ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic iridium > POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Basic information
- Product Name:
- POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
- Synonyms:
-
- POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
- potassium,(beta-4)-borate(1-hydrotris(1-methylpropyl)-
- potassiumtri-sec-butylborohydride,calselect?k,
- potassiumtri-sec-butylborohydride,calselect?k,intetrahydrofuran
- K-SELECTRIDE(R)
- Potassium tri-sec-butylborohydride, 1M solution in tetrahydrofuran, AcroSeal
- potassiumtri-sec-butylborohydride,calselectk,intetrahydrofur
- (ca. 1.0Mol/L in Tetrahydrofuran)
- CAS:
- 54575-49-4
- MF:
- C12H25BK
- MW:
- 219.24
- EINECS:
- 259-241-7
- Product Categories:
-
- B (Classes of Boron Compounds)
- Classes of Metal Compounds
- K (Potassium) Compounds (excluding simple potassium salts)
- Reduction
- Synthetic Organic Chemistry
- Tetrahydroborates
- Typical Metal Compounds
- metal alkyl
- Mol File:
- 54575-49-4.mol
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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Chemical Properties
- Density
- 0.913 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- form
- Solution
- color
- Clear slightly yellow
- Sensitive
- moisture sensitive
- InChI
- InChI=1S/C12H25B.K/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h13H,7-9H2,1-6H3;/q-1;+1
- InChIKey
- WRYQJJOHBLICCR-UHFFFAOYSA-N
- SMILES
- [B+3]([H-])([C-](C)CC)([C-](C)CC)[C-](C)CC.[K+]
- EPA Substance Registry System
- Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4)
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Safety Information
- Hazard Codes
- F,C
- Risk Statements
- 11-15-34-37-19-14/15-40
- Safety Statements
- 16-26-36/37/39-43-45
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 3
- F
- 10
- HS Code
- 29310099
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Usage And Synthesis
Description
Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes.
Chemical Properties
clear slightly yellow solution
Uses
Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions.
Uses
- Reducing reagent
Reactant for:
- Preparation of a PCP-pincer palladium hydride-K-Selectride complex
- Formation of P-H, P-C, and C-H bonds by hydride attack
- Stereoselective conjugate hydride reduction reactions
Uses
Mild reducing agents in organic synthesis.
reaction suitability
reagent type: reductant
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDESupplier
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259138 18621169109
- market03@meryer.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Shanghai Longsheng chemical Co.,Ltd.
- Tel
- 021-58099652-8005 13585536065
- bin.wu@shlschem.com
Shandong Xiya Chemical Co., Ltd
- Tel
- 4009903999 13355009207
- 3007715519@qq.com