Hydrazine acetate Chemical Properties

Melting point:

100-102 °C (lit.)

Boiling point:

171.46°C (rough estimate)

Density 

1.2495 (rough estimate)

refractive index 

1.4350 (estimate)

storage temp. 

Keep in dark place,Inert atmosphere,2-8°C

form 

Fine Crystalline Powder

color 

White

InChI

InChI=1S/C2H4O2.H4N2/c1-2(3)4;1-2/h1H3,(H,3,4);1-2H2

InChIKey

YFHNDHXQDJQEEE-UHFFFAOYSA-N

SMILES

C(=O)(O)C.NN

EPA Substance Registry System

Hydrazine, monoacetate (7335-65-1)

Safety Information

Hazard Codes 

N-T,N,T

Risk Statements 

50/53-45-43-23/24/25-34-46

Safety Statements 

61-60-53-45-36/37/39-28-27-26-23

RIDADR 

UN 3263

WGK Germany 

3

HS Code 

29280000

MSDS

• Language:English Provider:Hydrazine acetate
• Language:English Provider:ACROS

Hydrazine acetate Usage And Synthesis

Description

Hydrazine acetate is an acetate salt of hydrazine. It is used as a reagent to cleavage glycosidic esters and anomeric denitration of carbohydrates. In organic synthesis, it is also used as a building block to prepare various organic derivatives.

Chemical Properties

white to light yellow adhering crystals or powder

Uses

suzuki reaction

Uses

Hydrazine acetate has been used in preparation of:

• 2,3,5-tri-O-acetyl-α-L-arabinofuranosyl trichloroacetimidate
• disaccharide 4-methoxyphenyl glycoside

Definition

Deformylation with hydrazine acetate was slower than that with hydrazine. Approximately 90% and 5% of the formyl group were removed at 50 and 20 °C, respectively, after 5 h. The rate of deformylation with hydrazine acetate is slower than that with hydrazine alone, but hydrazine acetate would be less harmful to a peptide when the peptide hydrazide is recovered from a formylated peptide hydrazide[1].

References

[1] K. Hojo. “Acylation of hydrazides with acetic acid and formic acid.” Chemical pharmaceutical bulletin 34 1 (2002): 140–2.

Hydrazine acetate(7335-65-1)Related Product Information

• Acetic acid
• Glycine
• Cellulose acetate
• Phenylhydrazine
• Indole-3-acetic acid
• Trichloroacetic acid
• Sodium acetate
• Vinyl acetate
• HYDRAZINE
• Hydrazine monohydrochloride
• Ethyl acetate
• Trifluoroacetic acid
• Butyl acetate
• CALCIUM ACETATE HYDRATE
• Calcium acetate monohydrate
• Magnesium acetate
• Cobalt acetate
• Calcium acetate