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Borane

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Borane,also known as boron hydride, is the ageneraldesignation for a series of compounds formed by two elements of boron and hydrogen. Simple boranes are colorless, unpleasantly odorous and toxic. They are usually very unstable and spontaneous to generate boron oxide in air. With the increase of the number of boron atoms, boranes can be gaseous (e.g., diborane), liquid (e.g. pentaborane) and solid (e.g. decaborane). There have been more than 20 kinds of boranes ever prepared by human so far, which can be divided into two categories. The general formula of one of them is BnHR+4 (n≥2), such as diborane (B2H6), pentaborane-9 (B5H9) and sixteen borane (B16H20); the other is BnHR+6 (n≥3), such as triborane(B3H9), pentaborane-11 (B5H11), nonaborane (B9H15) and so on. Borane all have unpleasant odor. Simple borane (of relatively less boron atoms) is so chemically active that is spontaneous in air and easy for hydrolysis, halogenation and amination. Diborane is of the largest and most important usage. It is prepared from boron trifluoride with lithium hydride in ether in industry.

Other boranes can be prepared from the thermal decomposition of diborane at different temperatures.

Borane release a lot of heat when burned, therefore it can be used as high-energy fuel for rockets and missiles. It can also be used as the treatment agent of a metal or ceramic parts and rubber crosslinking agent. One of the important applications of diborane is reduction agent in the hydroboration reaction.

Borane is highly toxic, inhalation of diborane can cause lung damage, inhalation of decaborane can cause a heart recession, large boranes are toxic to the central nervous system and damaging to the liver and kidneys. Careful attention must be paid when using borane.

