2-furanboronic acid pinacol ester
Purity: 95%
Packaging: 1g
Price: $64.6
Updated: 2023/06/20

Sigma-Aldrich

Product number: 680109
Product name: 5-Methyl-2-furanboronic acid pinacol ester
Purity: 95%
Packaging: 10g
Price: $242
Updated: 2022/05/15

TCI Chemical

Product number: T3582
Product name: 4,4,5,5-Tetramethyl-2-(5-methylfuran-2-yl)-1,3,2-dioxaborolane
Purity: >97.0%(GC)(T)
Packaging: 1g
Price: $27
Updated: 2025/07/31

TCI Chemical

Product number: T3582
Product name: 4,4,5,5-Tetramethyl-2-(5-methylfuran-2-yl)-1,3,2-dioxaborolane
Purity: >97.0%(GC)(T)
Packaging: 5g
Price: $80
Updated: 2025/07/31

TRC

Product number: M226385
Product name: 5-Methyl-2-furanboronic acid pinacol ester
Packaging: 10g
Price: $275
Updated: 2021/12/16

More

Less

2-Methylfurane-5-boronic acid pinacol ester Chemical Properties,Usage,Production

Uses

5-Methyl-2-furanboronic Acid Pinacol Ester is used as a reagent for the borylation of furans, pyrroles and other organic reactions.

Synthesis

534-22-5

25015-63-8

338998-93-9

The general procedure for the synthesis of 2-methylfuran-5-boronic acid pinacol ester from 2-methylfuran and pinacolborane is as follows: according to the reaction scheme for the boronation of Example 9-aromatic five-membered heterocyclic rings (Fig. 2a), to a scintillation vial fitted with a magnetic stirring bar were added a cobalt complex of 1-4,2-methylfuran (0.01 mmol), 2-methylfuran (1 mmol) and pinacolborane ( 1 mmol). The reaction process was monitored by analyzing an aliquot of the mixture by GC-FID. The reaction mixture was stirred at room temperature until the reaction was complete and subsequently quenched by exposure to air. The resulting solid was dissolved in CDCl3 and filtered through a Pasteur pipette fitted with a silicone plug, followed by 1H and 13C NMR spectroscopy without further purification. If the reaction conditions need to be adjusted, the above reaction can be carried out in 2 ml of tetrahydrofuran (THF). Figure 2(a) demonstrates the percentage conversion of cobalt complexes 1-4, and the values in parentheses are the isolated yields. In addition, Figure 2(b) describes in detail the other boronation products achieved using cobalt complexes 2 and 3 according to the aforementioned reaction parameters.

References

[1] Patent: WO2015/89119, 2015, A1. Location in patent: Page/Page column 34
[2] ACS Catalysis, 2018, vol. 8, # 6, p. 5017 - 5022
[3] Journal of the American Chemical Society, 2014, vol. 136, # 11, p. 4133 - 4136
[4] Chemistry - An Asian Journal, 2010, vol. 5, # 7, p. 1657 - 1666
[5] Science, 2015, vol. 349, # 6247, p. 513 - 516

2-Methylfurane-5-boronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

2-Methylfurane-5-boronic acid pinacol ester Suppliers

China 88 Germany 1 India 4 Japan 1 United Kingdom 1 United States 16 Global 111

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Pure Chemistry Scientific Inc.

Tel: 001-857-928-2050 or 1-888-588-9418
Fax: 001-617-206-9595
Email: sales@chemreagents.com
Country: United States
ProdList: 10186
Advantage: 62

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Aemon Chemical

Tel: 0086-755-86198205
Email: acinfo@aemonchem.com
Country: China
ProdList: 1931
Advantage: 57

Beijing Yisiyan Technology Research Center

Tel: 010-56645598 13366904824
Fax: 01062230033
Email: bjkaida@163.com
Country: China
ProdList: 1618
Advantage: 59

Shanghai Litong Chemical Technology Co.,Ltd.

Tel: 13598610367 0373-7129549
Fax: 0373-8369699
Email: 2468833170@qq.com
Country: China
ProdList: 932
Advantage: 58

More

Less

View Lastest Price from 2-Methylfurane-5-boronic acid pinacol ester manufacturers

Career Henan Chemical Co

Product: 2-Methylfurane-5-boronic acid pinacol ester 338998-93-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-01

338998-93-9, 2-Methylfurane-5-boronic acid pinacol esterRelated Search:

Propyleneglycol alginate EPA 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate 2-Methylfuran Dimethyl succinate Methyl acrylate Bis(pinacolato)diboron Tris(trimethylsilyl)phosphate 3-Furanboronic acid 5-METHYLFURAN-2-BORONIC ACID 2-Furanboronic acid pinacol ester 2-Furanboronic acid 2-Methylfurane-5-boronic acid pinacol ester

2-Methylfurane-5-boronic acid pinacol ester

5-Methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxoborolan-2-yl)furan, 2-(5-Methylfur-2-yl)-4,4,5

5-Methyl-2-furanboronic acid pinacol ester

5-Methylfuran-2-boronic acid p

5-Methylfuran-2-boronic acid pinacol ester 95%

5-Methyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxoborolan-2-yl)furan, 2-(5-Methylfur-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(5-Methyl-2-furanyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(5-methyl-2-furanyl)-

(5-Methylfuran-2-yl)boronic Acid Pinacol Ester

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan

338998-93-9