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1,9-DECADIYNE

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1,9-DECADIYNE Basic information

Product Name:
1,9-DECADIYNE
Synonyms:
  • TIMTEC-BB SBB008879
  • 1,9-DECADIYNE
  • Decadiyne
  • deca-1,9-diyne
  • 1,9-Decanediyne
  • 1,9-Decadiyne,98%
  • 1,9-Decadiyne, 97+%
  • 1,9-Decadiyne (6CI, 7CI, 8CI, 9CI)
CAS:
1720-38-3
MF:
C10H14
MW:
134.22
EINECS:
217-012-9
Product Categories:
  • Acetylenes
  • Acetylenic Hydrocarbons
Mol File:
1720-38-3.mol
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1,9-DECADIYNE Chemical Properties

Melting point:
-6.35°C (estimate)
Boiling point:
80-81 °C (10 mmHg)
Density 
0.822
refractive index 
1.449-1.453
Flash point:
60°C
storage temp. 
Flammables area
form 
Liquid
Specific Gravity
0.816
color 
Clear yellow
Water Solubility 
Insoluble in water.
BRN 
1734594
CAS DataBase Reference
1720-38-3(CAS DataBase Reference)
EPA Substance Registry System
1,9-Decadiyne (1720-38-3)
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Safety Information

Risk Statements 
10
Safety Statements 
16
RIDADR 
1993
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29012900

MSDS

  • Language:English Provider:ACROS
  • Language:English Provider:ALFA
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1,9-DECADIYNE Usage And Synthesis

Chemical Properties

Clear yellow liquid

Uses

One-step synthesis of carbametacyclophane 3 from 1,9-decadiyne and diethyl acetylenedicarboxylate is described. The use of 1,9-decadiyne as a nucleophile led only to the monoalkynylation product, a selectivity that would be difficult to achieve with a catalytic in situ metalation process. 1,9-decadiyne reacts with iodobenzene (excess) to afford the bis-Sonogashira coupling product in excellent yield. 1,9-Decadiyne was dihydrated and gave 2,9-decanedione in 92% yield.

Definition

ChEBI: Deca-1,9-diyne is an alkadiyne and a terminal acetylenic compound.

1,9-DECADIYNESupplier

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