CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Basic information
- Product Name:
- CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
- Synonyms:
-
- CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
- CIS-6-AMINO-CYCLOHEX-3-ENECARBOXYLIC ACID
- cis-2-Amino-4-cyclohexene-1-carboxylic acid, 98+%
- 3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-rel-(9CI)
- 3-Cyclohexene-1-carboxylic acid, 6-amino-, (1R,6S)-rel-
- CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID USP/EP/BP
- 6-Aminocyclohex-3-ene-COOH(S,R)
- (1S,6R)-6-aminocyclohex-3-ene-1-carboxylic acid
- CAS:
- 54162-90-2
- MF:
- C7H11NO2
- MW:
- 141.17
- Product Categories:
-
- AMINOACID
- Mol File:
- 54162-90-2.mol
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Chemical Properties
- Melting point:
- 196-199 °C
- Boiling point:
- 258.21°C (rough estimate)
- Density
- 1.1522 (rough estimate)
- refractive index
- 1.5026 (estimate)
- CAS DataBase Reference
- 54162-90-2
Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-20/21/22-43
- Safety Statements
- 36/37/39-26-36/37
- HS Code
- 2922498590
MSDS
- Language:English Provider:ACROS
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID Usage And Synthesis
Chemical Properties
BEIGE FINE POWDER
Purification Methods
Purify the free amino-acid by dissolving it in H2O and passing it through a Dowex 50W (acid form) column and eluting with 1M aqueous NH4OH. The eluate is evaporated (in vacuo) and the residue is dissolved in H2O. Me2CO is added to turbidity, cooled at 0o and the colourless crystals of the amino-acid are collected and dried in vacuo [Bernáth et al. Tetrahedron 41 1315 1958, cf Mazza & Crapetta Gazzetta 57 297 1927]. In earlier work, it was recrystallised from aqueous EtOH and had reported melting points of 265-265o [Kricheldorf Justus Liebigs Ann Chem 1378 1975] and 269-271o [Marconi & Mazzochi J Org Chem 31 1372 1966]. The hydrochloride [57266-56-5] M 177.6 has m 210-213o and the methyl ester hydrochloride [52766-61-2] has m 85-87o (from Et2O). The trans-(±)-(1RS,2RS)-amino-acid [97945-19-2] crystallises from aqueous Me2CO with m 267-269o. [Beilstein 14 II 203.]
CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACIDSupplier
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CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID(54162-90-2)Related Product Information
- Cyclohexene
- cis-2-Amino-4-cyclohexene-1-carboxylic acid hydrochloride,cis-6-Amino-3-cyclohexene-1-carboxylic acid hydrochloride
- (1S,2R)-(-)-2-AMINO-1-CYCLOHEX-4-ENECARBOXYLIC ACID HYDROCHLORIDE
- 3-EXO-(BENZYLOXYCARBONYLAMINO)BICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLIC ACID
- BOC-3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLIC ACID
- CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLIC ACID
- FMOC-3-EXO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-EXO-CARBOXYLIC ACID
- (1S,2S,3R,4R)-(+)-3-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLIC ACID HYDROCHLORIDE
- DIENDO-3-AMINO-BICYCLO[2.2.1]HEPT-5-ENE-2-CARBOXYLIC ACID ETHYL ESTER
- ETHYL CIS-2-AMINO-4-CYCLOHEXENE-1-CARBOXYLATE HYDROCHLORIDE
- 3-ENDO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-ENDO-CARBOXYLIC ACID
- ETHYL 3-ENDO-AMINOBICYCLO[2.2.1]HEPT-5-ENE-2-ENDO-CARBOXYLATE HYDROCHLORIDE
- Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 3-amino-, (1R,2R,3S,4S)- (9CI)