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LINALYL PHENYL ACETATE

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LINALYL PHENYL ACETATE Basic information

Product Name:
LINALYL PHENYL ACETATE
Synonyms:
  • aceticacid,phenyl-,1,5-dimethyl-1-vinyl-4-hexenylester
  • benzeneaceticacid,1,5-dimethyl-1-ethenyl-4-hexenylester
  • 3,7-dimethylocta-1,6-dien-3-yl 2-phenylacetate
  • Benzeneaceticacid,1-ethenyl-1,5-dimethyl-4-hexenylester
  • linalylalpha-toluate
  • Linalylphenylacetat
  • Phenylacetic acid 3,7-dimethyl-1,6-octadiene-3-yl ester
  • LINALYL PHENYL ACETATE
CAS:
7143-69-3
MF:
C18H24O2
MW:
272.38
EINECS:
230-444-2
Mol File:
7143-69-3.mol
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LINALYL PHENYL ACETATE Chemical Properties

Boiling point:
375.44°C (rough estimate)
Density 
1.0134 (rough estimate)
refractive index 
1.5510 (estimate)
FEMA 
3501 | LINALYL PHENYLACETATE
color 
A colourless or pale straw-coloured viscous liquid
Odor
at 100.00 %. rose sweet honey sick neroli rose
Odor Type
floral
JECFA Number
1019
LogP
5.64
EPA Substance Registry System
Benzeneacetic acid, 1-ethenyl-1,5-dimethyl-4-hexenyl ester (7143-69-3)
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Safety Information

Toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg(Moreno, 1974).
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LINALYL PHENYL ACETATE Usage And Synthesis

Description

Linalyl phenylacetate has a mildly floral, intensely sweet Neroli rose type odor. May be synthesized from dehydrolinalool and methyl phenylacetate in the presence of sodium methylate catalyst, followed by hydrogenation of the ester, or by any other suitable means.

Chemical Properties

Linalyl phenylacetate has a mildly floral, intensely sweet Neroli rose–type odor.

Occurrence

Has apparently not been reported to occur in nature

Definition

ChEBI: Linalyl phenylacetate is a monoterpenoid.

Preparation

From dehydrolinalool and methyl phenylacetate in the presence of sodium methylate catalyst, followed by hydrogenation of the ester, or by any other suitable means.

Metabolism

Open-chain olefinic terpene esters are presumably hydrolysed to the alcohol and the acid (Fassett, 1963). Open-chain terpenes are metabolized in the rabbit by ω-oxidation and by reduction of an a,B-double bond (Williams, 1959)

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