2-Nitrodiphenyl
2-Nitrodiphenyl Basic information
- Product Name:
- 2-Nitrodiphenyl
- Synonyms:
-
- 2-phenylnitrobenzene
- Biphenyl, 2-nitro-
- cp368
- Onb
- Nitrodiphenyl
- ORTHO-NITROBIPHENYL
- ORTHO-NITRODIPHENYL
- 1-Nitro-2-phenylbenzene
- CAS:
- 86-00-0
- MF:
- C12H9NO2
- MW:
- 199.21
- EINECS:
- 201-646-8
- Product Categories:
-
- Camphor, etc. (Plasticizer)
- Functional Materials
- Plasticizer
- Mol File:
- 86-00-0.mol
2-Nitrodiphenyl Chemical Properties
- Melting point:
- 36-38 °C(lit.)
- Boiling point:
- 320 °C
- Density
- 1.44
- vapor density
- 5.9 (vs air)
- vapor pressure
- 2 mm Hg ( 140 °C)
- refractive index
- 1.613-1.615
- Flash point:
- >230 °F
- form
- powder to lump
- color
- White to Yellow to Green
- Water Solubility
- Insoluble
- Merck
- 14,6591
- CAS DataBase Reference
- 86-00-0(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,1'-Biphenyl, 2-nitro-(86-00-0)
- EPA Substance Registry System
- o-Nitrobiphenyl (86-00-0)
Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-40-68-22
- Safety Statements
- 2-7-36-45-36/37
- WGK Germany
- 3
- RTECS
- DV5530000
- HS Code
- 2904.20.5000
MSDS
- Language:English Provider:2-Nitrodiphenyl
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
2-Nitrodiphenyl Usage And Synthesis
Chemical Properties
CLEAR YELLOW LIQUID AFTER MELTING
Uses
Plasticizer for resins, cellulose acetate and nitrate, polystyrenes; fungicide for textiles; wood preservative; dye intermediate.
Synthesis Reference(s)
Tetrahedron Letters, 36, p. 6567, 1995 DOI: 10.1016/0040-4039(95)01327-E
General Description
Gold to tan crystals or brown solid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Aromatic nitro compounds, such as 2-Nitrodiphenyl, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Fire Hazard
2-Nitrodiphenyl is combustible.
Purification Methods
Crystallise it from EtOH (seeding required). Sublime it under vacuum. [Beilstein 5 H 582, 5 I 273, 5 II 487, 5 III 1750.]
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