[Bis(trifluoroacetoxy)iodo]benzene

Product Name: [Bis(trifluoroacetoxy)iodo]benzene
CAS No.: 2712-78-9
Chemical Name: [Bis(trifluoroacetoxy)iodo]benzene
Synonyms: PIFA;BTI;DFAIB;Bacillus thuringiensis israelensis;[Bis(trifluoroacetox;LABOTEST-BB LT00454809;uoroacetoxy)iodo]benzene;[Bis(trifluoroacetoxy)iodo]ben;1Bis-trifluoroacetoxyiodobenzene;IODOBENZENE BIS(TRIFLUOROACETATE)
CBNumber: CB9419191
Molecular Formula: C10H5F6IO4
Formula Weight: 430.04
MOL File: 2712-78-9.mol

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[Bis(trifluoroacetoxy)iodo]benzene Property

Melting point:: 121-125 °C(lit.)
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), Dichloromethane (Slightly), DMSO (Slightly)
form: Crystalline Powder
color: White to pale yellow
Water Solubility: insoluble
Sensitive: Moisture & Light Sensitive
BRN: 764767
Stability:: Air and Moisture Sensitive
CAS DataBase Reference: 2712-78-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
F: 4.10-8-9-21
Hazard Note: Irritant/Keep Cold
HazardClass: IRRITANT, KEEP COLD, LIGHT SENSITIVE
HS Code: 29036990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 15230
Product name: [Bis(trifluoroacetoxy)iodo]benzene
Purity: purum, ≥95.0% (AT)
Packaging: 10g
Price: $91.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 15230
Product name: [Bis(trifluoroacetoxy)iodo]benzene
Purity: purum, ≥95.0% (AT)
Packaging: 50g
Price: $200
Updated: 2024/03/01

Alfa Aesar

Product number: L15141
Product name: [Bis(trifluoroacetoxy)iodo]benzene, 97%
Packaging: 5g
Price: $45.8
Updated: 2024/03/01

Alfa Aesar

Product number: L15141
Product name: [Bis(trifluoroacetoxy)iodo]benzene, 97%
Packaging: 25g
Price: $118
Updated: 2024/03/01

Sigma-Aldrich

Product number: 232130
Product name: [Bis(trifluoroacetoxy)iodo]benzene
Purity: 97%
Packaging: 10g
Price: $91.9
Updated: 2024/03/01

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[Bis(trifluoroacetoxy)iodo]benzene Chemical Properties,Usage,Production

Chemical Properties

White to pale yellow crystalline powder

Uses

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Uses

In oxidation, cyclization, dehydrogenation, and dearomatization reactions.

reaction suitability

reagent type: oxidant

Purification Methods

Crystallise the iodo compound from warm trifluoroacetic acid and dry it over NaOH pellets. Recrystallise it also from Me2CO/pet ether. Its melting point depends on the heating rate. [Spyroudis & Varvoglis Synthesis 445 1975, application: Almond et al. Org Synth 66 132 1988.]

[Bis(trifluoroacetoxy)iodo]benzene Preparation Products And Raw materials

Raw materials

Iodobenzene Hexane Hydrogen peroxide Sodium percarbonate Trifluoroacetic anhydride Dichloromethane

Preparation Products

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[Bis(trifluoroacetoxy)iodo]benzene Suppliers

Belgium 1 China 262 Czech 1 Europe 3 France 2 Germany 5 India 13 Japan 2 Russia 1 Slovakia 1 South Korea 1 Switzerland 1 Ukraine 1 United Kingdom 13 United States 25 Global 332

Suzhou Highfine Biotech Co., Ltd

Tel: 0512-68417696 18306209966
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Email: linda@highfine.com
Country: China
ProdList: 499
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SiChuang NanBu Honesty Technology Co., Ltd.

Tel: 0838-5675166 15883665058
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Country: China
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Shanghai Yurlic Chemical S&T Co.Ltd.

Tel: 021-37285141 15618858630
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Email: yancf@yulibiotech.com
Country: China
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J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
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INTATRADE GmbH

Tel: +49 3493/605464
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Email: sales@intatrade.de
Country: Germany
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3B Pharmachem (Wuhan) International Co.,Ltd.

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future industrial shanghai co., ltd

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ProdList: 1995
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Chembest Research Laboratories Limited

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Email: sales@BioChemBest.com
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Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

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View Lastest Price from [Bis(trifluoroacetoxy)iodo]benzene manufacturers

Shanghai UCHEM Inc.