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Structure:
Chemical Name:
1-Methyl-4-pyrazole boronic acid pinacol ester
CAS:
761446-44-0
MF:
C10H17BN2O2
Structure:
Chemical Name:
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
CAS:
112022-83-0
MF:
C18H20BNO
Structure:
Chemical Name:
TRIS(PENTAFLUOROPHENYL)BORANE
CAS:
1109-15-5
MF:
C18BF15
Structure:
Chemical Name:
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
CAS:
112022-81-8
MF:
C18H20BNO
Structure:
Chemical Name:
2-CHLORO-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE
CAS:
444120-94-9
MF:
C11H15BClNO2
Structure:
Chemical Name:
Borane-methyl sulfide complex
CAS:
13292-87-0
MF:
C2H10BS
Structure:
Chemical Name:
(+)-Diisopinocampheyl chloroborane
CAS:
112246-73-8
MF:
C20H34BCl
Structure:
Chemical Name:
o-Carborane
CAS:
16872-09-6
MF:
C2B10
Structure:
Chemical Name:
Borane-tetrahydrofuran complex
CAS:
14044-65-6
MF:
C4H11BO
Structure:
Chemical Name:
BENZYLBORONIC ACID PINACOL ESTER
CAS:
87100-28-5
MF:
C13H19BO2
Structure:
Chemical Name:
4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)TOLUENE
CAS:
195062-57-8
MF:
C13H19BO2
Structure:
Chemical Name:
3-(ISOPROPOXYCARBONYL)PHENYLBORONIC ACID
CAS:
342002-80-6
MF:
C10H13BO4
Structure:
Chemical Name:
Diborane
CAS:
19287-45-7
MF:
B2H6
Structure:
Chemical Name:
3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)toluene
CAS:
253342-48-2
MF:
C13H19BO2
Structure:
Chemical Name:
Borane tert-butylamine complex
CAS:
7337-45-3
MF:
C4H11BN
Structure:
Chemical Name:
Methoxydiethylborane
CAS:
7397-46-8
MF:
C5H13BO
Structure:
Chemical Name:
4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)FLUOROBENZENE
CAS:
214360-58-4
MF:
C12H16BFO2
Structure:
Chemical Name:
2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
CAS:
69190-62-1
MF:
C10H21BO2
Structure:
Chemical Name:
2-(2-IODOPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
CAS:
857934-82-8
MF:
C12H16BIO2
Structure:
Chemical Name:
1,2-BIS(TERT-BUTYLTHIO)ETHANE:DIBORANE COMPLEX
CAS:
71522-78-6
MF:
C10H26B2S2
Structure:
Chemical Name:
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
CAS:
73624-47-2
MF:
C18H31B
Structure:
Chemical Name:
M-CARBORANE
CAS:
16986-24-6
MF:
C2H12B10
Structure:
Chemical Name:
DECABORANE
CAS:
17702-41-9
MF:
B10H14
Structure:
Chemical Name:
Borane-pyridine complex
CAS:
110-51-0
MF:
C5H8BN
Structure:
Chemical Name:
4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE
CAS:
195062-61-4
MF:
C12H16BClO2
Structure:
Chemical Name:
TRIBUTYLBORANE
CAS:
122-56-5
MF:
C12H27B
Structure:
Chemical Name:
(-)-Diisopinocampheyl borane
CAS:
21932-54-7
MF:
C20H35B
Structure:
Chemical Name:
SODIUM COBALTICARBORANE
CAS:
99492-72-5
MF:
C4B18CoNa
Structure:
Chemical Name:
Boron trifluoride-butyl ether complex
CAS:
593-04-4
MF:
C8H18BF3O
Structure:
Chemical Name:
Borane ammonia complex
CAS:
13774-81-7
MF:
BH6N
Structure:
Chemical Name:
5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiazole
CAS:
1086111-09-2
MF:
C9H14BNO2S
Structure:
Chemical Name:
B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE
CAS:
42371-63-1
MF:
C18H31B
Structure:
Chemical Name:
1-(TERT-BUTYL) 5-METHYL 3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-1H-INDOLE-1,5-DICARBOXYLATE
CAS:
2304634-20-4
MF:
C21H28BNO6
Structure:
Chemical Name:
4-(1,3,2-DIOXABORINAN-2-YL)BENZALDEHYDE
CAS:
160068-88-2
MF:
C10H11BO3
Structure:
Chemical Name:
2-(4-CARBOXYPHENYL)-1,3,2-DIOXABORINANE
CAS:
126747-13-5
MF:
C10H11BO4
Structure:
Chemical Name:
4,4,6-TRIMETHYL-2-VINYL-1,3,2-DIOXABORINANE
CAS:
4627-10-5
MF:
C8H15BO2
Structure:
Chemical Name:
9-BBN DIMER
CAS:
21205-91-4
MF:
C16H30B2
Structure:
Chemical Name:
TRIPHENYLBORANE
CAS:
960-71-4
MF:
C18H15B
Structure:
Chemical Name:
Borane morpholine complex
CAS:
4856-95-5
MF:
C4H12BNO
Structure:
Chemical Name:
Diisopinocampheylborane
CAS:
21947-87-5
MF:
C20H35B
Structure:
Chemical Name:
2-ALLENYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
CAS:
865350-17-0
MF:
C9H15BO2
Structure:
Chemical Name:
DICHLOROMETHYLDIISOPROPOXYBORANE
CAS:
62260-99-5
MF:
C7H15BCl2O2
Structure:
Chemical Name:
1,2-Diphenyl-1,2-dicarba-closo-dodecaborane
CAS:
17805-19-5
MF:
C14H10B10
Structure:
Chemical Name:
(S,S)-1,2-BIS[(TERT-BUTYL)METHYLPHOSPHINO]ETHANE BIS(BORANE)
CAS:
203000-48-0
MF:
C12H30B2P2
Structure:
Chemical Name:
TETRAKIS(DIMETHYLAMINO)DIBORON
CAS:
1630-79-1
MF:
