Basic information Reactions Safety Supplier Related

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE

Basic information Reactions Safety Supplier Related

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Basic information

Product Name:
(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
Synonyms:
  • (R,R)-ME-DUPHOS-RH
  • (S,S)-ME-DUPHOS-RH
  • (-)-1,2-BIS-((2R,5R)DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE
  • (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • (+)-1,2-BIS((2S,5S)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) TRIFLATE
  • (-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • (-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE
  • (-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfon
CAS:
136705-75-4
MF:
C27H40F3O3P2RhS
MW:
666.52
Product Categories:
  • Chiral Catalysts, Ligands, and Reagents
  • DuPhos/BPE
  • Privileged Ligands and Complexes
  • organometallic complex
Mol File:
136705-75-4.mol
More
Less

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Chemical Properties

Melting point:
136.0-154.7 °C
storage temp. 
Refrigerator (+4°C)
form 
crystal
color 
orange
Sensitive 
air sensitive, store cold
CAS DataBase Reference
136705-75-4
More
Less

Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
24/25-36/37-26
WGK Germany 
3

MSDS

  • Language:English Provider:ACROS
More
Less

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE Usage And Synthesis

Reactions

Catalyst for the enantioselective [2+2+2] cycloaddition of triynes.

Chemical Properties

orange crystalline powder

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(-)-1,2(2R,5R)-2,5-(DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATESupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
Energy Chemical
Tel
021-021-58432009 400-005-6266
Email
sales8178@energy-chemical.com
Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Email
han_yajun@dctc.daicel.com
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Email
product02@bidepharm.com