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TERT-BUTYLDIMETHYLSILYLACETYLENE

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TERT-BUTYLDIMETHYLSILYLACETYLENE Basic information

Product Name:
TERT-BUTYLDIMETHYLSILYLACETYLENE
Synonyms:
  • Silane,(1,1-diMethylethyl)ethynyldiMethyl-
  • tert-BUTYLDIMETHYLSILYLACETYLENE, 98%tert-BUTYLDIMETHYLSILYLACETYLENE, 98%tert-BUTYLDIMETHYLSILYLACETYLENE, 98%
  • (tert-Butyldimethylsilyl)acetylene
  • ETHYNYL-TERT-BUTYLDIMETHYLSILANE
  • (T-BUTYLDIMETHYLSILYL)ACETYLENE
  • TERT-BUTYLDIMETHYLSILYLACETYLENE
  • tert-BUTYLDIMETHYLSILYLACETYLENE 98%
  • (tert-Butyldimethylsilyl)ethyne
CAS:
86318-61-8
MF:
C8H16Si
MW:
140.3
Product Categories:
  • Alkynes
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • Terminal
Mol File:
86318-61-8.mol
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TERT-BUTYLDIMETHYLSILYLACETYLENE Chemical Properties

Melting point:
98-102℃ (chloroform hexane )
Boiling point:
116-117 °C (lit.)
Density 
0.751 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.451(lit.)
Flash point:
43 °F
storage temp. 
Flammables area
form 
powder to lump to clear liquid
color 
White or Colorless to Almost white or Almost colorless
Specific Gravity
0.751
Water Solubility 
Sparingly soluble in water (0.043 g/L at 25°C).
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
1921466
CAS DataBase Reference
86318-61-8
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Safety Information

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
9-16-23-24/25-29-33
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
10-21
HazardClass 
3
PackingGroup 
II
HS Code 
29319090

MSDS

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TERT-BUTYLDIMETHYLSILYLACETYLENE Usage And Synthesis

Chemical Properties

Clear colorless liquid

Uses

tert-Butyldimethylsilylacetylene may be used in the synthesis of β-alkynylketone and β-alkynyl aldehydes. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.

General Description

(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.

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