Acid Mordant Orange 14
Acid Mordant Orange 14 Basic information
- Product Name:
- Acid Mordant Orange 14
- Synonyms:
-
- Alizarine Orange A
- C.I.58015
- C.I.Mordant Orange 14
- Acid mordant Orange 14
- 1,2-dihydroxy-3-nitroanthracene-9,10-dione
- Mordant orange 14
- 1,2-Dihydroxy-3-nitroanthraquinone
- 3-Nitroalizarine
- CAS:
- 568-93-4
- MF:
- C14H7NO6
- MW:
- 285.21
- EINECS:
- 209-310-2
- Mol File:
- 568-93-4.mol
Acid Mordant Orange 14 Chemical Properties
- Melting point:
- 244°C (rough estimate)
- Boiling point:
- 427.65°C (rough estimate)
- Density
- 1.3989 (rough estimate)
- refractive index
- 1.4700 (estimate)
- storage temp.
- -20°C Freezer, Under inert atmosphere
- solubility
- Dichloromethane (Slightly), DMSO (Slightly)
- form
- Solid
- pka
- 3.95±0.20(Predicted)
- color
- Dark Yellow to Very Dark Yellow
- NIST Chemistry Reference
- 3-Nitroalizarine(568-93-4)
Acid Mordant Orange 14 Usage And Synthesis
Uses
1,2-Dihydroxy-3-nitroanthraquinone (cas# 568-93-4) is useful for the development of allosteric PGAM1 inhibitors that are effective at suppressing the proliferation of pancreatic ductal adenocarcinoma cells.
Uses
Dyes cloth mordanted with Al orange, with Fe red to violet. As indicator in satd alcohol solution. pH 2.0-4.0, color change from golden orange to flat yellow (in water). pH 5.0-6.5 from yellow to purplish red.
Preparation
(a) in the presence of boric acid 1,2-Dihydroxyanthracene-9,10-dione?in sulfuric acid in the nitration; (b) 1,2-Dihydroxyanthracene-9,10-dione?in glacial acetic acid, toluene, petroleum ether or the nitration of nitrobenzene.
Properties and Applications
red light brown (chromium), red orange (aluminum). Insoluble in water. In concentrated sulfuric acid to orange, dilution after yellow.
Standard | Ironing Fastness | Light Fastness | Fulling | Persperation Fastness | Soaping | Water | |
Alkali | Acid | ||||||
ISO | 3-4 | 6 | 3-4 | 4 | 4 | 4 | 3-4 |
Purification Methods
Crystallise the dye from AcOH (m 244-245o). It has max at 494nm (H2SO4) and forms Cu salts. [Beilstein 8 H 447, 8 II 491, 8 III 3774, 8 IV 2359.]
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