NITROMETHANE-D3 Chemical Properties

Melting point:

-29°C

Boiling point:

100 °C(lit.)

Density 

1.183 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.3795(lit.)

Flash point:

95 °F

storage temp. 

Store at +15°C to +25°C.

solubility 

117g/l

form 

Liquid

color 

Colorless

explosive limit

7.1-63%(V)

Sensitive 

Hygroscopic

BRN 

1751076

Exposure limits

ACGIH: TWA 20 ppm
OSHA: TWA 100 ppm(250 mg/m3)
NIOSH: IDLH 750 ppm

Stability:

May detonate if sensitized by amines, alkalies, strong acids, high temperatures or adiabatic compression. The dry alkali or amine salts are shock-sensitive and the sodium salt ignites on contact with water. Flammable. Incompatible with amines, strong acids, strong bases, strong oxidizing agents, strong reducing agents, copper, copper alloys,

CAS DataBase Reference

13031-32-8(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

5-10-22-2005/10/22

Safety Statements 

41

RIDADR 

UN 1261 3/PG 2

WGK Germany 

3

F 

10

TSCA 

Yes

HazardClass 

3

PackingGroup 

II

HS Code 

28459000

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

NITROMETHANE-D3 Usage And Synthesis

Chemical Properties

colourless liquid

Definition

ChEBI: Nitromethane-d3 is a deuterated compound, a primary nitroalkane and a volatile organic compound.

General Description

Nitromethane-d₃ is a deuterated derivative of nitromethane. Its pyrolytic decomposition in the absence and presence of nitrogen dioxide have been studied. Molecular structure studies suggest that its molecule is composed of a highly asymetrical top consisting of a heavy planar frame of NO₂ (C_2v symmetry) and a lighter top of CD₃ (C_3v symmetry). Rotational constants, high-resolution Fourier transform infrared (FTIR) spectrum and DFT (Density Functional Theory) calculations of nitromethane-d₃ have been evaluated. Various physicochemical properties (densities, viscosities, speed of sound and refractive indices) of CD₃NO₂ have been evaluated in the temperature range of 293K to 308K.

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