ChemicalBook > CAS DataBase List > (Diacetoxyiodo)benzene

(Diacetoxyiodo)benzene

Product Name
(Diacetoxyiodo)benzene
CAS No.
3240-34-4
Chemical Name
(Diacetoxyiodo)benzene
Synonyms
PIA;DAIB;BAIB;mAVO3;S-PIA;KIAA1999;MGC39830;PhI(OAc)2;I-diacetate;Iodobenzene I
CBNumber
CB2222138
Molecular Formula
C10H11IO4
Formula Weight
322.1
MOL File
3240-34-4.mol
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(Diacetoxyiodo)benzene Property

Melting point:
161-163 °C (lit.)
Density 
1.6865 (estimate)
refractive index 
n/D 1.444
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
INSOLUBLE
form 
Solution
color 
Clear to cloudy colorless to yellow
Water Solubility 
INSOLUBLE
Sensitive 
Light Sensitive
BRN 
1879369
InChIKey
ZBIKORITPGTTGI-UHFFFAOYSA-N
CAS DataBase Reference
3240-34-4(CAS DataBase Reference)
NIST Chemistry Reference
Iodobenzene diacetate(3240-34-4)
EPA Substance Registry System
Iodine, bis(acetato-.kappa.O)phenyl- (3240-34-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-37/39-26-36/37/39-27
RIDADR 
1479
WGK Germany 
3
RTECS 
DA3525000
4.10-8
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29310095
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
178721
Product name
(Diacetoxyiodo)benzene
Purity
98%
Packaging
5g
Price
$19.1
Updated
2021/03/22
Sigma-Aldrich
Product number
178721
Product name
(Diacetoxyiodo)benzene
Purity
98%
Packaging
25g
Price
$57.3
Updated
2021/03/22
TCI Chemical
Product number
I0330
Product name
Iodobenzene Diacetate
Purity
>97.0%(T)
Packaging
10g
Price
$24
Updated
2021/03/22
TCI Chemical
Product number
I0330
Product name
Iodobenzene Diacetate
Purity
>97.0%(T)
Packaging
25g
Price
$47
Updated
2021/03/22
Alfa Aesar
Product number
B24531
Product name
Iodosobenzene diacetate, 98+%
Packaging
25g
Price
$54.4
Updated
2021/03/22
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(Diacetoxyiodo)benzene Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Uses

(Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic a cid into the corresponding aldehydes, ketones and nitriles.

Purification Methods

The purity of diacetoxyiodobenzene can be checked by treatment with H2SO4 then KI and the liberated I2 is estimated with standard thiosulfate. It has been recrystallised from 5M acetic acid and dried overnight in a vacuum desiccator over CaCl2. The surface of the crystals may become slightly yellow but this does not affect its usefulness. [Sharefkin & Saltzman Org Synth Coll Vol V 600 1973, Beilstein 5 IV 693.]

(Diacetoxyiodo)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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(Diacetoxyiodo)benzene Suppliers

SiChuang NanBu Honesty Technology Co., Ltd.
Tel
0838-5675166
Fax
0838-5675535
Email
nbcxkj@126.com
Country
China
ProdList
669
Advantage
55
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
Manac (SHANGHAI) TRADING CO., LTD
Tel
021-32503616
Fax
021-32503616
Email
sales@manac-inc.com.cn
Country
China
ProdList
145
Advantage
60
Energy Chemical
Tel
021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
43496
Advantage
61
Shanghai Yurlic Chemical S&T Co.Ltd.
Tel
021-37285141- ;021-37285142- ;
Email
yancf@yulibiotech.com;david@yulibiotech.com;yuki@yulibiotech.com
Country
China
ProdList
170
Advantage
58
Shanghai RC Chemicals Co. Ltd
Tel
86-21-50322175; 50322680;021-50322680-
Fax
86-21-50322176
Email
rcchemicals@vip.163.com;chad@rcc.net.cn
Country
China
ProdList
287
Advantage
55
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280-
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
21578
Advantage
55
Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-83945878-
Fax
022-83945176
Email
export@creasyn.com
Country
China
ProdList
756
Advantage
68
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Sichuan Ruibo Technology Co., Ltd
Tel
+86-817-5586080
Fax
+86-817-5527378
Email
sales@scrbkj.com
Country
China
ProdList
42
Advantage
69
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View Lastest Price from (Diacetoxyiodo)benzene manufacturers

Jinan Finer Chemical Co., Ltd
Product
Iodobenzene diacetate 3240-34-4
Price
US $50.00-80.00/kg
Min. Order
100kg
Purity
99%
Supply Ability
200mt
Release date
2019-03-15
Hebei Guanlang Biotechnology Co., Ltd.
Product
(Diacetoxyiodo)benzene 3240-34-4
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2021-07-21
Shaanxi Dideu Medichem Co. Ltd
Product
(Diacetoxyiodo)benzene 3240-34-4
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-06

3240-34-4, (Diacetoxyiodo)benzeneRelated Search:


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  • bis(acetato-o)phenyl-iodin
  • Iodine, bis(acetato-O)phenyl-
  • iodoso-benzendiacetate
  • phenyliodine(iii)diacetate
  • Phenyliodo diacetate
  • phenyliododiacetate
  • Phenyliodoso acetate
  • Phenyliodoso diacetate
  • phenyliodosodiacetate
  • phenyliodosyldiacetate
  • Iodobenzene 1,1-diacetate
  • acetic acid coMpound with iodosylbenzene (2:1)
  • (Diacetoxyiodo)benzene, Bis(acetoxy)(phenyl)iodane
  • Iodosobenzene diacetate ,PIDA
  • Theiodoethyl ester two
  • acetic acid coMpound with iodobenzene (2:1)
  • DKFZp686B11164
  • KIAA1999
  • mAVO3
  • MGC39830
  • Monoclonal Anti-RICTOR antibody produced in mouse
  • PhI(OAc)2
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  • [acetyloxy(phenyl)-$l^{3}-iodanyl] acetate
  • bis(acetyloxy)(phenyl)-lambda~
  • (Diacetoxyiodo)benzene≥ 99% (HPLC)
  • [acetyloxy(phenyl)-λ<sup>3</sup>-iodanyl] acetate
  • -iodanyl acetate
  • bis(acetato-O)phenyliodine
  • Ethyl 2-(4-formylphenyl)2-methylpropionatephenyliodine diacetate
  • (Diacetoxyiodo)benzene=Phenyliodosodiacetate