Esters Aromatic acids fatty acid Fatty alcohols Boric acid Cyanide / nitrile Aromatic ketones Aromatic aldehydes Halogenated aliphatic hydrocarbons aliphatic ketones Amide Ethers Aromatics Aromatic alcohol Phosphine ligand Phenols Thiol / thiol Silane Acyl halide Sulfonates / Sulfinates salts Cyanate ester / isocyanate Nitro compounds Imide Olefin (cyclic and acyclic) The polycyclic compound Hydrazine Amine salt (ammonium salt) Aliphatic aldehydes Bicyclic compound Oxime Tricyclic compound Alkanes Sulfonyl halide Phosphonate / phosphonate Phosphorus halide Alkyne Carboxylic anhydride Urea Phosphorus-containing compound Siloxane Azo, diazo compound Ionic Liquids Thiocyanate / isothiocyanate Borate Sulfonates / Sulfinates Selenium compounds Guanidine salt Borane Thiourea Thiolate tetrafluoroborate Thiol ester Polycyclic compound Crown ether Sulfone, sulfoxide compound Hydrazone Imide, amidine Polyamines Tosylate Epoxide Azide Hydroxylamine Cyclodextrin
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Organic reagents

Esters Aromatic acids fatty acid Fatty alcohols Boric acid Cyanide / nitrile Aromatic ketones Aromatic aldehydes Halogenated aliphatic hydrocarbons aliphatic ketones Amide Ethers Aromatics Aromatic alcohol Phosphine ligand Phenols Thiol / thiol Silane Acyl halide Sulfonates / Sulfinates salts Cyanate ester / isocyanate Nitro compounds Imide Olefin (cyclic and acyclic) The polycyclic compound Hydrazine Amine salt (ammonium salt) Aliphatic aldehydes Bicyclic compound Oxime Tricyclic compound Alkanes Sulfonyl halide Phosphonate / phosphonate Phosphorus halide Alkyne Carboxylic anhydride Urea Phosphorus-containing compound Siloxane Azo, diazo compound Ionic Liquids Thiocyanate / isothiocyanate Borate Sulfonates / Sulfinates Selenium compounds Guanidine salt Borane Thiourea Thiolate tetrafluoroborate Thiol ester Polycyclic compound Crown ether Sulfone, sulfoxide compound Hydrazone Imide, amidine Polyamines Tosylate Epoxide Azide Hydroxylamine Cyclodextrin
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From early AD to mid-19 century, people mainly use the natural organic substance (such as animal and plant extracts) for qualitative analysis or quantitative analysis. From the second half of the 19th century to the 1920s, it had begun to appear of artificially synthetic organic reagent such as using potassium acetate xanthan for test of nickel, copper, and molybdenum; using morin for test of aluminum; using diazo coupling reaction for the detection of Nitrite; using α-β-nitroso naphthol for detection of cobalt; using dimethyglyoxime for nickel test.

After the proposal of the special-effects group in the 1930s and the proposal of theoretical analysis of functional groups theory in 1950s, people had carried out large-scale screen of organic reagents in search of special-effects analysis groups for different ions and had successfully synthesized a lot of agents of practical value (such as copper reagents, new copper agent, cadmium reagents, beryllium reagent, thorium reagents, etc.). Before the 1950s, the complex compound, in analytic chemistry, is mainly used in the aspects of the precipitation reaction of a binary chelate for the qualitative detection, precipitate isolation and gravimetric separation and other aspects. In the early 1950s and 1960, it is mainly in the form of complexometric titration. From the beginning of the late 1960s, the main focus has been moved to the photometric analysis. Meanwhile, it has been also developed of chelate organic solvent extraction.

