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PHENYLBORON DICHLORIDE

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PHENYLBORON DICHLORIDE Basic information

Product Name:
PHENYLBORON DICHLORIDE
Synonyms:
  • Borane,dichlorophenyl-
  • C6H5BCl2
  • PHENYLDICHLOROBORANE
  • PHENYLBORON DICHLORIDE
  • DICHLOROPHENYLBORANE
  • DICHLOROPHENYL BORON
  • Phenylborondichloride,95%
  • Phenylborondichloride,min.97%
CAS:
873-51-8
MF:
C6H5BCl2
MW:
158.82
Product Categories:
  • organoboron and borato-metal complexes
Mol File:
873-51-8.mol
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PHENYLBORON DICHLORIDE Chemical Properties

Melting point:
7 °C
Boiling point:
66 °C11 mm Hg(lit.)
Density 
1.224 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.545(lit.)
Flash point:
−5 °F
storage temp. 
2-8°C
form 
Liquid
color 
Colorless
Specific Gravity
1.224
Water Solubility 
Soluble in water (Reacts violently).
Sensitive 
Moisture Sensitive
BRN 
2243576
CAS DataBase Reference
873-51-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
F,C
Risk Statements 
11-34-37
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
10-23
HazardClass 
3
PackingGroup 
II
HS Code 
29310099

MSDS

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PHENYLBORON DICHLORIDE Usage And Synthesis

Chemical Properties

clear colorless liquid

Uses

Dichlorophenylborane is widely used as a catalyst in Antiproliferative macrolide and cell migration inhibitor lactimidomycin and in enantioselective synthesis of polypeptide segments using vinylogous Mukaiyama aldol reactions and in enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives. It is a stereo selective alkylative ring opening of cyclic anhydrides and in cross-metathesis reaction of amino derivatives with olefines.

Uses

Catalyst for:

  • Antiproliferative macrolide and cell migration inhibitor lactimidomycin
  • Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
  • Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
  • Stereoselective alkylative ring opening of cyclic anhydrides
  • Cross-metathesis reaction of amino derivatives with olefins
  • Asymmetric acetate aldol reactions
  • The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene

PHENYLBORON DICHLORIDE Preparation Products And Raw materials

Raw materials

PHENYLBORON DICHLORIDESupplier

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
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18621169107
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Alfa Aesar
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400-6106006
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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Sales-CN@TCIchemicals.com
Energy Chemical
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021-58432009 400-005-6266
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sales8178@energy-chemical.com
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