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ChemicalBook >  Product Catalog >  Organic Chemistry >  Inorganic acid Esters >  1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Basic information

Product Name:
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
Synonyms:
  • (+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
  • 1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
  • (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
  • 2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE
  • 4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide
  • (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
  • (R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID
  • (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
CAS:
35193-63-6
MF:
C20H13O4P
MW:
348.29
EINECS:
252-425-8
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • chiral
  • Phosphorus Catalysts
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
Mol File:
35193-63-6.mol
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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties

Melting point:
≥300 °C
Boiling point:
619.5±38.0 °C(Predicted)
Density 
1.49±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
1.14±0.20(Predicted)
form 
Solid
color 
White to Yellow to Orange
Water Solubility 
Extremely low soluble in water.
CAS DataBase Reference
35193-63-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39-22
WGK Germany 
3
RTECS 
RZ2475100
10-23
HS Code 
2931499090

MSDS

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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

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