1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Basic information
- Product Name:
- 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
- Synonyms:
-
- (+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
- 1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
- (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
- 2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE
- 4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide
- (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
- (R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID
- (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
- CAS:
- 35193-63-6
- MF:
- C20H13O4P
- MW:
- 348.29
- EINECS:
- 252-425-8
- Product Categories:
-
- Achiral Phosphine
- Aryl Phosphine
- chiral
- Phosphorus Catalysts
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Mol File:
- 35193-63-6.mol
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties
- Melting point:
- ≥300 °C
- Boiling point:
- 619.5±38.0 °C(Predicted)
- Density
- 1.49±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 1.14±0.20(Predicted)
- form
- Solid
- color
- White to Yellow to Orange
- Water Solubility
- Extremely low soluble in water.
- CAS DataBase Reference
- 35193-63-6(CAS DataBase Reference)
Safety Information
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-20/21/22
- Safety Statements
- 26-36-36/37/39-22
- WGK Germany
- 3
- RTECS
- RZ2475100
- F
- 10-23
- HS Code
- 2931499090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Usage And Synthesis
Chemical Properties
white to light yellow crystal powde
Uses
1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-63-6)Related Product Information
- Iron oxide black
- Clindamycin phosphate
- SULPHOSUCCINIC ACID ESTER
- Zinc oxide
- NITRIC OXIDE
- Magnesium oxide
- (S)-(-)-1,1'-Bi-2-naphthol
- ETHYLENE OXIDE
- 1,1'-Bi-2-naphthol
- Iron oxide
- Rutile
- naphthidine
- (Diethoxymethyl)diphenylphosphine oxide
- Water treatment agent POE
- NITROUS OXIDE
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%,(S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
- (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
- 1,1'-BINAPHTHYL