Basic information Safety Supplier Related

N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMide

Basic information Safety Supplier Related

N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMide Basic information

Product Name:
N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMide
Synonyms:
  • N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMide
  • 3-[[(1R,2R)-2-(1-piperidinyl)cyclohexyl]aMino]-4-[[4-(trifluoroMethyl)phenyl]aMino]-3-Cyclobutene-1,2-dione
  • Rawal Squaramide Organocatalyst
  • N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N'-[4-(trifluoromethyl)phenyl]squaramide 95%
  • 3-[[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]amino]-4-[[4- (trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione,99%e.e.
  • 3-[[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]amino]-4-[[4-(trifluoromethyl)phenyl]amino]-3-cyclobutene-1,2-dione, 98%, (99% ee)
  • 3-Cyclobutene-1,2-dione, 3-[[(1R,2R)-2-(1-piperidinyl)cyclohexyl]amino]-4-[[4-(trifluoromethyl)phenyl]amino]-
  • 3-(((1R,2R)-2-(Piperidin-1-yl)cyclohexyl)amino)-4-((4-(trifluoromethyl)phenyl)amino)cyclobut-3-ene-1,2-dione
CAS:
1211565-08-0
MF:
C22H26F3N3O2
MW:
421.46
Mol File:
1211565-08-0.mol
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N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMide Chemical Properties

Melting point:
250 °C (decomp)
Boiling point:
497.4±55.0 °C(Predicted)
Density 
1.31±0.1 g/cm3(Predicted)
pka
8.97±0.20(Predicted)
optical activity
[α]/D -42.0±2.0°, c = 1 in DMSO
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Safety Information

Hazard Codes 
C
Risk Statements 
37/38-41
Safety Statements 
26-39
WGK Germany 
3
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N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMide Usage And Synthesis

Uses

It can act as a catalyst for the asymmetric tandem aza-Michael addition-protonation between 1-nitro cyclohexene and 4-methoxyaniline to form the corresponding α-arylamino-β-nitro cyclohexane in a 35:65 trans/cis mixture.

N-[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]-N′-[4-(trifluoroMethyl)phenyl]squaraMideSupplier

Adamas Reagent, Ltd. Gold
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400-6009262 16621234537
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chenyj@titansci.com
Daicel Chiral Technologies (China)CO.,LTD
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021-50460086-9 15921403865
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han_yajun@dctc.daicel.com
Sigma-Aldrich
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021-61415566 800-8193336
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Shanghai Chiral bio-compound co., Ltd.
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021-5068 3667/17749785980/1029026415; 17749785980
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1029026415@qq.com
LaaJoo
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021-60702684 18516024827
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huang.jiayi@sinocompound.com