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(2R)-(-)-Glycidyl tosylate

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(2R)-(-)-Glycidyl tosylate Basic information

Product Name:
(2R)-(-)-Glycidyl tosylate
Synonyms:
  • (R)-(-)-Glycidyl p-toluenesulfonate
  • (2R)-OXIRAN-2-YLMETHYL4-METHYLBENZENESULFONATE
  • (2R)-(-)-GLYCIDYL TOSYLATE 99+%
  • Oxiran-2-ylmethyl 4-methylbenzenesulfonate
  • 2-(S)-(OXIRAN-2-YL)METHYL 4-METHYLBENZENE SULFONATE
  • OXIRANEMETHANOL, 4-METHYLBENZENESULFONATE, (2R)-
  • (S)-Oxiranemethanol 4-methylbenzenesulfonate
  • (R)-(-)-OXIRANE-2-METHANOL 4-TOLUENESULFONATE
CAS:
113826-06-5
MF:
C10H12O4S
MW:
228.26
EINECS:
601-283-9
Product Categories:
  • Aromatics
  • Carbohydrates & Derivatives
  • chiral
  • API intermediates
  • Ring Systems
  • Sulfur & Selenium Compounds
  • Chiral Compound
Mol File:
113826-06-5.mol
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(2R)-(-)-Glycidyl tosylate Chemical Properties

Melting point:
46-49 °C(lit.)
Boiling point:
340.07°C (rough estimate)
alpha 
-18 º (c=2.5,CHCl3)
Density 
1.3749 (rough estimate)
refractive index 
1.5400 (estimate)
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
dioxane: 50 mg/mL, clear
form 
powder
color 
yellow to orange
Water Solubility 
decomposes
BRN 
3592142
CAS DataBase Reference
113826-06-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn,N,T
Risk Statements 
45-41-43-51/53-68
Safety Statements 
61-45-36/37/39-26-53
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
RR0510000
F 
3-10-21
Hazard Note 
Irritant
HazardClass 
9
HS Code 
29109000

MSDS

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(2R)-(-)-Glycidyl tosylate Usage And Synthesis

Chemical Properties

white crystalline powder

Uses

(2R)-(-)-Glycidyl Tosylate is a protected glycidol used as an intermediate in the preparation of neurochemicals.

Uses

(2R)-(-)-Glycidyl tosylate may be used to prepare:

  • 1-O-hexadecyl-sn-glycerol 3-O-p-toluenesulfonate by reacting with 1-hexadecanol in the presence of boron trifluoride etherate.
  • 4-Oxiranylmethoxy-(1H)-indole by reacting with 4-hydroxyindole in the presence of sodium hydride.
  • [18F]Epifluorohydin, an intermediate for preparing of [18F]fluoromisonidazole.
It can also be used as a starting material in the synthesis of 1,2-diacyl-sn-3-glycerophosphocholines.

Uses

Protected Glycidol, (2R)-(-)-Glycidyl tosylate is used as an intermediate in the preparation of neurochemicals.

(2R)-(-)-Glycidyl tosylate Preparation Products And Raw materials

Raw materials

Ethyl acetateDichloromethanePETROLEUM ETHERSodium sulfateTriethylamineSodium bicarbonateTosyl chloride4-Dimethylaminopyridine(S)-Oxiranemethanol

(2R)-(-)-Glycidyl tosylateSupplier

Beijing Bosennuokang Pharmaceutical Technology Co., Ltd. Gold
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400-6106006
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saleschina@alfa-asia.com
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