C8H24B2N4
Structure:
Chemical Name:
4-(5,5-Dimethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde
CAS:
128376-65-8
MF:
C12H15BO3
Structure:
Chemical Name:
(+)-PINANEBORANE
CAS:
90084-43-8
MF:
C10H17BO2
Structure:
Chemical Name:
2-(4-BROMOBUTYL)-1 3 2-BENZODIOXABOROLE&
CAS:
142172-51-8
MF:
C10H12BBrO2
Structure:
Chemical Name:
(R)-2-METHYL-CBS-OXAZABOROLIDINE
CAS:
133261-83-3
MF:
C18H20BNO
Structure:
Chemical Name:
Dichlorophenylborane
CAS:
873-51-8
MF:
C6H5BCl2
Structure:
Chemical Name:
1-BROMO-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
CAS:
269410-06-2
MF:
C12H16BBrO2
Structure:
Chemical Name:
DICYCLOHEXYL(TRIFLUOROMETHANESULFONYLOXY)BORANE
CAS:
145412-54-0
MF:
C13H22BF3O3S
Structure:
Chemical Name:
2-CHLORO-1,3,2-BENZODIOXABOROLE
CAS:
55718-76-8
MF:
C6H4BClO2
Structure:
Chemical Name:
2,2-Difluoro-benzo[1,3]dioxole-5-boronic acid
CAS:
190903-71-0
MF:
C7H5BF2O4
Structure:
Chemical Name:
BUTYLDICHLOROBORANE
CAS:
14090-22-3
MF:
C4H9BCl2
Structure:
Chemical Name:
Pentaborane
CAS:
19624-22-7
MF:
B5H9
Structure:
Chemical Name:
L-TarB-NO2, 2-(3-Nitrophenyl)-1,3,2-dioxaborolane-4R,5R-dicarboxylic acid
CAS:
467443-01-2
MF:
C10H8BNO8
Structure:
Chemical Name:
BORANE-DIETHYLAMINE
CAS:
2670-68-0
MF:
C4H14BN
Structure:
Chemical Name:
BORANE-ISOAMYL SULFIDE COMPLEX
CAS:
183118-10-7
MF:
C5H15BS
Structure:
Chemical Name:
(S)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&
CAS:
463941-07-3
MF:
C24H24BNO
Structure:
Chemical Name:
Dicyclohexylborane
CAS:
1568-65-6
MF:
C12H23B
Chemical Name:
Borane-dimethylsulfide
Structure:
Chemical Name:
TRIMESITYLBORANE
CAS:
7297-95-2
MF:
C27H33B
Structure:
Chemical Name:
BORON MONOCHLORIDE-METHYL SULFIDE COMPLEX
CAS:
63348-81-2
MF:
C2H9BClS
Structure:
Chemical Name:
1-ISOPROPYL-O-CARBORANE
CAS:
13569-38-5
MF:
C5H18B10
Structure:
Chemical Name:
(+)-ISOPINOCAMPHEYLBORANE TMEDA COMPLEX
CAS:
68297-74-5
MF:
2C10H19B.C6H16N2
Structure:
Chemical Name:
3,3-diMethylbenzo[c][1,2]oxaborol-1(3H)-ol
CAS:
221352-10-9
MF:
C9H11BO2
Structure:
Chemical Name:
TRIS(DIMETHYLAMINO)BORANE
CAS:
4375-83-1
MF:
C6H18BN3
Structure:
Chemical Name:
2,6-dimethylpyridine--borane
CAS:
3999-42-6
MF:
C7H12BN
Chemical Name:
Dexsi l300
Structure:
Chemical Name:
MONOBROMOBORANE-METHYL SULFIDE COMPLEX
CAS:
55652-52-3
MF:
C2H10BBrS
Structure:
Chemical Name:
(R)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (R)-Phenyl oxazaborolidine
CAS:
145238-45-5
MF:
C23H22BNO
Structure:
Chemical Name:
DIMETHYLBORON BROMIDE
CAS:
5158-50-9
MF:
C2H6BBr
Structure:
Chemical Name:
DIBROMOBORANE DIMETHYL SULFIDE COMPLEX
CAS:
55671-55-1
MF:
C2H10BBr2S
Structure:
Chemical Name:
(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&
CAS:
865812-10-8
MF:
C24H24BNO
Structure:
Chemical Name:
Potassium tert-butyl N-[2-(trifluoroboranuidyl)ethyl]carbamate
CAS:
926280-83-3
MF:
C7H14BF3NO2.K
Structure:
Chemical Name:
BORANE-DI(TERT-BUTYL)PHOSPHINE COMPLEX
CAS:
128363-76-8
MF:
C8H22BP
Structure:
Chemical Name:
DIISOPROPOXYMETHYLBORANE
CAS:
86595-27-9
MF:
C7H17BO2
Structure:
Chemical Name:
2-Ethynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
CAS:
347389-74-6
MF:
C8H13BO2
Structure:
Chemical Name:
4-METHYL-MORPHOLINEBORANE
CAS:
15648-16-5
MF:
C5H14BNO
Structure:
Chemical Name:
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
CAS:
99438-28-5
MF:
C21H37BO
Structure:
Chemical Name:
DICHLORO(DIISOPROPYLAMINO)BORANE
CAS:
44873-49-6
MF:
C6H14BCl2N
Structure:
Chemical Name:
BORANE-N,N-DIISOPROPYLETHYLAMINE COMPLEX
CAS:
88996-23-0
MF:
C8H22BN
Structure:
Chemical Name:
(S)-Tetrahydro-1,3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxaborole, 99% (S)-Phenyl oxazaborolidine
CAS:
131180-90-0
MF:
C23H22BNO
Structure:
Chemical Name:
(-)-N-DODECYL-N-METHYLEPHEDRINIUM BROMIDE
CAS:
57155-63-2
MF:
C23H42BrNO
Structure:
Chemical Name:
(4R)-2-Methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine
CAS:
155268-88-5
MF:
C21H20BNO
Structure:
Chemical Name:
(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
CAS:
85134-98-1
MF:
C21H37BO
Structure:
Chemical Name:
3-AMINO-3'-CHLOROBENZANILIDE
CAS:
115175-22-9
MF:
C13H11ClN2O
Structure:
Chemical Name:
BUTYLDIISOPROPOXYBORANE
CAS:
86595-32-6
MF:
C10H23BO2
Structure:
Chemical Name:
DICHLOROBORANE-DIOXANE COMPLEX 3M SOLU&
CAS:
252265-33-1
MF:
C4H9BCl2O2
Structure:
Chemical Name:
BORON TRIS(TRIFLUOROACETATE)
CAS:
350-70-9
MF:
C6BF9O6