8-hydroxy quinoline, hydrazones, oximes, hydroxamic acids, polyphenols, 1, 10-phenanthroline, phosphorus-oxygen extractant, β- diketones, triphenylmethane acid dye, xanthene dyes and azo dyes and other agents has all been widely studied and applied. On the other hand, the structural theoretical research (such as electronic effects, spatial effects and substituent effects) of the organic reagent can further facilitate the development of new-type organic reagents such as heterocyclic azo reagent. During this period, it has been also developed of monoazo chromotropic acid-type and disazo chromotropic acid-type reagent. During the mid-1970s, the chelating resin and adsorbents have achieved rapid development. Since the 1980s, Chinese researchers of analytical chemistry have made progress in the field of the synthesis and application of asymmetric disazo chromotropic acid.

Organic chemical reagents have wide application in analytic chemistry and are mainly used in solvents, precipitation agents, complexing agents, indicator, coloring reagent and surface active agent, etc. In order to adapt to a variety of analytical needs, sometimes it is required to purify certain reagents. For example, liquid organic reagent is often purified by distillation while solid substance is often purified through crystallization and sublimation. Substance having a high vapor pressure, namely having low purification boiling point and undergoing no decomposition under boiling temperature commonly applied atmospheric distillation; for less volatile and water-insoluble substance, namely having high purification point or undergoing decomposition under boiling temperature, we can apply vacuum distillation or steam distillation for purification of it.

Distillation is a commonly used method for laboratory purification of organic reagent. Conventional distillation apparatus generally comprises distiller, condenser and receiver, three parts with auxiliary section also containing heater, a thermometer, a wetted tube and cork.

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Structure:
Chemical Name:
1,12-Dodecanediamine
CAS:
2783-17-7
MF:
C12H28N2
Structure:
Chemical Name:
7-Methoxy-1-naphthylacetonitrile
CAS:
138113-08-3
MF:
C13H11NO
Structure:
Chemical Name:
(+/-)-trans-1,2-Diaminocyclohexane
CAS:
1121-22-8
MF:
C6H14N2
Structure:
Chemical Name:
4-Bromo-2,6-dimethylaniline
CAS:
24596-19-8
MF:
C8H10BrN
Structure:
Chemical Name:
N-(3-AMINOPROPYL)CYCLOHEXYLAMINE
CAS:
3312-60-5
MF:
C9H20N2
Structure:
Chemical Name:
4-BROMO-2-(TRIFLUOROMETHOXY)IODOBENZENE
CAS:
175278-12-3
MF:
C7H3BrF3IO
Structure:
Chemical Name:
2-Chloro-6-methylaniline
CAS:
87-63-8
MF:
C7H8ClN
Structure:
Chemical Name:
(1R,2R)-(-)-1,2-Diaminocyclohexane
CAS:
20439-47-8
MF:
C6H14N2
Structure:
Chemical Name:
1-Methyl-4-pyrazole boronic acid pinacol ester
CAS:
761446-44-0
MF:
C10H17BN2O2
Structure:
Chemical Name:
2,5-Dibromoterephthalic acid
CAS:
13731-82-3
MF:
C8H4Br2O4
Structure:
Chemical Name:
Heptane
CAS:
142-82-5
MF:
C7H16
Structure:
Chemical Name:
N-BENZYL-N-BUTYLAMINE
CAS:
2403-22-7
MF:
C11H17N
Structure:
Chemical Name:
4-Methoxy-3-methylbenzoic acid
CAS:
6880-04-2
MF:
C9H10O3
Structure:
Chemical Name:
3,5-DIFLUOROBENZYL CHLORIDE
CAS:
220141-71-9
MF:
C7H5ClF2
Structure:
Chemical Name:
2,4,5-Trimethylbenzoic acid
CAS:
528-90-5
MF:
C10H12O2
Structure:
Chemical Name:
ANTHRAQUINONE-2-CARBOXYLIC ACID
CAS:
117-78-2
MF:
C15H8O4
Structure:
Chemical Name:
(S)-3-Amino-3-phenylpropan-1-ol
CAS:
82769-76-4
MF:
C9H13NO
Structure:
Chemical Name:
6-CHLORO-1-INDANONE 96
CAS:
14548-38-0
MF:
C9H7ClO
Structure:
Chemical Name:
4-FLUORO-2-(TRIFLUOROMETHYL)BENZOYL CHLORIDE
CAS:
189807-21-4
MF:
C8H3ClF4O
Structure:
Chemical Name:
2,6-DIMETHYLBENZONITRILE
CAS:
6575-13-9
MF:
C9H9N
Structure:
Chemical Name:
2-Bromo-4-methylbenzoic acid
CAS:
7697-27-0
MF:
C8H7BrO2
Structure:
Chemical Name:
9,9-DIMETHYL-9H-XANTHENE
CAS:
19814-75-6
MF:
C15H14O
Structure:
Chemical Name:
2-Chloro-4-trifluoromethylbenzoic acid
CAS:
23228-45-7
MF:
C8H4ClF3O2
Structure:
Chemical Name:
5-Fluoro-2-methoxyaniline
CAS:
1978-39-8
MF:
C7H8FNO
Structure:
Chemical Name:
7-Chloro-1-cyclopropyl-6-fluoro-4-oxo-1,4-dihydro-1,8-naphthyridine-3-carboxylic acid
CAS:
100361-18-0
MF:
C12H8ClFN2O3
Structure:
Chemical Name:
3-HYDRAZINOBENZOIC ACID
CAS:
38235-71-1
MF:
C7H8N2O2
Structure:
Chemical Name:
trans-4-(4-Propylcyclohexyl)benzonitrile
CAS:
61203-99-4
MF:
C16H21N
Structure:
Chemical Name:
4-Methylmorpholine
CAS:
109-02-4
MF:
C5H11NO
Structure:
Chemical Name:
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
CAS:
144222-34-4
MF:
C21H22N2O2S
Structure:
Chemical Name:
3-FLUORO-2-METHYLBENZOIC ACID
CAS:
699-90-1
MF:
C8H7FO2
Structure:
Chemical Name:
Luminol
CAS:
521-31-3
MF:
C8H7N3O2
Structure:
Chemical Name:
2-(4-Chlorophenoxy)-2-methylpropionic acid
CAS:
882-09-7
MF:
C10H11ClO3
Structure:
Chemical Name:
2-Amino-4-chlorobenzoic acid
CAS:
89-77-0
MF:
C7H6ClNO2
Structure:
Chemical Name:
(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine
CAS:
29841-69-8
MF:
C14H16N2
Structure:
Chemical Name:
2,2,6,6-Tetramethyl-3,5-heptanedione
CAS:
1118-71-4
MF:
C11H20O2
Structure:
Chemical Name:
4-Fluoro-3-methoxyaniline
CAS:
64465-53-8
MF:
C7H8FNO
Structure:
Chemical Name:
N,N-Diethylhydroxylamine
CAS:
3710-84-7
MF:
C4H11NO
Structure:
Chemical Name:
4-Fluoro-2-(trifluoromethyl)benzaldehyde
CAS:
90176-80-0
