Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Basic information
- Product Name:
- Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)
- Synonyms:
-
- CHLORO(4-CYANOPHENYL){(R)-1-[(S)-2-(BIS(4-FLUOROPHENYL)PHOSPHINOFERROCENYL]ETHYL(DI-T-BUTYLPHOSPHINE)}NICKEL(II)
- Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) >=95%
- Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)
- )[(R)-1-[(S)-2-[bis(4-fL
- CAS:
- 2049086-37-3
- MF:
- C39H37ClF2FeNNiP2
- MW:
- 769.66
- Mol File:
- 2049086-37-3.mol
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Chemical Properties
- form
- solid
- color
- red-violet
- CAS DataBase Reference
- 2049086-37-3
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) Usage And Synthesis
Uses
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II) is used for：
1.Versatile air-stable low cost nickel catalyst alternative to palladium for carbon-carbon and carbonheteroatom cross-coupling reactions.
2.Used to react substituted aryl and heteroaryl halides and tosylates with ammonia to produce diverse aryl and heteroaryl amines.
3.Used in monoarylation experiments using commercially available ammonia gas, ammonium salts or ammonia stock solutions.
4.Catalyzes the coupling of aryl chlorides with gaseous amines in the form of their hydrochloride salts.
Uses
Amination of functionalized aryl chlorides with ammonia and ammonium salts.
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)Supplier
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Chloro(4-cyanophenyl){(R)-1-[(S)-2-(bis(4-fluorophenyl)phosphinoferrocenyl]ethyl(di-t-butylphosphine)}nickel(II)(2049086-37-3)Related Product Information
- Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (diphenylphosphine)}nickel(II)
- Chloro(4-cyanophenyl){(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl (dicyclohexylphosphine)}nickel(II)
- Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II)