OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Chemical Properties

form 

powder

InChI

1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3

InChIKey

GIBDGLAUIKUJJX-UHFFFAOYSA-K

SMILES

CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

• Language:English Provider:SigmaAldrich

OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) Usage And Synthesis

Uses

Catalyst for:

• Enantioselective reduction of ketones and imines
• Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
• Synthesis of 2-deoxy-α glycosides
• Sulfurization of phosphorous(III) compounds with thiiranes

Reactant for synthesis of mono and dinuclear compounds

Reagent for rhenium-cyclized somatostatine derivative series synthesis

reaction suitability

core: rhenium
reagent type: catalyst

OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)(108695-90-5)Related Product Information

• Triphenylphosphine oxide