Dess-Martin periodinane

Product Name: Dess-Martin periodinane
CAS No.: 87413-09-0
Chemical Name: Dess-Martin periodinane
Synonyms: DESS-MARTIN;Dess-Martin periodane;DESS-MARTIN REAGENT;PERIODINANE;DESS-MARTINE;1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE;Dess-Martin periodinane,D M P, TAPI;3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate;1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE;Martin's reagent
CBNumber: CB0776475
Molecular Formula: C13H13IO8
Formula Weight: 424.14
MOL File: 87413-09-0.mol

More

Less

Dess-Martin periodinane Property

Melting point:: 130-133 °C (lit.)
Boiling point:: 40 °C
Density: 1.369 g/mL at 25 °C
Flash point:: >221 °F
storage temp.: -20°C
solubility: Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form: Liquid
color: Colorless to light yellow
Sensitive: Light Sensitive
Merck: 14,2933
BRN: 4548207
Stability:: Light Sensitive
InChI: InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey: NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES: I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference: 87413-09-0(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xn,O,Xi
Risk Statements: 22-36/37/38-40-8-20/21/22-44
Safety Statements: 26-36-36/37-24/25-23-17-45-36/37/39
RIDADR: UN 1593 6.1/PG 3
WGK Germany: 3
Hazard Note: Harmful/Light sensitive
TSCA: No
HazardClass: 5.1
PackingGroup: Ⅲ
HS Code: 29349990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 274623
Product name: Dess-Martin periodinane
Purity: 97%
Packaging: 5g
Price: $136
Updated: 2024/03/01

Sigma-Aldrich

Product number: 274623
Product name: Dess-Martin periodinane
Purity: 97%
Packaging: 25g
Price: $648
Updated: 2024/03/01

TCI Chemical

Product number: D2045
Product name: Dess-Martin Periodinane
Purity: >95.0%(T)
Packaging: 1g
Price: $35
Updated: 2024/03/01

TCI Chemical

Product number: D2045
Product name: Dess-Martin Periodinane
Purity: >95.0%(T)
Packaging: 5g
Price: $106
Updated: 2024/03/01

Alfa Aesar

Product number: L15779
Product name: Dess-Martin periodinane
Packaging: 1g
Price: $39.3
Updated: 2024/03/01

More

Less

Dess-Martin periodinane Chemical Properties,Usage,Production

Description

Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.

Chemical Properties

White Crystalline powder

Uses

Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

Uses

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Uses

Oxidizing reagent.

Advantages

Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups

Dess-Martin periodinane Preparation Products And Raw materials

Raw materials

2-Iodobenzoic acid p-Toluenesulfonic acid Acetic anhydride 2-Iodoxybenzoic acid Potassium bromate Acetic acid

Preparation Products

C-(3,4-DIHYDRO-2H-BENZO[1,4]OXAZIN-3-YL)-METHYLAMINE

More

Less

Dess-Martin periodinane Suppliers

Americas 1 Belgium 4 Canada 3 China 395 Czech Republic 1 Europe 3 France 2 Germany 7 India 64 Japan 6 Poland 1 Spain 2 Switzerland 3 The Netherlands 2 United Kingdom 24 United States 59 Global 577

Herd chemical

Tel: 18051217850
Email: jingwen.li@herdchem.com
Country: China
ProdList: 19
Advantage: 58

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

Jikang Chemical Industry Co. , Ltd.

Tel: 0573-85609002 18157336032
Email: zhejia01@163.com
Country: China
ProdList: 7858
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

Shenniao Chemical Technology (Shanghai) Co., Ltd.

Tel: 021-18221934698 18221934698
Email: 1024868512@qq.com
Country: China
ProdList: 88
Advantage: 58

Innochem(Beijing) Technology Co.,Ltd.

Tel: 10-56541685 13070143590
Fax: 010-56541685
Email: sales@innochem.cn
Country: China
ProdList: 99
Advantage: 57

Nantong Haigine Pharma Technology Co., Ltd

Tel: 0513-86266699-8010 13166080856
Fax: QQ1355175393
Country: China
ProdList: 186
Advantage: 58

Shanghai Boyle Chemical Co., Ltd.

