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Trifluoroacetic anhydride

Product Name
Trifluoroacetic anhydride
CAS No.
407-25-0
Chemical Name
Trifluoroacetic anhydride
Synonyms
TFAA;trifluoroacetic;Trifluoroacetic anhy;trimethylamine (TMA);TRIFLUOROACETO ANHYDRIDE;TIFLUOROACETIC ANHYDRIDE;RIFLUOROACETIC ANHYDRIDE;TRIFLUORACETIC ANHYDRIDE;perfluoroaceticanhydride;Perfluoracetic anhydride
CBNumber
CB6853606
Molecular Formula
C4F6O3
Formula Weight
210.03
MOL File
407-25-0.mol
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Trifluoroacetic anhydride Property

Melting point:
-63.5 °C
Boiling point:
39.5-40 °C(lit.)
Density 
1.511 g/mL at 20 °C(lit.)
vapor pressure 
6.28 psi ( 20 °C)
refractive index 
n20/D 1.3(lit.)
Flash point:
-26 °C
storage temp. 
2-8°C
solubility 
Miscible with benzene, dichloromethane, diethyl ether, dimethylformamide, terahydrofuran and acetonitrile.
form 
Liquid
Specific Gravity
1.487
color 
Clear
Water Solubility 
Hydrolysis
Sensitive 
Moisture Sensitive
BRN 
746197
Stability:
Stable, but moisture sensitive. Reacts with water to liberate hydrogen (flammable!). Incompatible with water, strong oxidizing agents.
CAS DataBase Reference
407-25-0(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, trifluoro-, anhydride(407-25-0)
EPA Substance Registry System
Acetic acid, trifluoro-, anhydride(407-25-0)
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Safety

Hazard Codes 
C,T
Risk Statements 
14-20-35-52/53-34-23/24/25
Safety Statements 
26-36/37/39-43-45-61-9-8-28A-27
RIDADR 
UN 3265 8/PG 1
WGK Germany 
2
RTECS 
AJ9800000
3-10
Hazard Note 
Corrosive/Moisture Sensitive
TSCA 
T
HazardClass 
8
PackingGroup 
I
HS Code 
29159080
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H332Harmful if inhaled

H402Harmful to aquatic life

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
106232
Product name
Trifluoroacetic anhydride
Purity
ReagentPlus , ≥99%
Packaging
10x1g
Price
$177
Updated
2018/11/13
Sigma-Aldrich
Product number
106232
Product name
Trifluoroacetic anhydride
Purity
ReagentPlus , ≥99%
Packaging
3kg
Price
$1100
Updated
2018/11/13
TCI Chemical
Product number
T0433
Product name
Trifluoroacetic Anhydride
Purity
>98.0%(GC)
Packaging
20mL
Price
$29
Updated
2018/11/22
TCI Chemical
Product number
T0433
Product name
Trifluoroacetic Anhydride
Purity
>98.0%(GC)
Packaging
100mL
Price
$94
Updated
2018/11/22
Alfa Aesar
Product number
A13614
Product name
Trifluoroacetic anhydride
Purity
99+%
Packaging
25g
Price
$20.6
Updated
2018/11/20
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Trifluoroacetic anhydride Chemical Properties,Usage,Production

Chemical Properties

Clear, colorless liquid

Uses

Used as analytical reagents, solvents, catalysts, dehydration condensing agent, protection agent of trifluoroacetylation of carboxyl and amino; used as Intermediate of fluorine fine chemicals, pharmaceutical, agrochemical.

Purification Methods

Purification by distilling over KMnO4, as for the acid above, is EXTREMELY DANGEROUS due to the possiblility of EXPLOSION. It is best purified by distilling from P2O5 slowly, and collecting the fraction boiling at 39.5o. Store it in a dry atmosphere. Highly TOXIC vapour and attacks skin, work in an efficient fume hood. [Beilstein 2 IV 469.]

Trifluoroacetic anhydride Preparation Products And Raw materials

Raw materials

Preparation Products

1-[4-(TRIFLUOROMETHYL)PYRIMID-2-YL]PIPERAZINE 2-CYANO-4-PYRIDINE CARBOXYLIC ACID 2-Hydroxy-4-(trifluoromethyl)pyrimidine 2-Hydroxymethyl-5-bromopyridine 2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carbonitrile 2-Chloro-4-(trifluoromethyl)pyrimidine [BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE 6-Aminobenzothiazole 2-HYDROXY-6-(TRIFLUOROMETHYL)NICOTINIC ACID 2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carboxamide (2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidin-4-yl)methanamine 2,6-DICHLORO-4-ISOCYANATOPYRIDINE Ethyl 2-(4-hydroxypiperidin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carboxylate Ethyl 2-(4-(ethoxycarbonyl)piperidin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carboxylate Ethyl 2-(4-(hydroxymethyl)piperidin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carboxylate 3-(Trifluoromethyl)pyrazole 1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE Chlorfenapyr (2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidin-4-yl)methanol 3-(Trifluoromethyl)-1,2,4-triazolo[4,3-a]pyrazine 4-CHLORO-ALPHA-[METHYL(TRIFLUOROACETYL)AMINO]-BENZENEACETIC ACID 2-(METHYLTHIO)-4-(TRIFLUOROMETHYL)PYRIMIDINE tert-Butyl 4-[4-(trifluoromethyl)pyrimidin-2-yl]piperazine-1-carboxylate ,97% 3-Nitroisonicotinic acid Ethyl 2-(4-methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carboxylate 3-(Trifluoromethyl)-5,6,7,8-tetrahydro-[1,2,4]triazolo[4,3-a]pyrazine hydrochloride 5-Iodo-2,4-dimethoxypyrimidine N10-(TRIFLUOROACETYL)PTEROIC ACID 3-Amino-4-nitrobenzitrifluoride 2-(TRIFLUOROACETYL)THIOPHENE 2-BROMO-4-(TRIFLUOROMETHYL)PYRIMIDINE 2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carbaldehyde Epirubicin 2-(Bromomethyl)-6-methylpyridine 5-Bromopyridine-2-carbaldehyde ETHYL 5-AMINO-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE-4-CARBOXYLATE 2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidine-4-carboxylic acid 2-(4-Methylpiperazin-1-yl)-6-(trifluoromethyl)pyrimidin-4-amine 3-CHLORO-5-NITROPYRIDINE [Bis(trifluoroacetoxy)iodo]benzene
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Trifluoroacetic anhydride Suppliers

