Borane tert-butylamine complex Chemical Properties

Melting point:

98-100 °C (dec.)(lit.)

Density 

0,87 g/cm³

storage temp. 

Refrigerator

solubility 

27g/l

form 

powder

color 

White to off-white

Water Solubility 

Soluble in water (27 g/L at 20°C) and methanol.

BRN 

4134905

EPA Substance Registry System

Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- (7337-45-3)

Safety Information

Hazard Codes 

T

Risk Statements 

21-25-36/37/38

Safety Statements 

26-36/37-45

RIDADR 

UN 2811 6.1/PG 3

WGK Germany 

3

RTECS 

EO3900000

F 

9

TSCA 

Yes

HazardClass 

4.1

PackingGroup 

III

HS Code 

29299090

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Borane tert-butylamine complex Usage And Synthesis

Chemical Properties

white to off-white crystalline powder

Uses

Borane-tert-butylamine complex is used in stereoselective reduction of a steroidal ketone and for a review of amine boranes as selective reducing and hydroborating agents. It is also used as strong co-reducing agent in the syntheses of copper (I) oxide nanoparticles, diphosphine-protected gold nanocluster and 4-acetoxycinnamyl alcohols.

Application

Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:
copper (I) oxide nanoparticles
diphosphine-protected gold nanocluster
4-acetoxycinnamyl alcohols
Reactant involved in:
Non-destructive analyses and conservation treatments of Indian drawings
Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
The formation of σ-borane complexes
Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
Photochemical hydroboration and oxidation of single-walled carbon nanotubes

General Description

Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.

Borane tert-butylamine complex(7337-45-3)Related Product Information

• Dimethylaminoborane
• Borane-2-picoline complex
• Borane tert-butylamine complex
• 2-(tert-Butylamino)sulfonylphenylboronic acid
• Orthoboric acid
• tert-Butylamine
• Boron
• 1-(TRIPHENYLMETHYL)PYRIDINIUM TETRAFLUOROBORATE
• [2-[2-(TRIPHENYLMETHYL)-2H-TETRAZOL-5-YL]PHENYL]BORONIC ACID
• 4-ACETAMIDO-2,2,6,6-TETRAMETHYL-1-OXOPIPERIDINIUM TETRAFLUOROBORATE,95.0+%(T)
• RARECHEM AQ NN 0482
• RARECHEM AQ NN 0505
• RARECHEM AQ NN 0483
• RARECHEM AQ NN 0503
• RARECHEM AQ NN 0507
• AURORA KA-108
• RARECHEM AQ NN 0499
• RARECHEM AQ NN 0512