Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II) Chemical Properties

form 

solid

color 

red-violet

CAS DataBase Reference

2049086-34-0

Safety Information

RIDADR 

UN 3175 4.1 / PGII

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II) Usage And Synthesis

Uses

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II) has the following various uses:1.Versatile, air-stable, low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions. 2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines. 3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts.

Uses

Amination of aryl chlorides with ammonia.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst
reaction type: Asymmetric synthesis

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II)(2049086-34-0)Related Product Information

• Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (diphenylphosphine)}nickel(II)
• Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)
• Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)