ChemicalBook > CAS DataBase List > 2-(Bromomethyl)-6-methylpyridine

2-(Bromomethyl)-6-methylpyridine

Product Name
2-(Bromomethyl)-6-methylpyridine
CAS No.
68470-59-7
Chemical Name
2-(Bromomethyl)-6-methylpyridine
Synonyms
AKOS B016008;ART-CHEM-BB B016008;Bromomethyl)-6-methylpyridine;6-Methyl-2-(bromomethyl)pyridine;2-(BROMOMETHYL)-6-METHYLPYRIDINE;PYRIDINE, 2-(BROMOMETHYL)-6-METHYL-;2-(BroMoMethyl)-6-Methylpyridine 97%;2-(Bromomethyl)-6-methylpyridine ,97%;Pyridine, 2-(bromomethyl)-6-methyl- (6CI, 9CI);2-(Bromomethyl)-6-methylpyridine ISO 9001：2015 REACH
CBNumber
CB8348157
Molecular Formula
C7H8BrN
Formula Weight
186.05
MOL File
68470-59-7.mol
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2-(Bromomethyl)-6-methylpyridine Property

Melting point:
38-42 °C
Boiling point:
209.9±25.0 °C(Predicted)
Density 
1.448±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
form 
solid
pka
4.16±0.12(Predicted)
Appearance
Off-white to pink Solid
Sensitive 
Air Sensitive
InChI
InChI=1S/C7H8BrN/c1-6-3-2-4-7(5-8)9-6/h2-4H,5H2,1H3
InChIKey
WJFDCFHWFHCLIW-UHFFFAOYSA-N
SMILES
C1(CBr)=NC(C)=CC=C1
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Safety

Hazard Codes 
Xn
Risk Statements 
22-37/38-41
Safety Statements 
26-36/37/39
RIDADR 
UN 3335
WGK Germany 
3
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
682179
Product name
2-(Bromomethyl)-6-methylpyridine
Purity
97%
Packaging
1g
Price
$46.8
Updated
2025/07/31
Sigma-Aldrich
Product number
682179
Product name
2-(Bromomethyl)-6-methylpyridine
Purity
97%
Packaging
5g
Price
$296
Updated
2025/07/31
TRC
Product number
B808060
Product name
2-(Bromomethyl)-6-methylpyridine
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
B808060
Product name
2-(Bromomethyl)-6-methylpyridine
Packaging
50mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB149775
Product name
2-(Bromomethyl)-6-methylpyridine
Packaging
10g
Price
$584
Updated
2021/12/16
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2-(Bromomethyl)-6-methylpyridine Chemical Properties,Usage,Production

Chemical Properties

Solid

Synthesis

1122-71-0

68470-59-7

A. Triphenylphosphine (0.4 g × 4, 6.1 mmol) was added to a stirred solution of (6-methylpyridin-2-yl)methanol (640 mg, 5.2 mmol) and carbon tetrabromide (2.77 g, 8.35 mmol) in batch to a solution of dichloromethane (12 mL) at 0 °C, each time at 2 min intervals. The reaction was continued for 30 min. Upon completion of the reaction, the reaction mixture was purified using rapid column chromatography using a hexane solution of 10% ethyl acetate as eluent to afford 2-(bromomethyl)-6-methylpyridine as a crystalline solid (675 mg, 70% yield).

References

[1] Journal of the American Chemical Society, 1994, vol. 116, # 18, p. 8410 - 8411
[2] Patent: WO2008/110793, 2008, A1. Location in patent: Page/Page column 112
[3] Patent: WO2008/125839, 2008, A2. Location in patent: Page/Page column 44
[4] Tetrahedron Letters, 2001, vol. 42, # 32, p. 5393 - 5395
[5] Canadian Journal of Chemistry, 2002, vol. 80, # 8, p. 973 - 982

2-(Bromomethyl)-6-methylpyridine Preparation Products And Raw materials

Raw materials

Acetic anhydride Hydrogen peroxide Hydrogen bromide 2,6-Lutidine Trifluoroacetic anhydride Acetic acid Sulfuric acid

Preparation Products

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View Lastest Price from 2-(Bromomethyl)-6-methylpyridine manufacturers

Dideu Industries Group Limited
Product
2-(Bromomethyl)-6-methylpyridine 68470-59-7
Price
US $1.10/g
Min. Order
1g
Purity
99.00%
Supply Ability
100 Tons min
Release date
2021-08-26
Career Henan Chemical Co
Product
2-(Bromomethyl)-6-methylpyridine 68470-59-7
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-30

68470-59-7, 2-(Bromomethyl)-6-methylpyridineRelated Search:

4-Methylpyridine 2-Chloro-5-chloromethylpyridine 1-Hexadecylpyridinium bromide 2-Bromo-6-methylpyridine 2,6-Lutidine 2,4,6-Collidine 2-BROMOMETHYL-PYRIDINE 2,6-BIS(BROMOMETHYL)PYRIDINE 2-BROMOMETHYL-6-PYRIDINE CARBOXYLIC ACID METHYL ESTER 2-(BROMOMETHYL)-6-(HYDROXYMETHYL)PYRIDINE Pyridine, 2-(bromomethyl)-4,6-dimethyl- (9CI) 6,6''-BIS(BROMOMETHYL)-[2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID ETHYL ESTER 6-BROMOMETHYL-2-CYANOPYRIDINE 1-[6-(BROMOMETHYL)PYRIDIN-2-YL]ETHANONE 2-BROMOMETHYL-6-METHYL-PYRIDINE HYDROBROMIDE 3-(BROMOMETHYL)-4-METHYLPYRIDINE 2-(Bromomethyl)-6-methylpyridine 2-(Bromomethyl)-4,6-dimethylpyridine hydrochloride

  • ART-CHEM-BB B016008
  • PYRIDINE, 2-(BROMOMETHYL)-6-METHYL-
  • AKOS B016008
  • 2-(BROMOMETHYL)-6-METHYLPYRIDINE
  • Pyridine, 2-(bromomethyl)-6-methyl- (6CI, 9CI)
  • 6-Methyl-2-(bromomethyl)pyridine
  • Bromomethyl)-6-methylpyridine
  • 2-(Bromomethyl)-6-methylpyridine ,97%
  • 2-(BroMoMethyl)-6-Methylpyridine 97%
  • 2-(Bromomethyl)-6-methylpyridine ISO 9001：2015 REACH
  • 68470-59-7
  • Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Pyridines
  • Building Blocks
  • HALOMETYL
  • Pyridine series