Adamas Reagent, Ltd.
Tel
400-600-9262
Email
bxy@titansci.com
Country
China
ProdList
13919
Advantage
59
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30163
Advantage
84
Beijing Ouhe Technology Co., Ltd
Tel
+86-10-4006331231;+86-10-51280831;+86-10-82967028
Fax
+86-10-82967029
Email
sales@ouhechem.com
Country
China
ProdList
12495
Advantage
60
Ji'nan Langhua Chemical Co. Ltd.
Tel
+86-0531-85906691
Fax
+86-0531-85906692
Email
325912680@qq.com
Country
China
ProdList
106
Advantage
50
Jinan LangHua Chemical Co., Ltd.
Tel
+86-531-85906692
Fax
+86-531-85906692
Email
325912681@qq.com
Country
China
ProdList
215
Advantage
58
Shanghai Kangman Biological Technology Co., Ltd.
Tel
18800375331
Fax
021-50908862
Email
kangmansales@163.com
Country
China
ProdList
7596
Advantage
55
Energy Chemical
Tel
021-58432009 / 400-005-6266
Fax
021-58436166-800
Email
info@energy-chemical.com
Country
China
ProdList
44025
Advantage
61
SHANG FLUORO
Tel
021-65170832 13331983812 18019716620
Fax
021-66315200
Email
shangfluoro@hotmail.com
Country
China
ProdList
412
Advantage
60
J & K SCIENTIFIC LTD.
Tel
400-666-7788 +86-10-82848833
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
+86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
Fax
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)
Email
sh@meryer.com
Country
China
ProdList
40269
Advantage
62
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View Lastest Price from Trifluoroacetic anhydride manufacturers

career henan chemical co
Product
Trifluoroacetic anhydride 407-25-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1
Release date
2018-08-06

407-25-0, Trifluoroacetic anhydrideRelated Search:


  • TRIFLUOROACETIC ANHYDRIDE, 99%TRIFLUOROACETIC ANHYDRIDE, 99%TRIFLUOROACETIC ANHYDRIDE, 99%TRIFLUOROACETIC ANHYDRIDE, 99%
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  • Bis(2,2,2-trifluoroacetic acid)anhydride
  • Bis(trifluoroacetic acid) anhydride
  • Di(trifluoroacetic)anhydride
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  • RIFLUOROACETIC ANHYDRIDE
  • trifluoroacetyl 2,2,2-trifluoroacetate
  • Trifluoroacetic anhydride, 99+% 100GR
  • Trifluoroacetic anhydride, 99+% 25GR
  • Trifluoroethanoicanhydride
  • TFAA
  • TRIFLUORACETIC ANHYDRIDE
  • TRIFLUOROACETIC ANHYDRIDE
  • TRIFLUOROACETIC ACID ANHYDRIDE
  • BIS(TRIFLUOROACETIC) ANHYDRIDE
  • Triflyuoroacetic anhydride
  • Aceticacid,trifluoro-,anhydride
  • Anhydrid kyseliny trifluoroctove
  • anhydridkyselinytrifluoroctove
  • Hexafluoroacetic anhydride
  • hexafluoroaceticanhydride
  • Perfluoroacetic anhydride
  • perfluoroaceticanhydride
  • TRIFLUOROACETIC ANHYDRIDE, REAGENTPLUS, >=99%
  • TRIFLUOROACETIC ANHYDRIDE, DERIVATIZA-TI ON REAGENT
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  • Trifluoraceticanhydride,min.98%
  • TRIFLUOROACETICANHYDRIDE,REAGENT
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  • TRIFLUOROACETIC ANHYDRINE
  • Trifluoressigsureanhydrid
  • Perfluoracetic anhydride
  • TRIFLUOROACETIC ANHYDRIDE: 99.5%
  • TRIFLUOROACETIC ANHYDRIDE FOR SYNTHESIS
  • TRIFLUOROACETIC ANHYDRIDE FOR GAS CHROMA
  • TFAH)Trifluoroacetic anhyd
  • 1,1,1,5,5,5-Hexafluoro-3-oxapentan-2,4-dione, Perfluoro(3-oxapentan-2,4-dione), 2,2,2-Trifluoroethanoic anhydride
  • Aceticacid, 2,2,2-trifluoro-, 1,1'-anhydride
  • Three fluorineacetic anhydride
  • trimethylamine (TMA)
  • Trifluoroacetic anhydride ReagentPlus(R), >=99%
  • Trifluoroacetyl 2,2,2-trifluoroacetate (Trifluoroacetic anhydride)
  • Trifluoroacetic anhydride≥ 99% (GC)
  • TFAA Trifluoroacetic acid anhydride
  • trifluoroacetic
  • trifluoro-aceticacianhydride
  • Trifluoroacetyl anhydride