TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Chemical Properties

Melting point:

145-147 °C(lit.)

Boiling point:

566.4±50.0 °C(Predicted)

storage temp. 

Sealed in dry,Room Temperature

solubility 

very faint turbidity in hot Methanol

form 

Powder

color 

white to off-white

Sensitive 

air sensitive

CAS DataBase Reference

85417-41-0

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

TSCA 

No

HS Code 

29310099

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

• Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
• Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
• Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
• Oxycylizations of allendiols
• Enantioselective aldol reactions
• Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions

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