3-Vinylaniline Chemical Properties

Boiling point:

212.46°C (rough estimate)

Density 

1.051 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.611(lit.)

Flash point:

228 °F

storage temp. 

2-8°C

solubility 

Chloroform (Slightly), Methanol (Slightly)

pka

4.39±0.10(Predicted)

form 

Oil

color 

Clear Colourless

InChIKey

IFSSSYDVRQSDSG-UHFFFAOYSA-N

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

HS Code 

2921420090

MSDS

• Language:English Provider:SigmaAldrich

3-Vinylaniline Usage And Synthesis

Description

3-vinylaniline (3-VA) is a significant compound of aniline having a vinyl group and can be used for the production of fine chemicals, functionalized polymers, pigment and pharmaceuticals. Generally, 3-VA is produced by the selective hydrogenation reaction of 3-nitrostyrene (3-NS).

Uses

The formation of m-Vinylaniline from the reduction of m-Nitrostyrene containing an easily reducible vinyl-group using hydrazine hydrate as the reducing agent.

References

[1] Mekasuwandumrong O, Chaitaworn S, Panpranot J, Praserthdam P.Photocatalytic Liquid-Phase Selective Hydrogenation of 3-Nitrostyrene to 3-vinylaniline of Various Treated-TiO2 Without Use of Reducing Gas. Catalysts. 2019; 9(4):329.DOI: 10.3390/catal9040329
[2] DAI C, ZHANG Y, CHEN J, et al. Support Morphology Effect on Selective Hydrogenation of 3-Nitrostyrene to 3-Vinylaniline over Pt/α-Fe2 O3 Catalysts.[J]. Chemistry, 2022: e202200199. DOI: 10.1002/chem.202200199

3-Vinylaniline(15411-43-5)Related Product Information

• 6-nitrocoumarin
• 3-NITROCINNAMIC ACID
• ETHYL 3-NITROCINNAMATE
• 3-Nitrostyrene
• 3-NITROCHALCONE
• 1',3',3'-TRIMETHYLSPIRO-8-NITRO(2H-1-BENZOPYRAN)-2',2'-INDOLINE
• PINACRYPTOL YELLOW
• EOSIN B
• 9-DICYANOMETHYLENE-2,4,7-TRINITROFLUORENE
• 4-Vinylanilin
• 6-ACETAMIDOCOUMARIN
• 3-Vinylaniline
• 1-(4-METHYLPHENYL)-3-(3-NITROPHENYL)PROP-2-EN-1-ONE
• 4-(3-NITRO-STYRYL)-PYRIDINE ETHYL IODIDE
• 5-IAF
• 2-AMINOSTYRENE,2-AMINOSTYRENE
• POLY(4-AMINOSTYRENE),POLY(4-AMINOSTYRENE)
• 1-(2-HYDROXYPHENYL)-3-(3-NITROPHENYL)PROP-2-EN-1-ONE