MF:
C8H4F4O
Structure:
Chemical Name:
5-FLUORO-2-(TRIFLUOROMETHYL)BENZONITRILE
CAS:
240800-45-7
MF:
C8H3F4N
Structure:
Chemical Name:
Methyl 4-bromo-3-methylbenzoate
CAS:
148547-19-7
MF:
C9H9BrO2
Structure:
Chemical Name:
ETHYL 1-METHYL-1H-IMIDAZOLE-2-CARBOXYLATE
CAS:
30148-21-1
MF:
C7H10N2O2
Structure:
Chemical Name:
Hexane
CAS:
110-54-3
MF:
C6H14
Structure:
Chemical Name:
N-OCTANE
CAS:
111-65-9
MF:
C8H18
Structure:
Chemical Name:
2-CHLORO-6-FLUOROPHENYLACETONITRILE
CAS:
75279-55-9
MF:
C8H5ClFN
Structure:
Chemical Name:
N-Bromosuccinimide
CAS:
128-08-5
MF:
C4H4BrNO2
Structure:
Chemical Name:
(S)-Oxiranemethanol
CAS:
60456-23-7
MF:
C3H6O2
Structure:
Chemical Name:
4-FLUORO-2-(TRIFLUOROMETHYL)PHENOL
CAS:
130047-19-7
MF:
C7H4F4O
Structure:
Chemical Name:
3-BROMO-4-METHOXYPHENYLACETIC ACID
CAS:
774-81-2
MF:
C9H9BrO3
Structure:
Chemical Name:
4-Bromo-3,5-dimethylisoxazole
CAS:
10558-25-5
MF:
C5H6BrNO
Structure:
Chemical Name:
2-Phenoxyethylamine
CAS:
1758-46-9
MF:
C8H11NO
Structure:
Chemical Name:
4-BENZYLANILINE
CAS:
1135-12-2
MF:
C13H13N
Structure:
Chemical Name:
N,O-Dimethylhydroxylamine hydrochloride
CAS:
6638-79-5
MF:
C2H8ClNO
Structure:
Chemical Name:
1-Bromo-2-fluoro-4-(trifluoromethoxy)benzene
CAS:
168971-68-4
MF:
C7H3BrF4O
Structure:
Chemical Name:
4,5-DIFLUOROPHTHALIC ANHYDRIDE
CAS:
18959-30-3
MF:
C8H2F2O3
Structure:
Chemical Name:
3-CHLORO-4-(TRIFLUOROMETHOXY)ANILINE
CAS:
64628-73-5
MF:
C7H5ClF3NO
Structure:
Chemical Name:
Ethyl 3-(4-fluorophenyl)-3-oxopropanoate
CAS:
1999-00-4
MF:
C11H11FO3
Structure:
Chemical Name:
2,2,2-TRIFLUOROETHYL P-TOLUENESULFONATE
CAS:
433-06-7
MF:
C9H9F3O3S
Structure:
Chemical Name:
3-Amino-4-methylphenol
CAS:
2836-00-2
MF:
C7H9NO
Structure:
Chemical Name:
2-Fluoro-5-bromoanisole
CAS:
103291-07-2
MF:
C7H6BrFO
Structure:
Chemical Name:
2-FLUORO-5-METHYLPHENYLBORONIC ACID
CAS:
166328-16-1
MF:
C7H8BFO2
Structure:
Chemical Name:
3,6-Dihydro-2H-pyran-4-boronic acid pinacol ester
CAS:
287944-16-5
MF:
C11H19BO3
Structure:
Chemical Name:
2-CHLORO-5-METHYLPHENYLBORONIC ACID
CAS:
193353-35-4
MF:
C7H8BClO2
Structure:
Chemical Name:
(3-BOC-AMINOPHENYL)BORONIC ACID
CAS:
380430-68-2
MF:
C11H16BNO4
Structure:
Chemical Name:
1,1,1,3,3,3-Hexafluoro-2-propanol
CAS:
920-66-1
MF:
C3H2F6O
Structure:
Chemical Name:
3-IODO-4-METHOXYANILINE
CAS:
74587-12-5
MF:
C7H8INO
Structure:
Chemical Name:
2-BENZYLOXYANILINE
CAS:
20012-63-9
MF:
C13H13NO
Structure:
Chemical Name:
1-Boc-pyrazole-4-boronic acid pinacol ester
CAS:
552846-17-0
MF:
C14H23BN2O4
Structure:
Chemical Name:
3-Methoxydiphenylamine
CAS:
101-16-6
MF:
C13H13NO
Structure:
Chemical Name:
2-FLUORO-5-(TRIFLUOROMETHYL)BENZOYL CHLORIDE
CAS:
207981-46-2
MF:
C8H3ClF4O
Structure:
