Potassium trifluoromethanesulfonate Chemical Properties

Melting point:

238.5°C

storage temp. 

Inert atmosphere,Room Temperature

form 

solid

color 

White to Almost white

Water Solubility 

Soluble in water.

Sensitive 

Hygroscopic

Hydrolytic Sensitivity

6: forms irreversible hydrate

BRN 

3727495

InChI

InChI=1S/CHF3O3S.K/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChIKey

GLGXXYFYZWQGEL-UHFFFAOYSA-M

SMILES

C(F)(F)(F)S([O-])(=O)=O.[K+]

CAS DataBase Reference

2926-27-4(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,C

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

F 

3-10

TSCA 

No

HazardClass 

CORROSIVE

HS Code 

29049090

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Potassium trifluoromethanesulfonate Usage And Synthesis

Chemical Properties

white crystals or crystalline powder

Uses

Potassium trifluoromethanesulfonate is used as a reagent in the synthesis of guanine-quadruplex hybrid materials. It acts as a supporting electrolyte in the electrochemical study of evidence for gold anion in ethylenediamine. It is involved in the preparation of N-fluoro-2,4,6-trimethylpyridinium triflate by reacting with 2,4,6-trimethyl-pyridine. Further, it is used in the preparation of imidazolium salt, 3-methyl-1-(3R,3aR,6S,6aR)-[6-(benzyloxy)-hexahydrofuro[3,2-b]furan-3-yl]imidazolium trifluoromethanesulfonate.

Uses

Potassium trifluoromethanesulfonate is used in studies of mixed alkali effects and short range interactions in poly(ethylene oxide) electrolytes,1 and characteristics of the electrochemical behavior of glassy carbon in super-acid media.

General Description

Potassium trifluoromethanesulfonate (KOTf, potassium triflate) is the potassium salt of trifluoromethanesulphonic acid. It has been prepared by neutralizing a warm aqueous solution of trifluoromethanesulphonic acid with potassium carbonate. The structure of siloxane–poly(oxyethylene) hybrids doped with potassium triflate has been investigated.

structure and hydrogen bonding

According to the results of temperature dependent powder diffractometry potassium trifluoromethanesulfonate is dimorphic. The phase transition occurs between -63 degreesC and 45 degreesC. The low-temperature modification crystallizes monoclinic with a=10.300(3)Angstrom, b = 6.052(1) Angstrom, c = 14.710(4) Angstrom, beta =111.83(2)degrees (-120 degreesC) and the room-temperature modification with a=10.679(5) Angstrom, b=5.963(2)Angstrom, c=14.624(5)Angstrom, beta =111.57(3)degrees, Z=6, P2(1). According to single crystal structure determination, potassium trifluoromethanesulfonate consists of three different potassium-oxygen-coordination polyhedra, linked by sulfur atoms of the trifluoromethanesulfonate groups. This results in a channel structure with all lipophilic trifluoromethane groups pointing into these channels[1].

References

[1] Korus, G. , and M. Jansen . "Crystal structure, phase transition, and potassium ion conductivity of potassium trifluoromethanesulfonate." (2001).

Potassium trifluoromethanesulfonate(2926-27-4)Related Product Information

• Trifluoromethanesulfonic acid
• (Trifluoromethylsulfonyloxy) copper(I)
• Lanthanum trifluoromethanesulfonate
• Aluminum trifluoromethanesulfonate
• YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
• Sodium trifluoromethanesulfonate
• Trifluoromethanesulfonic anhydride
• Trifluoromethanesulfonyl chloride
• Trifluoromethanesulfonimide
• Lithium trifluoromethanesulfonate
• Zinc trifluoromethanesulfonate
• Lithium bis(trifluoromethanesulphonyl)imide
• N-Phenyl-bis(trifluoromethanesulfonimide)
• SILVER TRIFLUOROMETHANESULFONATE
• N-MethyltrifluoroMethanesulfonaMide
• P-TOLYL TRIFLATE
• YTTERBIUM(III) TRIFLATE HYDRATE, 99.90%
• ERBIUM (III) TRIFLUOROMETHANESULFONATE