2-Furanboronic acid pinacol ester

Product Name: 2-Furanboronic acid pinacol ester
CAS No.: 374790-93-9
Chemical Name: 2-Furanboronic acid pinacol ester
Synonyms: AKOS BRN-1103;2-DIOXABOROLAN-2-YL)FURAN;2-furylboronic acid pinacol ester;2-Furanboronic acid pinacol ester;FURAN-2-BORONIC ACID PINACOL ESTER;FURAN-2-BORONIC ACID PINACOL CYCLIC ESTER;2-(2-FURYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;2'-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan;2-(2-Furanyl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane;2-(furan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CBNumber: CB9694527
Molecular Formula: C10H15BO3
Formula Weight: 194.04
MOL File: 374790-93-9.mol

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2-Furanboronic acid pinacol ester Property

Boiling point:: 255.0±13.0 °C(Predicted)
Density: 1.03±0.1 g/cm3(Predicted)
refractive index: 1.473-1.475
storage temp.: Inert atmosphere,2-8°C
Appearance: Colorless to light yellow Solid-Liquid Mixture
BRN: 9045028
CAS DataBase Reference: 374790-93-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,T
Risk Statements: 22-36/37/38-25
Safety Statements: 24/25-37/39-26-45
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

TRC

Product number: B414268
Product name: 2-(Furan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Packaging: 50mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: 7245CS
Product name: Furan-2-boronicacidpinacolester
Packaging: 1g
Price: $47
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6H60-1-1Y
Product name: Furan-2-boronic acid, pinacol ester
Purity: 98%
Packaging: 5G
Price: $136
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0001693
Product name: FURAN-2-BORONIC ACID PINACOL ESTER
Purity: 95.00%
Packaging: 1G
Price: $163.8
Updated: 2021/12/16

AK Scientific

Product number: J57387
Product name: Furan-2-boronicacidpinacolester
Packaging: 5g
Price: $95
Updated: 2021/12/16

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2-Furanboronic acid pinacol ester Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to pale yellow liquid

Synthesis

584-12-3

61676-62-8

374790-93-9

The general procedure for the synthesis of 2-(2-furyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane from 2-bromofuran and isopropanol pinacol borate was as follows: at -78 °C, a hexane solution of n-butyllithium (n-BuLi, 1.6 M, 65 mL, 0.10 mol) was slowly added to a 2-bromofuran (11 g, 0.068 mol) tetrahydrofuran (THF, 200 mL) solution. The reaction mixture was stirred at 0 °C for 2 hours. Subsequently, the reaction mixture was slowly added to a solution of 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (13 g, 0.068 mol) in THF (150 mL) at the same temperature. The mixture was gradually warmed to room temperature and stirred overnight. Upon completion of the reaction, a small amount of methanol was added to quench the reaction. The resulting solution was washed three times with water and the organic phase was dried over anhydrous sodium sulfate and subsequently concentrated under reduced pressure. The crude product was purified by silica gel column chromatography using hexane as eluent to afford the target product 2-(2-furyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane.

References

[1] Polymer, 2012, vol. 53, # 20, p. 4380 - 4387

2-Furanboronic acid pinacol ester Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Furanboronic acid pinacol ester Suppliers

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View Lastest Price from 2-Furanboronic acid pinacol ester manufacturers

Career Henan Chemical Co

Product: 2-Furanboronic acid pinacol ester 374790-93-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-14

374790-93-9, 2-Furanboronic acid pinacol esterRelated Search:

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2-furylboronic acid pinacol ester

AKOS BRN-1103

2'-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan

2-(2-FURYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE

2-Furylboronic acid pinacol ester~2-(2-Furyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-Furanboronic acid pinacol ester

FURAN-2-BORONIC ACID PINACOL CYCLIC ESTER

FURAN-2-BORONIC ACID PINACOL ESTER

2'-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)furan,97%

2-(furan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-DIOXABOROLAN-2-YL)FURAN

2-(2-Furanyl)-4,4,5,5-tetraMethyl-1,3,2-dioxaborolane

4,4,5,5-tetraMethyl-2-(furanyl-2-yl)-1,3,2-dioxaborolane

1,3,2-Dioxaborolane, 2-(2-furanyl)-4,4,5,5-tetramethyl-

374790-93-9

BORONIC ACID