(+)-Diisopinocampheyl chloroborane Chemical Properties

Melting point:

53-55 °C(lit.)

Boiling point:

369.6±25.0 °C(Predicted)

Density 

0.91

Flash point:

>230 °F

storage temp. 

2-8°C

solubility 

sol in both polar and nonpolar aprotic solvents like diethyl ether, THF, methylene chloride, pentane, hexane, etc

form 

clear liquid

color 

Colorless to Almost colorless

InChIKey

PSEHHVRCDVOTID-YYNWCRCSSA-N

CAS DataBase Reference

112246-73-8(CAS DataBase Reference)

Safety Information

Hazard Codes 

C

Risk Statements 

34-37

Safety Statements 

26-36/37/39-45

RIDADR 

UN 3261 8/PG 2

WGK Germany 

3

F 

10-21

HazardClass 

8

PackingGroup 

III

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

(+)-Diisopinocampheyl chloroborane Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

Precautions

(+)-Diisopinocampheyl chloroborane and its solutions are moisture and air sensitive. The reagent reacts instantaneously with water and protic solvents to liberate HCl. Containers of DIP-Chloride should be stored in the absence of moisture. Cans or bottles of DIP-Chloride should be flushed with N2 and kept tightly sealed to avoid contact of oxygen and moisture.

storage

(+)-Diisopinocampheyl chloroborane should be crushed, transferred, or weighed only in glove bag or dry box under N2 atmosphere. The reagent can be stored for several years under N2 atmosphere below 25 °C.

(+)-Diisopinocampheyl chloroborane (112246-73-8)Related Product Information

• Polyvinyl chloride
• Borane-tetrahydrofuran complex
• Sodium chloride
• Calcium chloride
• Borane-methyl sulfide complex
• Choline chloride
• Ammonium chloride
• Potassium chloride
• Thionyl chloride
• Diborane
• Pentaborane
• Hexane
• (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE,(-)-Diisopinocampheyl chloroborane
• (1R)-(+)-TRANS-PINANE
• Methylene Chloride
• HEXANES
• CHLORODICYCLOHEXYLBORANE
• Disiamylborane