1,2,4-Benzenetriamine dihydrochloride
1,2,4-Benzenetriamine dihydrochloride Basic information
- Product Name:
- 1,2,4-Benzenetriamine dihydrochloride
- Synonyms:
-
- 1,2,4-Benzenetriamine 2HCL
- 1,2,4-TRIAMINOBENZENE 2HCL
- 1,2,4-Benzenetriamine dihydrochloride, pract., 99%
- benzene-1,2,4-triyltriamine dihydrochloride
- 1,2,4-Benzenetriamine dihydrochloride,99%,pract.
- Benzene-1,2,4-triaMine 2HCl
- benzene-1,2,4-triaMine dihydrochloride
- 1,2,4-BENZENETRIAMINE DIHYDROCHLORIDE PRACT., 99% (TITR.)
- CAS:
- 615-47-4
- MF:
- C6H10ClN3
- MW:
- 159.62
- EINECS:
- 210-428-1
- Product Categories:
-
- Furans ,Coumarins
- Anilines, Aromatic Amines and Nitro Compounds
- Benzene derivates
- Mol File:
- 615-47-4.mol
1,2,4-Benzenetriamine dihydrochloride Chemical Properties
- Melting point:
- 290°C
- storage temp.
- Hygroscopic, -20°C Freezer, Under inert atmosphere
- solubility
- slightly soluble
- form
- Solid
- color
- Dark Brown to Black
- Water Solubility
- slightly soluble
- Sensitive
- Hygroscopic
- Stability:
- Hygroscopic
- CAS DataBase Reference
- 615-47-4(CAS DataBase Reference)
- EPA Substance Registry System
- 1,2,4-Benzenetriamine, dihydrochloride (615-47-4)
MSDS
- Language:English Provider:1,2,4-Triaminobenzene dihydrochloride
- Language:English Provider:ACROS
- Language:English Provider:ALFA
1,2,4-Benzenetriamine dihydrochloride Usage And Synthesis
Uses
1,2,4-Triaminobenzene Dihydrochloride is a useful reagent for making multicolor fluorescent carbon dots that can be detected via white-light-emitting diodes and water.
Synthesis
(1) Using m-dichlorobenzene as raw material, dropwise addition at low temperature and high temperature nitration in a mixed acid system of concentrated sulfuric acid and fuming nitric acid to obtain 1,3-dichloro-4,6-dinitrobenzene;
(2) 1 ,3-Dichloro-4,6-dinitrobenzene is placed in a high-pressure reactor in the presence of ammonia water, and the temperature is raised to 145~150 ℃ for ammonolysis reaction to obtain 4,6-dinitro-1,3-benzenediol Amine;
(3) Place 4,6-dinitro-1,3-phenylenediamine, oxygen-free distilled water and palladium-carbon catalyst in a hydrogenation autoclave, and catalyze it under a hydrogen atmosphere of 1-1.5MPa and 85°C After the hydrogenation reaction, the catalyst was removed by hot filtration under nitrogen protection to obtain a 1,2,4-triaminobenzene hydrochloric acid solution;
(4) take the 1,2,4,5-tetraaminobenzene obtained in step (3) The solution was added with concentrated hydrochloric acid, cooled to room temperature, filtered under nitrogen protection, and the filter cake was dried in a vacuum desiccator at 40°C to obtain 1,2,4-triaminobenzene hydrochloric acid.
The molar ratio of m-dichlorobenzene to fuming nitric acid described in the step (1) is 2.2:1, the mass ratio of concentrated sulfuric acid to fuming nitric acid is 3:8~10, and the dropping temperature is -5~0°C, The nitration temperature is 100-104°C.
The reaction time of the ammonolysis described in step (2) is 3.5~4h, and the molar ratio of 1,3-dichloro-4,6-dinitrobenzene to ammonia water is 1:(10~14).
The oxygen-free distilled water described in step (3) is distilled water purified by nitrogen, and the reaction time of catalytic hydrogenation is 3-4h; 4,6-dinitro-1,3-phenylenediamine, palladium-carbon catalyst and oxygen-free The mass ratio of the three distilled water is 1:0.05:10.
The volume ratio of the 1,2,4-triaminobenzene hydrochloric acid solution described in step (4) to concentrated hydrochloric acid is 1:0.2-0.3.
Description
1,2,4-Triaminobenzene hydrochloride is an aromatic triamine with a relatively simple structure. Compared with triaminopyridine, it is easier to synthesize and realize industrialization. To a certain extent, it can replace TAP and 2,5-dihydroxyterephthalene. Formic acid (DHTA) for polymerization.
Chemical Properties
PURPLE POWDER
Uses
1,2,4-triaminobenzene hydrochloride can be used as a co-doping reagent, aconitic acid-based fluorescent carbon nanomaterials with high quantum yield can be prepared, and controll the emission wavelength.
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1,2,4-Benzenetriamine dihydrochloride(615-47-4)Related Product Information
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- 1,2,4-Benzenetriamine dihydrochloride