Chemical Name:
4-FLUORO-3-METHOXYACETOPHENONE
CAS:
64287-19-0
MF:
C9H9FO2
Structure:
Chemical Name:
3-(Trifluoromethoxy)benzyl bromide
CAS:
159689-88-0
MF:
C8H6BrF3O
Structure:
Chemical Name:
2,4,6-Trimethoxybenzoic acid
CAS:
570-02-5
MF:
C10H12O5
Structure:
Chemical Name:
N-Ethylbenzylamine
CAS:
14321-27-8
MF:
C9H13N
Structure:
Chemical Name:
2-Amino-2'-fluoro-5-bromobenzophenone
CAS:
1479-58-9
MF:
C13H9BrFNO
Structure:
Chemical Name:
4-Bromo-2-hydroxybenzoic acid
CAS:
1666-28-0
MF:
C7H5BrO3
Structure:
Chemical Name:
alpha-Bromo-2-chlorophenylacetic acid
CAS:
141109-25-3
MF:
C8H6BrClO2
Structure:
Chemical Name:
2-FLUORO-5-METHOXYBENZONITRILE
CAS:
127667-01-0
MF:
C8H6FNO
Structure:
Chemical Name:
2-Chloro-5-aminophenol
CAS:
6358-06-1
MF:
C6H6ClNO
Structure:
Chemical Name:
3-CHLORO-2-FLUOROBENZOYL CHLORIDE
CAS:
85345-76-2
MF:
C7H3Cl2FO
Structure:
Chemical Name:
5-Chloro-2,4-dimethoxyaniline
CAS:
97-50-7
MF:
C8H10ClNO2
Structure:
Chemical Name:
2-Fluoro-4-(trifluoromethyl)aniline
CAS:
69409-98-9
MF:
C7H5F4N
Structure:
Chemical Name:
2-ISOPROPYLANILINE
CAS:
643-28-7
MF:
C9H13N
Structure:
Chemical Name:
(1R,2R)-(+)-1,2-Diphenylethylenediamine
CAS:
35132-20-8
MF:
C14H16N2
Structure:
Chemical Name:
4-Aminobenzylamine
CAS:
4403-71-8
MF:
C7H10N2
Structure:
Chemical Name:
(1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
CAS:
167316-27-0
MF:
C21H22N2O2S
Structure:
Chemical Name:
2-Fluoro-3-methylaniline
CAS:
1978-33-2
MF:
C7H8FN
Structure:
Chemical Name:
(R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol
CAS:
127852-28-2
MF:
C10H8F6O
Structure:
Chemical Name:
3-FLUORO-4-(TRIFLUOROMETHYL)BENZALDEHYDE
CAS:
204339-72-0
MF:
C8H4F4O
Structure:
Chemical Name:
2-Amino-3,4-dimethylbenzoic acid
CAS:
50419-58-4
MF:
C9H11NO2
Structure:
Chemical Name:
(R)-(+)-Glycidol
CAS:
57044-25-4
MF:
C3H6O2
Structure:
Chemical Name:
2,4,6-TRI-TERT-BUTYLANILINE
CAS:
961-38-6
MF:
C18H31N
Structure:
Chemical Name:
Di-p-toluoyl-D-tartaric acid monohydrate
CAS:
71607-32-4
MF:
C20H20O9
Structure:
Chemical Name:
N-Phenyl-bis(trifluoromethanesulfonimide)
CAS:
37595-74-7
MF:
C8H5F6NO4S2
Structure:
Chemical Name:
3-CHLORO-4-METHYLBENZONITRILE
CAS:
21423-81-4
MF:
C8H6ClN
Structure:
Chemical Name:
1,3-DIBROMO-5-(TRIFLUOROMETHOXY)BENZENE
CAS:
207226-31-1
MF:
C7H3Br2F3O
Structure:
Chemical Name:
3-Amino-5-phenylpyrazole
CAS:
1572-10-7
MF:
C9H9N3
Structure:
Chemical Name:
2,4,6-Trimethylaniline
CAS:
88-05-1
MF:
C9H13N
Structure:
Chemical Name:
4-BROMO-2-METHYLANISOLE
CAS:
14804-31-0
MF:
C8H9BrO
Structure:
Chemical Name:
(1S,2S)-(-)-1,2-Diaminocyclohexane L-tartrate
CAS:
67333-70-4
MF:
C10H20N2O6
Structure:
Chemical Name:
2'-Methylacetoacetanilide
CAS:
93-68-5
MF:
C11H13NO2