Product: [Bis(trifluoroacetoxy)iodo]benzene 2712-78-9
Price: US $8.00-129.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 25kg
Release date: 2023-12-14

WUHAN FORTUNA CHEMICAL CO., LTD

Product: [Bis(trifluoroacetoxy)iodo]benzene 2712-78-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-31

Shaanxi Dideu Medichem Co. Ltd

Product: [Bis(trifluoroacetoxy)iodo]benzene 2712-78-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KG
Release date: 2024-08-08

2712-78-9, [Bis(trifluoroacetoxy)iodo]benzeneRelated Search:

(Trifluoromethoxy)benzene Iodine Ethylbenzene Anisole Allylbenzene Sodium triacetoxyborohydride (Diacetoxyiodo)benzene Acetoxyacetic acid Benzene Acetoxyacetyl chloride Povidone iodine 2-Phenoxyethanol Sliver bis(trifluoromethane sulfonimide) Cobalt bis(trifluoroMethylsulfonyl)iMide Silicon tetraacetate BIS(DICYCLOHEXYLPHOSPHINO)METHANE Bis(dibenzylideneacetone)palladium Bis(2-dicyclohexylphosphinophenyl)ether, 98%

IODOSOBENZENE I,I-BIS(TRIFLUOROACETATE)

IODINE, PHENYLBIS(TRIFLUOROACETATO)-

IODOBENZENE BIS(TRIFLUOROACETATE)

IODOBENZENE I,I-BIS(TRIFLUOROACETATE)

BTI

BIS(TRIFLUORACETOXY)- IODOBENZENE

[BIS(TRIFLUOROACETOXY)IODO]BENZENE

[Bis(trifluoroacetoxy)](phenyl)iodane

[Bis(trifluoroacetoxy)iodo]ben

Iodobenzene 1,1-bis(trifluoroacetate)

[Bis(trifluoroacetoxy)iodo]benzene purum, >=95.0% (AT)

[Bis(trifluoroacetoxy)iodo]benzene SynonyMs Phenylbis(trifluoroacetato-O)iodine

[phenyl-(2,2,2-trifluoroacetyl)oxy-3-iodanyl] 2,2,2-trifluoroacetate

[phenyl-(2,2,2-trifluoroacetyl)oxy-λ<sup>3</sup>-iodanyl] 2,2,2-trifluoroacetate

uoroacetoxy)iodo]benzene

PIFA

BTI~Iodosobenzene bis(trifluoroacetate)~Phenyliodine(III) bis(trifluoroacetate)~PIFA

phenylbis(trifluoroacetato-O)iodine

Bis-Trifluoroacetoxyiodobenzene99%

Bis-Trifluoroacetoxyiodobenzene 99%

Iodosobenzene-bis(trifluoroacetate)

Phenyliodine(III)bis(trifluoroacetate)

Bis(trifluoroacetoxy)iodoübenzene, 97%

BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA

[Bis(trifluoroacetoxy)iodo(III)]benzene

[Di(trifluoroacetoxy)iodo(III)]benzene

Bis(trifluoroacetic acid)phenyliodine(III) salt

Phenylbis(trifluoroacetyloxy) iodine(III)

Iodine, phenylbis(trifluoroacetato-.kappa.O)-

bis(I,I-trifluoroacetoxy)iodobenzene

[Bis(trifluoroacetoxy)iodo]benzene,98%

1Bis-trifluoroacetoxyiodobenzene

[Bis(trifluoroethoxy)iodo]benzene

[Bis(trifluoroacetoxy)iodo]benzene,BTI, Iodobenzene I,I-bis(trifluoroacetate), PIFA

[Bis(trifluoroacetox

[Bis(trifluoroacetoxy)iodo]benzene, 98% 10GR

[Bis(trifluoroacetoxy)iodo]benzene, 98% 50GR

LABOTEST-BB LT00454809

DFAIB

BIS(TRIFLUOROACETOXY)IODOBENZENE FOR SYN

[Bis(trifluoroacetoxy)iodo]benzene, 98%, for synthesis

[Bis(trifluoroacetoxy)iodo]benzene &gt

Iodine, phenylbis(2,2,2-trifluoroacetato-κO)-

[Bis(trifluoroacetoxy)iodo]benzene ISO 9001：2015 REACH

Bacillus thuringiensis israelensis

[phenyl-(2,2,2-trifluoroacetyl)oxy-

2712-78-9

C10H3F6IO4

C10H5F6IO4

C10H5O4F6I

CF3CO22IC6H5

C10F6H5I1O4

C10H9F6IO2

Oxidation

Synthetic Reagents

Hypervalent Iodine

Carbazoles