DIPHENYLIODONIUM CHLORIDE Chemical Properties

Melting point:

233-235 °C (subl.) (lit.)

Density 

1.6151 (estimate)

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

solubility 

soluble in Methanol

form 

Powder

color 

White to light cream-yellow

Water Solubility 

Soluble in water and methanol.

Sensitive 

Light Sensitive

Merck 

14,7464

BRN 

3574977

InChIKey

RSJLWBUYLGJOBD-UHFFFAOYSA-M

CAS DataBase Reference

1483-72-3(CAS DataBase Reference)

EPA Substance Registry System

Iodonium, diphenyl-, chloride (1483-72-3)

Safety Information

Hazard Codes 

T,Xi

Risk Statements 

25-36/37/38

Safety Statements 

26-36

RIDADR 

UN 2811 6.1/PG 3

WGK Germany 

3

RTECS 

NN6651666

F 

8

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

III

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

DIPHENYLIODONIUM CHLORIDE Usage And Synthesis

Chemical Properties

WHITE TO LIGHT CREAM-YELLOW POWDER

Uses

Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.

Uses

Reactant for:

• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
• Synthesis of acetylenic arylselenides
• Sonogashira coupling reactions for the preparation of aryl alkynes
• C-H functionalization for synthesis of (arylmethylene)oxindoles
• Arylation of anilines
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators

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