ChemicalBook > Product Catalog > Catalyst and Auxiliary > Precious Metal Catalysts > Dess-Martin periodinane
Dess-Martin periodinane
Dess-Martin periodinane Basic information
- Product Name:
- Dess-Martin periodinane
- Synonyms:
-
- Dess-Martin periodinane,D M P, TAPI
- dess-martin periodinate
- 1,1,1-Triacetoxy-1,2-benziodoxole-IV-3(1H)-one
- 1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV
- 1,1,1-Triacetoxy-3H-1,2-benziodoxole-IV-3-one
- Martin's reagent
- 1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M
- Dess-Martin periodinane solution
- CAS:
- 87413-09-0
- MF:
- C13H13IO8
- MW:
- 424.14
- EINECS:
- 672-328-8
- Product Categories:
-
- Hypervalent Iodine
- Synthetic Reagents
- Hypervalent Iodine Compounds
- Oxidation
- Synthetic Organic Chemistry
- Fused Ring Systems
- Mol File:
- 87413-09-0.mol
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Dess-Martin periodinane Chemical Properties
- Melting point:
- 130-133 °C (lit.)
- Boiling point:
- 40 °C
- Density
- 1.369 g/mL at 25 °C
- Flash point:
- >221 °F
- storage temp.
- -20°C
- solubility
- Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
- form
- Liquid
- color
- Colorless to light yellow
- Sensitive
- Light Sensitive
- Merck
- 14,2933
- BRN
- 4548207
- Stability:
- Light Sensitive
- InChI
- InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
- InChIKey
- NKLCNNUWBJBICK-UHFFFAOYSA-N
- SMILES
- I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
- CAS DataBase Reference
- 87413-09-0(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- Xn,O,Xi
- Risk Statements
- 22-36/37/38-40-8-20/21/22-44
- Safety Statements
- 26-36-36/37-24/25-23-17-45-36/37/39
- RIDADR
- UN 1593 6.1/PG 3
- WGK Germany
- 3
- Hazard Note
- Harmful/Light sensitive
- TSCA
- No
- HazardClass
- 5.1
- PackingGroup
- Ⅲ
- HS Code
- 29349990
MSDS
- Language:English Provider:(1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Dess-Martin periodinane Usage And Synthesis
Chemical Properties
White Crystalline powder
Uses
Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.
Uses
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
Uses
Oxidizing reagent.
Dess-Martin periodinane Preparation Products And Raw materials
Raw materials
Acetic acid glacialAcetic anhydridep-Toluenesulfonic acidPotassium bromate 2-Iodobenzoic acid2-Iodoxybenzoic acid
Preparation Products
Dess-Martin periodinaneSupplier
Herd chemical Gold
- Tel
- 18051217850
- jingwen.li@herdchem.com
Shanghai Yolne Chemical Co., Ltd. Gold
- Tel
- 021-62960152
- 934678158@qq.com
Meryer (Shanghai) Chemical Technology Co., Ltd. Gold
- Tel
- 4006608290; 18621169109
- market03@meryer.com
Jikang Chemical Industry Co. , Ltd. Gold
- Tel
- 0573-85609002 18157336032
- zhejia01@163.com
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. Gold
- Tel
- 025-66099280 17798518460
- cfzhang@aikonchem.com
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Dess-Martin periodinane(87413-09-0)Related Product Information
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- 2-Amino-1,9-dihydro-9-[(1S,3R,4S)-4-(benzyloxy)-3-(benzyloxymethyl)-2-methylenecyclopentyl]-6H-purin-6-one
- Entecavir
- 6-(Benzyloxy)-9-((1S,3S)-4-(benzyloxy)-3-((benzyloxy)methyl)-2-methylenecyclopentyl)-N-((4-methoxyphenyl)diphenylmethyl)-9H-purin-2-amine
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- HATU
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- Dess-Martin periodinane