(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Basic information
- Product Name:
- (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE
- Synonyms:
-
- (S)-(+)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE
- (R)-PHANEPHOS
- (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE
- Bisdiphenylphosphinoparacyclophane
- 4-FLUOROBENZOYLACETONITRILE, 97% N-BOC-4-OXO-L-PROLINE, 97%
- (s)-phanephos
- (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane,min.95%(S)-PHANEPHOS
- (S)-(+)-4,12-BIS-(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE (S)-PHANEPHOS
- CAS:
- 192463-40-4
- MF:
- C40H34P2
- MW:
- 576.65
- Product Categories:
-
- Chiral Phosphine
- PHANEPhos Series
- organophosphine ligand
- Mol File:
- 192463-40-4.mol
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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Chemical Properties
- Melting point:
- 222-225°C
- alpha
- +63.2° (c 3.27, CH2Cl2)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- solid
- color
- white
- optical activity
- [α]22/D +34°, c = 1 in chloroform
- CAS DataBase Reference
- 192463-40-4
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-37
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Usage And Synthesis
Reaction
- Ligand for rhodium-catalyzed enantioselective hydroboration of cyclopropenes.
- Ligand for iridium-catalyzed enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
- Ligand for the palladium-catalyzed enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
- Ligand for the palladium-catalyzed amides synthesis via C(sp3 )–H bond functionalization and CO insertion.
- Ligand for iridium-catalyzed diene hydrohydroxymethylation.
Uses
Efficient ligand for asymmetric hydrogentation of dehydroamino acids, methyl esters and keytones.
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANESupplier
J & K SCIENTIFIC LTD.
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Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE(192463-40-4)Related Product Information
- Diphenylphosphine
- [2.2]Paracyclophane
- 4-FLUOROBENZOYLACETONITRILE
- (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% (R)-PHANEPHOS
- (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE (R)-PHANEPHOS
- (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS
- (S)-PARAPHOS RUTHENIUMCL2 (R,R)-DPEN
- DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM
- [(R)-PARAPHOS RHODIUM (NBD)]BF4
- DICHLORO[(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
- (R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
- (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE