ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Aromatics > 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Basic information
- Product Name:
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- Synonyms:
-
- TRISYLHYDRAZIDE
- TPSH
- TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE
- 2,4,6-triisopropylbenzenesulphonohydrazide
- 2,4,6-Triisopropyl benzenesulphonohydrazine
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- 2,4,6-TRIISOPROPYL BENZENESULFONYL HYDRAZINE
- 2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE
- CAS:
- 39085-59-1
- MF:
- C15H26N2O2S
- MW:
- 298.44
- EINECS:
- 254-282-7
- Product Categories:
-
- Building Blocks
- Chemical Synthesis
- Organic Building Blocks
- Sulfonyl Hydrazides
- Sulfur Compounds
- Mol File:
- 39085-59-1.mol
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemical Properties
- Melting point:
- 110-112 °C (dec.) (lit.)
- Boiling point:
- 396.6±52.0 °C(Predicted)
- Density
- 1.075
- storage temp.
- -20°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- pka
- 9.51±0.10(Predicted)
- form
- Solid
- color
- Off-White
- Sensitive
- Moisture Sensitive
- BRN
- 2145001
- InChIKey
- GBQCDUBJTLROBV-UHFFFAOYSA-N
- CAS DataBase Reference
- 39085-59-1(CAS DataBase Reference)
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MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Usage And Synthesis
Chemical Properties
White crystal
Uses
As a reagent for generation of diimide
Uses
2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:
- Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
- Vinyl sulfones by sulfonylation reaction of vinyl bromides.
- Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDESupplier
Suzhou Highfine Biotech Co., Ltd Gold
- Tel
- 0512-68311833 13962195826
- wuhao@highfine.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE(39085-59-1)Related Product Information
- 2,4,6-Trimethylbenzenesulfonyl hydrazide
- 4-Ethylbenzenesulfonamide
- 2,4-Dimethylbenzenethiol
- 1,3,5-Triisopropylbenzene
- 2,4,6-TRIISOPROPYLBENZENESULFONAMIDE
- METHANESULFONYL HYDRAZIDE
- 2,6-DIMETHYLTHIOPHENOL
- Benzenesulfonyl hydrazide
- 4-Methylbenzenesulfonhydrazide
- 1,3,5-TRIETHYLBENZENE
- 2,4,6-TRIMETHYLTHIOPHENOL
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- (4-Isopropyl)thiophenol
- 2-Methylbenzene-1-sulfonamide
- antioxidant 1024
- Benzenesulfonamide, 4-(1-methylethyl)- (9CI)
- TRIFLUOROACETYLTRIPHENYLSILANE 2,4,6-TRIISOPROPYLBENZENESULFONYLHYDRAZONE
- Benzenesulfonamide, 2,4,6-trimethyl- (9CI)