Basic information Reaction Safety Supplier Related

(S)-VANOL

Basic information Reaction Safety Supplier Related

(S)-VANOL Basic information

Product Name:
(S)-VANOL
Synonyms:
  • (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL
  • (2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL
  • (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol
  • (S)-VANOL
  • (R)-VANOL
  • (S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL)
  • (R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL
  • (2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
CAS:
147702-13-4
MF:
C32H22O2
MW:
438.52
Product Categories:
  • BINOL Series
  • Chiral Oxygen
Mol File:
147702-13-4.mol
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(S)-VANOL Chemical Properties

Melting point:
200-204 °C
alpha 
+362° (c 1.0, THF)
Boiling point:
580.1±50.0 °C(Predicted)
Density 
1.251±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
7.71±0.50(Predicted)
form 
Powder
color 
white to pale yellow
optical activity
[α]20/D +310°, c = 1 in chloroform
CAS DataBase Reference
147702-13-4
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Safety Information

Hazard Codes 
Xi
Risk Statements 
37/38-41
Safety Statements 
26-39
WGK Germany 
3
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(S)-VANOL Usage And Synthesis

Reaction

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes. 

Uses

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(S)-VANOLSupplier

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