Tris(3-methoxyphenyl)phosphine Chemical Properties

Melting point:

113-115 °C(lit.)

Boiling point:

476.3±40.0 °C(Predicted)

storage temp. 

Inert atmosphere,Room Temperature

form 

Crystalline Powder

color 

White to almost white

InChI

InChI=1S/C21H21O3P/c1-22-16-7-4-10-19(13-16)25(20-11-5-8-17(14-20)23-2)21-12-6-9-18(15-21)24-3/h4-15H,1-3H3

InChIKey

CCXTYQMZVYIQRP-UHFFFAOYSA-N

SMILES

P(C1=CC=CC(OC)=C1)(C1=CC=CC(OC)=C1)C1=CC=CC(OC)=C1

CAS DataBase Reference

29949-84-6(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

TSCA 

No

HS Code 

29310099

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Tris(3-methoxyphenyl)phosphine Usage And Synthesis

Chemical Properties

White to almost white crystalline powder

Uses

suzuki reaction

Synthesis

1-iodo-3-methoxybenzene could be used to synthesize Tri(o-anisole)phosphine (Tris(3-methoxyphenyl)phosphine). Reactions performed using 0.1?mmol NaPH2, 2?mol?% PF6, 11?equiv 1-iodo-3-methoxybenzene, 15?equiv Et3N in 2.0?mL MeCN under blue LED irradiation and N2 atmosphere for 24?h[1]. 

References

[1]"Photocatalytic Arylation of P4 and PH3: Reaction Development Through Mechanistic Insight." Angewandte Chemie (2021).

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