Tel
Fax: 86-21-57758967
Email: sales@boylechem.com
Country: China
ProdList: 2923
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

More

Less

View Lastest Price from Dess-Martin periodinane manufacturers

Hunan aslsen technology co.,ltd

Product: 2-benziodoxol-(1H)-one 87413-09-0
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 1000000000 ton
Release date: 2024-04-10

ANHUI WITOP BIOTECH CO., LTD

Product: Dess-Martin periodinane 87413-09-0
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 10 tons
Release date: 2021-03-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: Dess-Martin periodinane 87413-09-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

87413-09-0, Dess-Martin periodinaneRelated Search:

ACETYLTHIOCHOLINE IODIDE 4-Acetoxystyrene Dihydromyrcenol Sodium triacetoxyborohydride ACETYLCHOLINE IODIDE Benzyloxyacetyl chloride (1S,2S,3S,5S)-5-(2-Amino-6-(benzyloxy)-9H-purin-9-yl)-3-(benzyloxy)-2-(benzyloxymethyl)cyclopentanol 2-Amino-1,9-dihydro-9-[(1S,3R,4S)-4-(benzyloxy)-3-(benzyloxymethyl)-2-methylenecyclopentyl]-6H-purin-6-one Entecavir 6-(Benzyloxy)-9-((1S,3S)-4-(benzyloxy)-3-((benzyloxy)methyl)-2-methylenecyclopentyl)-N-((4-methoxyphenyl)diphenylmethyl)-9H-purin-2-amine Methyl (R)-2-(Benzylamino)-3-hydroxypropanoate N-Benzyl-DL-serine Methyl Ester HATU Dichloromethane (Diacetoxyiodo)benzene 2-Iodobenzoic acid Dess-Martin periodinane

Dess-Martin periodinane,D M P, TAPI

dess-martin periodinate

1,1,1-Triacetoxy-1,2-benziodoxole-IV-3(1H)-one

1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV

1,1,1-Triacetoxy-3H-1,2-benziodoxole-IV-3-one

Martin's reagent

1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M

Dess-Martin periodinane solution

Dess-Martin periodinane,1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one

Acetic acid, 1,1',1''-(3-oxo-1.lambda.5-1,2-benziodoxol-1(3H)-ylidyne) ester

Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal

1,1-dihydro-1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one

1,1,1-Triacetoxy-1,2-benziodoxol-3(1H)-one(Dess-Martin periodinane)

Dess-Martin periodinane, 15 wt.% solution in dichloroMethane 50ML

Dess-Martin Periodinane (Technical Grade)

Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, J&KSeal

Dess-Martin periodinane 97%

Dess-Martin periodinane solution 0.3 M in Methylene chloride

Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, SpcSeal

Deiss Martin reagent

DESS-MARTIN

DESS-MARTIN PERIODINANE

DESS-MARTIN REAGENT

DESSS-MARTIN PERIODINANE

1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE

1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE

1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE

ACETIC ACID 1,1-DIACETOXY-3-OXO-1L5-IODA-2-OXA-INDAN-1-YL ESTER

TRIACETOXYPERIODINANE

Dess-Martinperiodinane,97%

Dess-Martin periodane

3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate

1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE(DESSMARTINE)

1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE (DESS-MARTIN PERIODINANE)

DESS-MARTIN(1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE)

Dess Martin Periodinane 0.3M in DCM

Dess-Martin Periodinane (8-12% in Dichloromethane)

(1,1-diacetyloxy-3-oxo-1λ5,2-benziodoxol-1-yl) Acetate

RARECHEM AR PA 0035

Triacetoxyperiodinane (Dess-Martin periodinane)

DESS-MARTIN PERIODINANE, 0.3M SOLUTION &

(7,7-DIACETYLOXY-9-OXO-7$L^{5}-IODA-8-OXABICYCLO[4.3.0]NONA-1,3,5-TRIEN-7-YL) ACETATE

DesmartinPeriodinane

DmpDess-MartinPeriodinane

Dess-Martin periodinane, 15 wt.% solution in dichloromethane

1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro-

1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE(DESS-MARTINPERIODINANE)

DESS-MARTINE

DMP DESS-MARTIN PERIODINANE TRIACETOXYPERIODINANE

Dess-Martin Periodinane Triacetoxyperiodinane

Dess-martin oxidizer

PERIODINANE

1,1-bis(acetyloxy)-3-oxo-3H-1λ,2-benziodaoxol-1-yl acetate

Dess-Martin Periodinane (DMP)

Aceticacid,1,1',1''-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne)ester

Dess-Martin periodinane, 15 wt.% solution in CH2Cl2

Days Martin oxidant

Dess-MartinPeriodinane&gt