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(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&

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(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& Basic information

Product Name:
(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&
Synonyms:
  • (R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&
  • (r)-(+)-o-tolyl-cbs-oxazaborolidine solution
  • (3aR)-1-(2-methylphenyl)-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaboro
  • 1H,3H-Pyrrolo[1,2-c][1,3,2]oxazaborole,tetrahydro-1-(2-Methylphenyl)-3,3-diphenyl-, (3aR)-
  • (3aR)-1-(2-methylphenyl)-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
  • (R)-(+)-o-Tolyl-CBS-oxazaborolidine solution 0.5 M in toluene
  • (R)-3,3-Diphenyl-1-(o-tolyl)tetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
  • (R)-(+)-o-Tolyl-CBS-oxazaborolidine solution
CAS:
865812-10-8
MF:
C24H24BNO
MW:
353.26
Mol File:
865812-10-8.mol
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(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& Chemical Properties

Boiling point:
473.3±55.0 °C(Predicted)
Density 
0.900 g/mL at 25 °C
refractive index 
n20/D 1.514
Flash point:
4 °C
pka
-0.32±0.40(Predicted)
InChI
1S/C24H24BNO/c1-19-11-8-9-16-22(19)25-26-18-10-17-23(26)24(27-25,20-12-4-2-5-13-20)21-14-6-3-7-15-21/h2-9,11-16,23H,10,17-18H2,1H3/t23-/m1/s1
InChIKey
XHMKFCAQQGBIPZ-HSZRJFAPSA-N
SMILES
[H][C@]12CCCN1B(OC2(c3ccccc3)c4ccccc4)c5ccccc5C
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
11-38-48/20-63-65-67
Safety Statements 
36/37-62-16
RIDADR 
UN 1294 3/PG 2
WGK Germany 
3
Storage Class
3 - Flammable liquids
Hazard Classifications
Aquatic Chronic 3
Asp. Tox. 1
Flam. Liq. 2
Repr. 2
Skin Irrit. 2
STOT RE 2
STOT SE 3
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(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I& Usage And Synthesis

Uses

(R)-(+)-o-Tolyl-CBS-oxazaborolidine is a chiral catalyst used in the organic reactions such as enantioselective diels-alder reactions.

Uses

CBS Catalysts for Asymmetric Reduction and Asymmetric Synthesis

(R)-O-TOLYL-CBS-OXAZABOROLIDINE, 0.5M I&Supplier

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