BENZAL CHLORIDE Chemical Properties

Melting point:

-16 °C

Boiling point:

207 °C

Density 

1.254

vapor pressure 

60Pa at 25℃

refractive index 

1.5500

Flash point:

92°C

Water Solubility 

Insoluble in water

solubility 

Chloroform (Soluble), Methanol (Slightly)

form 

clear liquid

color 

Very refractive liquid

Merck 

14,1057

BRN 

1099407

Dielectric constant

6.9（20℃）

Stability:

Stable, but moisture sensitive. Combustible. Incompatible with strong bases, strong oxidizing agents, most metals. Readily hydrolyzes in acidic or basic conditions.

LogP

2.97

CAS DataBase Reference

98-87-3(CAS DataBase Reference)

IARC

2A (Vol. 29, Sup 7, 71) 1999

EPA Substance Registry System

Benzal chloride (98-87-3)

Safety Information

Hazard Codes 

T

Risk Statements 

22-23-37/38-40-41

Safety Statements 

23-26-36/37/39-45-38-36/37

RIDADR 

1886

RTECS 

CZ5075000

HazardClass 

6.1

PackingGroup 

II

HS Code 

29036990

Hazardous Substances Data

98-87-3(Hazardous Substances Data)

Toxicity

LD50 orl-rat: 3249 mg/kg NTIS** PB214-270

MSDS

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BENZAL CHLORIDE Usage And Synthesis

Description

Benzal chloride (dichloromethylbenzene, a,adichlorotoluene, benzylidene chloride) is produced exclusively by the side-chain chlorination of toluene. It was first synthesized in 1848 by A. CAHOURS, by using the reaction of PCl5 with benzaldehyde. Almost the sole application of benzal chloride is in the production of benzaldehyde.

Chemical Properties

colourless oily liquid

Chemical Properties

Benzal chloride is a combustible, fuming, colorless, oily liquid; fumes on exposure to air. Faint, pungent odor.

Physical properties

Benzal chloride is a liquid which fumes in moist air and which has a pungent odor and a strong irritant effect on the mucous membranes and eyes.Benzal chloride is freely soluble in alcohol, ether, chloroform, and carbon tetrachloride, but only slightly soluble in water (0.05 g/L at 5 ℃; 0.25 g/L at 39 ℃). The solubility of chlorine in 100 g of benzal chloride is 6.2 g at 30 ℃, 4.3 g at 50 ℃, 1.5 g at 100 ℃.

Uses

manufacture of benzaldehyde, cinnamic acid.

Uses

α,α-Dichlorotoluene has been useds as initiator during the atom transfer radical polymerization (ATRP) of styrene and methyl methacrylate.

Definition

ChEBI: Benzal chloride is a member of benzenes.

Synthesis Reference(s)

The Journal of Organic Chemistry, 15, p. 795, 1950 DOI: 10.1021/jo01150a012
Tetrahedron Letters, 9, p. 4951, 1968

General Description

A colorless oily liquid with a faint aromatic odor. Insoluble in water and denser than water. Strongly irritates skin and eyes. Used to manufacture dyes.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

BENZAL CHLORIDE is incompatible with strong oxidizers and strong bases. BENZAL CHLORIDE readily hydrolyzes under acid or alkaline conditions. BENZAL CHLORIDE reacts with metals (except nickel and lead). .

Hazard

Strong irritant and lachrymator. Probable carcinogen.

Health Hazard

Acute: vapors are highly irritating to eyes. May be fatal if inhaled, swallowed, or absorbed through skin.

Fire Hazard

Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases and may cause pollution. Cylinder may explode in the heat of fire. Reacts with water to release hydrochloric acid.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Poison by inhalation. Moderately toxic by ingestion. A strong irritant and lachrymator. Causes central nervous system depression. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, AROMATIC.

Potential Exposure

Benzal chloride is used almost exclusively for the manufacture of benzaldehyde. It can also be used to prepare cinnamic acid and benzoyl chloride.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24
48 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers,strong acids, flammable materials, sources fire as this material is combustible. Sources of ignition, such as smokingand open flames, are prohibited where this chemical isused, handled, or stored in a manner that could create apotential fire or explosion hazard.

Shipping

UN1886 Benzylidene chloride, Hazard class 6.1; Label 6.1—Poisonous materials.

Incompatibilities

May form explosive mixture with air. Reacts with water, air, or heat, forming fumes of hydrochloric acid. Reacts (possibly violently) with acids, bases, strong oxidizers; many metals; potassium, sodium, aluminum. Attacks plastics and coatings.

Waste Disposal

Incineration @ 816 C, 0.5 second minimum for primary combustion; 1204 C, 1.0 second for secondary combustion; elemental chlorine formation may be alleviated through injection of steam or methane into the combustion process.

BENZAL CHLORIDE(98-87-3)Related Product Information

• Diphenyldichloromethane
• 3-FLUOROBENZOTRICHLORIDE
• ALPHA,ALPHA,ALPHA,ALPHA',ALPHA',ALPHA'-HEXACHLORO-M-XYLENE
• 2-CHLORO-6-FLUOROBENZOTRICHLORIDE
• 2-FLUOROBENZAL CHLORIDE
• alpha,alpha,alpha',alpha'-Tetrachloro-p-xylene
• 3-(DICHLOROMETHYL)BENZOYL CHLORIDE
• 4-FLUOROBENZOTRICHLORIDE
• 9,9-DICHLOROFLUORENE
• 2-Chlorobenzotrichloride
• 4-FLUOROBENZAL CHLORIDE
• ALPHA,ALPHA,2-TRICHLORO-6-FLUOROTOLUENE
• 2,4-DICHLOROBENZOTRICHLORIDE
• 3,4-Dichlorobenzotrichloride
• BENZAL CHLORIDE
• 4-Chlorobenzotrichloride
• Benzotrichloride
• 2-FLUOROBENZOTRICHLORIDE