(S)-VANOL Chemical Properties

Melting point:

200-204 °C

alpha 

+362° (c 1.0, THF)

Boiling point:

580.1±50.0 °C(Predicted)

Density 

1.251±0.06 g/cm3(Predicted)

storage temp. 

2-8°C

pka

7.71±0.50(Predicted)

form 

Powder

color 

white to pale yellow

optical activity

[α]20/D +310°, c = 1 in chloroform

InChI

1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H

InChIKey

NDTDVKKGYBULHF-UHFFFAOYSA-N

SMILES

Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6

CAS DataBase Reference

147702-13-4

Safety Information

Hazard Codes 

Xi

Risk Statements 

37/38-41

Safety Statements 

26-39

WGK Germany 

3

Storage Class

11 - Combustible Solids

Hazard Classifications

Aquatic Chronic 4
Eye Dam. 1
Skin Irrit. 2
STOT SE 3

(S)-VANOL Usage And Synthesis

Reaction

1. Chiral ligand used in catalytic asymmetric aziridination.
2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes. 

(S)-VANOL(147702-13-4)Related Product Information

• (R)-VANOL,(S)-VANOL,(2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(S)-VANOL,(2S)-(-)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (S)-VANOL
• 2,2'-binaphthalene
• o-Terphenyl
• (R)-VAPOL
• o-Quaterphenyl
• (S)-VANOL
• (S)-VAPOL phosphoric acid, (S)-2,2μ-Diphenyl-3,3μ-biphenanthryl-4,4μ-diyl phosphate, (S)-18-Hydroxy-8,9-diphenyl-diphenanthro[4,3-d:3μ,4μ-f][1,3,2]dioxaphosphepin-18-oxide