2-(Bromomethyl)-6-methylpyridine
- Product Name
- 2-(Bromomethyl)-6-methylpyridine
- CAS No.
- 68470-59-7
- Chemical Name
- 2-(Bromomethyl)-6-methylpyridine
- Synonyms
- AKOS B016008;ART-CHEM-BB B016008;Bromomethyl)-6-methylpyridine;6-Methyl-2-(bromomethyl)pyridine;2-(BROMOMETHYL)-6-METHYLPYRIDINE;PYRIDINE, 2-(BROMOMETHYL)-6-METHYL-;2-(BroMoMethyl)-6-Methylpyridine 97%;2-(Bromomethyl)-6-methylpyridine ,97%;Pyridine, 2-(bromomethyl)-6-methyl- (6CI, 9CI);2-(Bromomethyl)-6-methylpyridine ISO 9001:2015 REACH
- CBNumber
- CB8348157
- Molecular Formula
- C7H8BrN
- Formula Weight
- 186.05
- MOL File
- 68470-59-7.mol
2-(Bromomethyl)-6-methylpyridine Property
- Melting point:
- 38-42 °C
- Boiling point:
- 209.9±25.0 °C(Predicted)
- Density
- 1.448±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- form
- solid
- pka
- 4.16±0.12(Predicted)
- Appearance
- Off-white to pink Solid
- Sensitive
- Air Sensitive
- InChI
- InChI=1S/C7H8BrN/c1-6-3-2-4-7(5-8)9-6/h2-4H,5H2,1H3
- InChIKey
- WJFDCFHWFHCLIW-UHFFFAOYSA-N
- SMILES
- C1(CBr)=NC(C)=CC=C1
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-37/38-41
- Safety Statements
- 26-36/37/39
- RIDADR
- UN 3335
- WGK Germany
- 3
- HS Code
- 29333990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 682179
- Product name
- 2-(Bromomethyl)-6-methylpyridine
- Purity
- 97%
- Packaging
- 1g
- Price
- $46.8
- Updated
- 2025/07/31
- Product number
- 682179
- Product name
- 2-(Bromomethyl)-6-methylpyridine
- Purity
- 97%
- Packaging
- 5g
- Price
- $296
- Updated
- 2025/07/31
- Product number
- B808060
- Product name
- 2-(Bromomethyl)-6-methylpyridine
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- B808060
- Product name
- 2-(Bromomethyl)-6-methylpyridine
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FB149775
- Product name
- 2-(Bromomethyl)-6-methylpyridine
- Packaging
- 10g
- Price
- $584
- Updated
- 2021/12/16
2-(Bromomethyl)-6-methylpyridine Chemical Properties,Usage,Production
Chemical Properties
Solid
Synthesis
1122-71-0
68470-59-7
A. Triphenylphosphine (0.4 g × 4, 6.1 mmol) was added to a stirred solution of (6-methylpyridin-2-yl)methanol (640 mg, 5.2 mmol) and carbon tetrabromide (2.77 g, 8.35 mmol) in batch to a solution of dichloromethane (12 mL) at 0 °C, each time at 2 min intervals. The reaction was continued for 30 min. Upon completion of the reaction, the reaction mixture was purified using rapid column chromatography using a hexane solution of 10% ethyl acetate as eluent to afford 2-(bromomethyl)-6-methylpyridine as a crystalline solid (675 mg, 70% yield).
References
[1] Journal of the American Chemical Society, 1994, vol. 116, # 18, p. 8410 - 8411
[2] Patent: WO2008/110793, 2008, A1. Location in patent: Page/Page column 112
[3] Patent: WO2008/125839, 2008, A2. Location in patent: Page/Page column 44
[4] Tetrahedron Letters, 2001, vol. 42, # 32, p. 5393 - 5395
[5] Canadian Journal of Chemistry, 2002, vol. 80, # 8, p. 973 - 982
2-(Bromomethyl)-6-methylpyridine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(Bromomethyl)-6-methylpyridine manufacturers
- Product
- 2-(Bromomethyl)-6-methylpyridine 68470-59-7
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-08-26
- Product
- 2-(Bromomethyl)-6-methylpyridine 68470-59-7
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2019-12-30