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(S)-Oxiranemethanol

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(S)-Oxiranemethanol Basic information

Product Name:
(S)-Oxiranemethanol
Synonyms:
  • (S)-(-)-GLYCIDOL ((S)-(-)-2,3-EPOXY-1-PROPANOL)
  • [(2r)-oxiran-2-yl]methanol
  • (S)-(-)-GLYCIDOL, 97% (98% EE/GLC)
  • S-Glycidoe
  • (R)-3-Hydroxy-1,2-epoxypropane
  • (S)-(-)-2,3-Epoxy-1-propanol, (S)-(-)-Oxirane-2-methanol
  • (S)-(-)-Glycidol, (98% ee), 97%
  • (2S)-(-)-3-Hydroxy-1,2-propenoxide 97%
CAS:
60456-23-7
MF:
C3H6O2
MW:
74.08
Product Categories:
  • Chiral Compound
  • CHIRAL COMPOUNDS
  • chiral
  • API intermediates
Mol File:
60456-23-7.mol
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(S)-Oxiranemethanol Chemical Properties

Melting point:
72-73 °C
alpha 
-15 º (neat)
Boiling point:
66-67 °C19 mm Hg(lit.)
Density 
1.116 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.433(lit.)
Flash point:
178 °F
storage temp. 
-20°C
solubility 
Soluble in chloroform, DMSO and methanol.
pka
14.62±0.10(Predicted)
form 
Liquid
color 
Pale yellow
optical activity
[α]20/D 15°, neat
BRN 
79783
InChIKey
CTKINSOISVBQLD-VKHMYHEASA-N
CAS DataBase Reference
60456-23-7(CAS DataBase Reference)
NIST Chemistry Reference
Oxiranemethanol, (S)-(60456-23-7)
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Safety Information

Hazard Codes 
T
Risk Statements 
45-60-21/22-23-36/37/38-68-41-37/38
Safety Statements 
53-45-36/37/39-26
RIDADR 
UN 2810 6.1/PG 2
WGK Germany 
3
RTECS 
RR0508100
10-21
HazardClass 
6.1
PackingGroup 
III
HS Code 
29109000

MSDS

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(S)-Oxiranemethanol Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

Employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis.

Definition

ChEBI: (S)-glycidol is a glycidol. It is functionally related to a (S)-1,2-epoxypropane. It is an enantiomer of a (R)-glycidol.

General Description

Glycidol or 2,3-epoxy-1-propanol is a highly reactive epoxy derivative, which is generally used as a monomer in the preparation of many polymers like polyesters,?polycarbonates,?polyurethanes,?and polyamides. It is also used in the preparation of detergents, rubbers, perfumes, fabric dyes, varnishes, cosmetics, and paints.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

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